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公开(公告)号：KR1020030029253A
公开(公告)日：2003-04-14
申请号：KR1020010061520
申请日：2001-10-05
Applicant: 한국화학연구원 , 여천엔씨씨 주식회사
IPC: B01J31/18
CPC classification number: B01J31/18 , B01J31/1805 , B01J2531/62 , C07C2/02
Abstract: PURPOSE: Provided is a catalytic system that consists of Cr compound, ligand, alkylaluminium and halogen compound and for increasing 1-hexene selectivity in ethylene trimerization. CONSTITUTION: The catalytic system consists of chrome compound, ligand, alkylaluminium and halogen compound, wherein the ligand is a complex ligand being comprised of 1-coordinate ligand and 2-coordinate ligand, and wherein the 2-coordinate ligand includes at least two elements selected from oxygen (O), nitrogen (N) and sulfur (S), and the 1-coordinate ligand includes one element selected from oxygen (O), nitrogen (N), phosphorous (P), and sulfur (S), and further wherein the 2-coordinate ligand and the 1-coordinate ligand are included in the catalytic system with a mole ratio to chrome 0.5-1.5:1.
Abstract translation: 目的：提供由Cr化合物，配体，烷基铝和卤素化合物组成的催化体系，并且用于在乙烯三聚中增加1-己烯选择性。 构成：催化体系由铬化合物，配位体，烷基铝和卤素化合物组成，其中配体是由1-配位配位体和2-配位配体构成的复合配体，其中2-配位配体包括至少两个选自 来自氧（O），氮（N）和硫（S），并且1-配位配体包括选自氧（O），氮（N），磷（P）和硫（S）中的一种元素， 其中2-配位配体和1-配位配位体以摩尔比为0.5-1.5:1包含在催化体系中。
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公开(公告)号：KR100369707B1
公开(公告)日：2003-02-05
申请号：KR1020010001196
申请日：2001-01-09
Applicant: 한국화학연구원
IPC: C07D251/56
Abstract: PURPOSE: A method for preparing a crystalline melamine cyanurate composite is provided, to control the shape and size of particles by controlling the content of water-insoluble metal oxides and water-soluble hydroxides and the reaction conditions. CONSTITUTION: The method comprises the step of reacting melamine and cyanuric acid with a water-insoluble metal hydroxide or metal oxide and a water-soluble hydroxide. Preferably the reaction is carried out at a temperature of 80-100 deg.C for 0.5-2 hours. The water-insoluble metal hydroxide is selected from the group consisting of Mg(OH)2, Al(OH)3, Ca(OH)2 and magnesium/aluminum composite hydroxide; the water-insoluble metal oxide is selected from the group consisting of MgO, Al2O3, CaO and magnesium/aluminum composite oxide; and the water-soluble hydroxide is selected from the group consisting of NH4OH, LiOH, NaOH and KOH. Preferably the particle size of the water-insoluble metal hydroxide or metal oxide is 0.5-10 micrometers. The content of the water-insoluble metal hydroxide or metal oxide is 0.1-5.0 wt% based on the weight of solid reactant; and the content of water-soluble hydroxide is less than 20 wt% based on the weight of the water-insoluble metal hydroxide or metal oxide.
