公开(公告)号：KR100559367B1

公开(公告)日：2006-03-10

申请号：KR1020040036107

申请日：2004-05-20

Applicant: 한국과학기술연구원

Inventor： 한호규 ,  남기달 ,  조광연 ,  최경자

IPC: A01N43/78

Abstract: 일반식(I)로 표시되는 2-페닐이미노-1,3-티아졸리딘 유도체 및 그 염을 유효 성분으로 하는 식물 탄저병균 방제제

公开(公告)号：KR1020020010028A

公开(公告)日：2002-02-02

申请号：KR1020000043795

申请日：2000-07-28

Applicant: 한국과학기술연구원

Inventor： 한호규 ,  남기달 ,  장기혁 ,  조광연 ,  김흥태

IPC: A01N43/78

CPC classification number: A01N43/78 ,  C07D277/42

Abstract: PURPOSE: A process of preparing 2-phenyliminothiazoline derivatives and salts thereof by reacting isothiocyanate derivatives and phenylamine in an inactive organic solvent and then reacting the obtained phenylthiourea derivatives with gamma-halo-beta-ketoanilide derivatives in the presence of an inactive organic solvent is provided. Whereby, the compounds are useful as an agricultural germicide. CONSTITUTION: 2-phenyliminothiazoline derivatives of formula(I-a) show a fungicidal activity, in particular against rice blast disease. In formula, R1 and R2 are each alkyl expressed by H, methyl, ethyl, propyl, butyl, pentyl or hexyl, halo expressed by fluoro, chloro or bromo, alkoxy expressed by methoxy, ethoxy, propoxy, isopropoxy, butyl, isobutoxy or sec-butoxy, alkoxycarbonyl expressed by cyano, nitro, trifluoromethyl, trifluoromethoxy, methylthio, phenyl, phenoxy, methoxycarbonyl, ethoxycaronyl, propoxycarbonyl or isopropoxycarbonyl; R3 is alkyl expressed by H, methyl, ethyl, propyl, isopropyl, cyclopropyl, butyl, pentyl, cyclopentyl, hexyl, cyclohexyl or aryl, or cycloalkyl; and X is Cl or Br.

Abstract translation: 目的：提供通过使异硫氰酸酯衍生物和苯胺在无活性有机溶剂中反应制备2-苯基亚氨基噻唑啉衍生物及其盐的方法，然后在惰性有机溶剂的存在下使得到的苯基硫脲衍生物与γ-卤代-β-酮替苯胺衍生物反应， 。 因此，这些化合物可用作农业杀菌剂。 构成：式（I-a）的2-苯基亚氨基噻唑啉衍生物显示杀真菌活性，特别是抗稻瘟病。 在式中，R 1和R 2各自是被H，甲基，乙基，丙基，丁基，戊基或己基表示的烷基，由氟，氯或溴表示的卤代，由甲氧基，乙氧基，丙氧基，异丙氧基，丁基，异丁氧基或仲 硝基，三氟甲基，三氟甲氧基，甲硫基，苯基，苯氧基，甲氧基羰基，乙氧基羰基，丙氧基羰基或异丙氧基羰基表示的烷氧基羰基; R3是由H，甲基，乙基，丙基，异丙基，环丙基，丁基，戊基，环戊基，己基，环己基或芳基或环烷基表示的烷基; X为Cl或Br。

公开(公告)号：KR1019890005273A

公开(公告)日：1989-05-13

申请号：KR1019870009944

申请日：1987-08-28

Applicant: 한국과학기술연구원 ,  신무룡 ,  이성용 ,  한국화학연구원 ,  삼성전자주식회사 ,  주식회사 포스코 ,  주식회사 엘지이아이

Inventor： 장호남 ,  정봉현 ,  이성용 ,  이재현 ,  최일영 ,  김영애 ,  강철훈 ,  김형진 ,  조광연 ,  이정모 ,  박병곤 ,  정세영 ,  정석동 ,  신무룡

IPC: C07C51/00

Abstract: 내용 없음

公开(公告)号：KR1020050111413A

公开(公告)日：2005-11-25

申请号：KR1020040036107

申请日：2004-05-20

Applicant: 한국과학기술연구원

Inventor： 한호규 ,  남기달 ,  조광연 ,  최경자

IPC: A01N43/78

CPC classification number: A01N43/78 ,  C07D277/42

Abstract: 일반식(I)로 표시되는 2-페닐이미노-1,3-티아졸리딘 유도체 및 그 염을 유효 성분으로 하는 식물 탄저병균 방제제

公开(公告)号：KR100387583B1

公开(公告)日：2003-06-18

申请号：KR1020000043795

申请日：2000-07-28

Applicant: 한국과학기술연구원

Inventor： 한호규 ,  남기달 ,  장기혁 ,  조광연 ,  김흥태

IPC: A01N43/78

CPC classification number: A01N43/78 ,  C07D277/42

Abstract: 2-phenyliminothiazolines of the following formula I, their salts, their preparation method and their use for treating rice blast. The phenyliminothiazolines and their salts of the present invention have low toxicity to environment or living organisms, and exert high activity at low concentration for treating rice blast through a new control mechanism, that is by inhibiting pentaketide synthesis and cyclization of the melanin sythesis process in formula I

Abstract translation: 下式I的2-苯基亚氨基噻唑啉及其盐，其制备方法及其用于治疗稻瘟病的用途。 本发明的苯基亚氨基噻唑啉类及其盐类对环境或生物体的毒性低，通过新的调控机制在低浓度下发挥高活性，用于抑制稻瘟病的发生，即通过抑制方案中黑色素合成和黑素合成过程的环化 一世