公开(公告)号：KR100457824B1

公开(公告)日：2004-11-18

申请号：KR1020010048336

申请日：2001-08-10

Applicant: 한국화학연구원

Inventor： 김윤수 ,  김창균 ,  성기환 ,  임종태

IPC: B82B3/00 ,  B82Y40/00

CPC classification number: B82Y30/00 ,  C01B13/18 ,  C01F5/06 ,  C01G9/02 ,  C01G11/00 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/64 ,  C01P2006/12

Abstract: A nanoparticle of a metal oxide is prepared by pyrolyzing a compound of formula (I) in a solvent:RMOR' (I) wherein M is beryllium, zinc, magnesium or cadmium; and R and R' are independently a C1-5 alkyl group.

Abstract translation: 金属氧化物的纳米颗粒通过式（I）化合物在溶剂中热解而制备：RMOR'（I）其中M是铍，锌，镁或镉; 并且R和R'独立地为C 1-5烷基。

公开(公告)号：KR1020030014019A

公开(公告)日：2003-02-15

申请号：KR1020010048336

申请日：2001-08-10

Applicant: 한국화학연구원

Inventor： 김윤수 ,  김창균 ,  성기환 ,  임종태

IPC: B82B3/00 ,  B82Y40/00

CPC classification number: B82Y30/00 ,  C01B13/18 ,  C01F5/06 ,  C01G9/02 ,  C01G11/00 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/64 ,  C01P2006/12

Abstract: PURPOSE: Provided is a method for producing divalent metal oxide powder having a nano size by solution pyrolysis by which it is possible to readily produce the metal oxide powder having a nano size and control the size and shape of the particles using a ligand. CONSTITUTION: The method for producing divalent metal oxide powder having a nano size is conducted by pyrolysis of alkylate alkyl metal compound represented by the formula of RMOR', in which M is beryllium, zinc, magnesium or cadmium and R and R' are a hydrogen atom or an alkyl group containing 1 to 5 carbon atoms, in an organic solvent. The solvent is an organic compound having a boiling point between 100 to 400 deg.C, such as hexadecane, tetra(ethyleneglycol)dimethylether, dimethoxyethane and octylether.

Abstract translation: 目的：提供通过溶液热解生产具有纳米尺寸的二价金属氧化物粉末的方法，通过该方法可以容易地制备具有纳米尺寸的金属氧化物粉末，并使用配体控制颗粒的尺寸和形状。 构成：制造具有纳米尺寸的二价金属氧化物粉末的方法是通过将由式RMOR'表示的烷基化烷基金属化合物热解，其中M是铍，锌，镁或镉，R和R'是氢 原子或含有1至5个碳原子的烷基。 溶剂是沸点在100-400℃之间的有机化合物，如十六烷，四（乙二醇）二甲醚，二甲氧基乙烷和辛醚。