Abstract translation: 目的：提供一种制备结晶三聚氰胺氰尿酸酯复合物的方法，通过控制水不溶性金属氧化物和水溶性氢氧化物的含量以及反应条件来控制颗粒的形状和尺寸。 组成：该方法包括使三聚氰胺和氰尿酸与水不溶性金属氢氧化物或金属氧化物和水溶性氢氧化物反应的步骤。 优选反应在80-100℃的温度下进行0.5-2小时。 水不溶性金属氢氧化物选自Mg（OH）2，Al（OH）3，Ca（OH）2和镁/铝复合氢氧化物; 水不溶性金属氧化物选自MgO，Al 2 O 3，CaO和镁/铝复合氧化物; 并且水溶性氢氧化物选自由NH 4 OH，LiOH，NaOH和KOH组成的组。 优选水不溶性金属氢氧化物或金属氧化物的粒度为0.5-10微米。 基于固体反应物的重量，水不溶性金属氢氧化物或金属氧化物的含量为0.1-5.0重量％ 并且基于水不溶性金属氢氧化物或金属氧化物的重量，水溶性氢氧化物的含量小于20重量％。
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公开(公告)号：KR1020040067435A
公开(公告)日：2004-07-30
申请号：KR1020030004534
申请日：2003-01-23
Applicant: 한국화학연구원
IPC: C08F4/06
CPC classification number: C08F110/02 , C08F10/00 , C08F2500/23 , Y10S585/946
Abstract: PURPOSE: Provided is a catalyst system, with which polyolefin wax having increased wax content and excellent physical properties can be prepared under mild reaction conditions. CONSTITUTION: The catalyst system for preparing polyolefin wax comprises a main catalyst containing a transition metal component, a calixarene ligand and a halogen component, and a co-catalyst containing an organoaluminum compound. In the main catalyst, the transition metal component is selected from the group consisting of chrome, titanium, vanadium and zirconium. The calixarene ligand is one selected from the group consisting of para-butylcalix£4|arene, parabutylcalix£5|arene, parabutylcalix£6|arene, parabutylcalix£8| arene and derivatives thereof, or a combination thereof. Additionally, the halogen component is chlorine or bromine.
Abstract translation: 目的：提供了一种催化剂体系，可以在温和的反应条件下制备蜡含量增加和物理性能优异的聚烯烃蜡。 构成：用于制备聚烯烃蜡的催化剂体系包括含有过渡金属组分，杯芳烃配体和卤素组分的主催化剂和含有有机铝化合物的助催化剂。 在主催化剂中，过渡金属组分选自铬，钛，钒和锆。 杯芳烃配体是选自对 - 丁基水ix ix ne ne ne ne ix ix ne ne ne ne ix£££££££| | | | | | | 芳烃及其衍生物，或其组合。 另外，卤素组分是氯或溴。
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公开(公告)号：KR100453741B1
公开(公告)日：2004-10-20
申请号：KR1020010068514
申请日：2001-11-05
Applicant: 한국화학연구원 , 여천엔씨씨 주식회사
IPC: C08F4/69
Abstract: PURPOSE: Provided is a chrome-calixarene-organoaluminum catalyst which has excellent catalytic activity and is stable in polymerizing olefin. The catalyst is simple to synthesize and reproducible. It can be used in making specific polymers different from polymers made by usual Ziegler-Natta or chrome supported catalysts in molecular weight distribution and the degree of crystallinity and unsaturation. CONSTITUTION: The catalyst comprises 1 mole of chrome(III) compound, 0.5-2 moles of calixarene compound and 10-1000 moles of organic aluminum compound. The polymerization is carried out with the catalyst at 30-200deg.C under 3-50 atm and the catalyst is either added with molecular chrome-calixarene and organic aluminum respectively or in one shot of the mixed component.
Abstract translation: 用途：提供一种铬 - 杯芳烃 - 有机铝催化剂，其具有优异的催化活性并且在聚合烯烃中稳定。 该催化剂合成简单，重现性好。 它可以用于制造不同于由通常的齐格勒 - 纳塔制造的聚合物或铬负载的催化剂的特定聚合物，其分子量分布和结晶度和不饱和度。 构成：催化剂包含1摩尔铬（III）化合物，0.5-2摩尔杯芳烃化合物和10-1000摩尔有机铝化合物。 用催化剂在30〜200℃，3-50大气压下进行聚合反应，催化剂分别加入分子铬 - 杯芳烃和有机铝或一次加入混合组分。
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公开(公告)号：KR100435513B1
公开(公告)日：2004-06-10
申请号：KR1020010061520
申请日：2001-10-05
Applicant: 한국화학연구원 , 여천엔씨씨 주식회사
IPC: B01J31/18
Abstract: PURPOSE: Provided is a catalytic system that consists of Cr compound, ligand, alkylaluminium and halogen compound and for increasing 1-hexene selectivity in ethylene trimerization. CONSTITUTION: The catalytic system consists of chrome compound, ligand, alkylaluminium and halogen compound, wherein the ligand is a complex ligand being comprised of 1-coordinate ligand and 2-coordinate ligand, and wherein the 2-coordinate ligand includes at least two elements selected from oxygen (O), nitrogen (N) and sulfur (S), and the 1-coordinate ligand includes one element selected from oxygen (O), nitrogen (N), phosphorous (P), and sulfur (S), and further wherein the 2-coordinate ligand and the 1-coordinate ligand are included in the catalytic system with a mole ratio to chrome 0.5-1.5:1.
Abstract translation: 目的：提供一种由Cr化合物，配体，烷基铝和卤素化合物组成的催化体系，用于提高乙烯三聚中的1-己烯选择性。 构成：催化体系由铬化合物，配体，烷基铝和卤素化合物组成，其中配体是由1-配位配体和2-配位配体组成的配位配体，其中2-配位配体包括至少两种选择的元素 （O），氮（N）和硫（S），并且1-配位配体包括选自氧（O），氮（N），磷（P）和硫（S）中的一种元素，并且进一步 其中所述2-配位配体和1-配位配体以相对于铬0.5-1.5:1的摩尔比包含在所述催化体系中。
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Patent Agency Ranking6.发明授权
公开(公告)号：KR100427458B1
公开(公告)日：2004-04-27
申请号：KR1020010022042
申请日：2001-04-24
IPC: C07C29/74
Abstract: PURPOSE: Provided is a method for separating a liquid alkoxylation product efficiently from an alkoxylation product containing a gel type by-product, which can increase filtering velocity and maximize the yield of the alkoxylation product. CONSTITUTION: The method is performed by adding 10-100vol%(based on an alkoxylation mixture) of a C1-C4 alcohol having a boiling point of 50-100deg.C to the alkoxylation mixture comprising the alkoxylation product produced by alkoxylation of an aliphatic alcohol or an aliphatic acid ester in the presence of a solid catalyst, the gel type by-product, and a catalyst residue to disperse uniformly and filtering the dispersed solution and then distilling and removing the alcohol from the filtrate.
Abstract translation: 目的：提供一种从含有凝胶型副产物的烷氧基化产物中有效地分离液体烷氧基化产物的方法，其可以提高过滤速度并使烷氧基化产物的产率最大化。 构成：该方法通过将含有沸点为50-100℃的C 1 -C 4醇的10-100体积％（基于烷氧基化混合物）加入到烷氧基化混合物中，所述烷氧基化混合物包含通过烷氧基化脂族醇 或脂肪酸酯在固体催化剂，凝胶型副产物和催化剂残余物存在下均匀分散并过滤分散的溶液，然后蒸馏并从滤液中除去醇。
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公开(公告)号：KR1020020082574A
公开(公告)日：2002-10-31
申请号：KR1020010022042
申请日：2001-04-24
IPC: C07C29/74
Abstract: PURPOSE: Provided is a method for separating a liquid alkoxylation product efficiently from an alkoxylation product containing a gel type by-product, which can increase filtering velocity and maximize the yield of the alkoxylation product. CONSTITUTION: The method is performed by adding 10-100vol%(based on an alkoxylation mixture) of a C1-C4 alcohol having a boiling point of 50-100deg.C to the alkoxylation mixture comprising the alkoxylation product produced by alkoxylation of an aliphatic alcohol or an aliphatic acid ester in the presence of a solid catalyst, the gel type by-product, and a catalyst residue to disperse uniformly and filtering the dispersed solution and then distilling and removing the alcohol from the filtrate.
Abstract translation: 目的：提供一种从含有凝胶型副产物的烷氧基化产物有效分离液体烷氧基化产物的方法，其可提高过滤速度并使烷氧基化产物的产率最大化。 构成：该方法通过将含有沸点为50-100℃的C 1 -C 4醇的10-100vol％（基于烷氧基化混合物）加入到通过脂族醇的烷氧基化产生的烷氧基化产物的烷氧基化混合物 或脂肪酸酯在固体催化剂，凝胶型副产物和催化剂残余物的存在下均匀分散并过滤分散的溶液，然后从滤液中蒸馏除去醇。
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公开(公告)号：KR1020020060000A
公开(公告)日：2002-07-16
申请号：KR1020010001196
申请日：2001-01-09
Applicant: 한국화학연구원
IPC: C07D251/56
Abstract: PURPOSE: A method for preparing a crystalline melamine cyanurate composite is provided, to control the shape and size of particles by controlling the content of water-insoluble metal oxides and water-soluble hydroxides and the reaction conditions. CONSTITUTION: The method comprises the step of reacting melamine and cyanuric acid with a water-insoluble metal hydroxide or metal oxide and a water-soluble hydroxide. Preferably the reaction is carried out at a temperature of 80-100 deg.C for 0.5-2 hours. The water-insoluble metal hydroxide is selected from the group consisting of Mg(OH)2, Al(OH)3, Ca(OH)2 and magnesium/aluminum composite hydroxide; the water-insoluble metal oxide is selected from the group consisting of MgO, Al2O3, CaO and magnesium/aluminum composite oxide; and the water-soluble hydroxide is selected from the group consisting of NH4OH, LiOH, NaOH and KOH. Preferably the particle size of the water-insoluble metal hydroxide or metal oxide is 0.5-10 micrometers. The content of the water-insoluble metal hydroxide or metal oxide is 0.1-5.0 wt% based on the weight of solid reactant; and the content of water-soluble hydroxide is less than 20 wt% based on the weight of the water-insoluble metal hydroxide or metal oxide.
Abstract translation: 目的：提供一种制备结晶三聚氰胺氰脲酸酯复合物的方法，通过控制水不溶性金属氧化物和水溶性氢氧化物的含量以及反应条件来控制颗粒的形状和尺寸。 构成：该方法包括使三聚氰胺和氰尿酸与水不溶性金属氢氧化物或金属氧化物和水溶性氢氧化物反应的步骤。 优选地，反应在80-100℃的温度下进行0.5-2小时。 水不溶性金属氢氧化物选自Mg（OH）2，Al（OH）3，Ca（OH）2和镁/铝复合氢氧化物; 水不溶性金属氧化物选自MgO，Al2O3，CaO和镁/铝复合氧化物; 水溶性氢氧化物选自NH 4 OH，LiOH，NaOH和KOH。 优选地，水不溶性金属氢氧化物或金属氧化物的粒度为0.5-10微米。 基于固体反应物的重量，水不溶性金属氢氧化物或金属氧化物的含量为0.1-5.0重量％ 并且水溶性氢氧化物的含量相对于水不溶性金属氢氧化物或金属氧化物的重量小于20重量％。
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公开(公告)号：KR100524814B1
公开(公告)日：2005-10-31
申请号：KR1020030004534
申请日：2003-01-23
Applicant: 한국화학연구원
IPC: C08F4/06
Abstract: 본 발명은 폴리올레핀 왁스 제조용 촉매계 및 이를 이용하는 왁스의 제조방법에 관한 것으로서, 더욱 상세하게는 중심금속성분에 칼릭사렌계 리간드와 할로겐 성분을 포함하는 주촉매물질과 유기알루미늄 화합물의 조촉매물질로 구성된 새로운 촉매계 및 이를 이용하는 올레핀의 소중합 반응에서 이들 구성 성분의 조합 비율을 일정 범위로 제한하고 분자량 제어 역할을 하는 수소를 사용하지 않으며 반응조건을 선택함으로써, 반응 활성을 높게 유지할 수 있으며 결정성과 분자량 분포에서 우수한 물성을 갖는 왁스를 제조하는 방법에 관한 것이다.
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公开(公告)号：KR100493926B1
公开(公告)日：2005-06-10
申请号：KR1020020061271
申请日：2002-10-08
Applicant: 한국화학연구원 , 여천엔씨씨 주식회사
IPC: B01J31/34
Abstract: 본 발명은 올레핀, 특별히 에틸렌 소량화 촉매 조성물과 소량화 반응 방법에 관한 것으로, 더욱 상세하게는 Cr 화합물, 리간드, 알킬알루미늄로 구성되고, 리간드 성분으로 피리딘 골격의 2,6 위치에 적절한 배위자리를 갖는 원자를 포함하는 작용기가 치환된 3배위 피리딘 골격 리간드를 적용하며 또한 이들 구성 성분의 조합 비율을 조절함으로써, 올레핀, 특별히 에틸렌의 소량화 반응을 통하여 C
4 ∼C
10 범위의 올레핀을 선택적이며 높은 반응활성으로 제조하는 화학반응에 적용되는 새로운 형태의 촉매 조성물과 이의 적용 방법에 관한 것이다.
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