Abstract:
본 발명은 기존 가솔린 자동차 엔진에서 발생하는 질소산화물 (NOx) 저감 성능 개선을 위한 삼원 촉매(THREE-WAY CATALYST, TWC)-SCR 촉매 시스템의 암모니아 (NH 3 ) 생성용 삼원 촉매(THREE-WAY CATALYST, TWC) 개발에 관한 내용이다. 특히 삼원 촉매(THREE-WAY CATALYST, TWC)의 주요 구성원인 귀금속 (noble metal)의 대체 없이 기존 시스템을 유지하면서 삼원 촉매(THREE-WAY CATALYST, TWC)를 산화열처리 후 암모니아 생성량 증대 및 지지체에 따른 NH 3 생성량 변화 확인을 통한 NH 3 생성 최적 촉매 개발이 본 발명의 주요 착안점이다.
Abstract:
PURPOSE: A manufacturing method of three-way catalyst producing ammonia for passive ammonia/selective catalytic reduction and a tree-way catalyst manufactured by the same are provided to be effectively used for environmentally-friendly automobiles. CONSTITUTION: A catalyst for reducing nitrogen oxide into ammonia is carried in a metal oxide carrier. A manufacturing method of the catalyst includes a step for thermally treating noble metal powder carried in the metal oxide carrier in the process of manufacturing a three-way catalyst based on an impregnation method. The noble metal is rhodium(Rh). The metal oxide support is Al2O3, SiO2, ZrO2, CeO2, C3Z1(Ce0.75Zr0.25O2), or the mixture. The noble metal carried in the carrier is thermally treated at 800-1,200 deg. C. The weight ratio of the noble metal impregnated in the metal oxide carrier is 0.01-1 weight%. [Reference numerals] (AA) NH3 productivity(ppm)
Abstract:
The object of the present invention is to provide a catalyst for converting nitrogen oxides into ammonia and a manufacturing method thereof, wherein the catalyst is capable of converting nitrogen oxides into ammonia under the condition of diluted exhaust gas with stoichiometric air-fuel ratio (A/F=14.7). To achieve the object, the catalyst for converting nitrogen oxides into ammonia according to the present invention includes a metal support with precious metal and is capable of converting nitrogen oxides into ammonia under the condition of diluted exhaust gas with stoichiometric air-fuel ratio (A/F=14.7). [Reference numerals] (AA) NH_3 generation amount (ppm);(BB) Temperature ()
Abstract translation:本发明的目的是提供一种用于将氮氧化物转化为氨的催化剂及其制造方法,其中该催化剂能够在化学计量空燃比稀释的废气条件下将氮氧化物转化为氨(A / F = 14.7)。 为了达到上述目的,根据本发明的用于将氮氧化物转化为氨的催化剂包括具有贵金属的金属载体,并且能够在化学计量空燃比的稀释废气条件下将氮氧化物转化为氨(A / F = 14.7)。 (AA)NH_3产生量(ppm);(BB)温度(℃)
Abstract:
본 발명은 산화 금속 지지체에 Rh을 담지한 촉매를 적용하여 이론 공연비(A/F=14.7) 이상의 연료가 희박한 배기가스 조건에서도 질소산화물을 암모니아로 전환시킬 수 있는 질소산화물의 암모니아 전환용 촉매 및 이의 제조방법을 제공하는데 그 목적이 있다. 상기와 같은 목적을 달성하기 위해 본 발명에 따른 질소산화물의 암모니아 전환용 촉매는 귀금속이 담지된 산화 금속 지지체를 포함하여, 이론 공연비(A/F=14.7) 이상의 연료가 희박한 배기가스 조건에서도 질소산화물을 암모니아로 전환시킬 수 있도록 된 것을 특징으로 한다.
Abstract:
The present invention relates to a perovskite catalyst for NO oxidation and a manufacturing method thereof and, in particular, to a perovskite catalyst for NO oxidation and a manufacturing method thereof capable of accelerating the usage of the perovskite catalyst for NO oxidation and reducing production costs owing to the excluded use of precious metals because the perovskite catalyst for NO oxidation can be used as a main component of an aftertreatment system for reducing NOx in exhaust gas of a leanburn gasoline engine or a diesel engine by producing the perovskite catalyst including silver (Ag) having the function of NO oxidation and excellent hydrothermal stability. The perovskite catalyst for NO oxidation is the core technology of an aftertreatment system for vehicle exhaust gas which can be used for an eco-friendly low-pollution vehicle to react to environmental restrictions in the WTO system. [Reference numerals] (AA) Pt-based commercial catalyst
Abstract:
A reducing agent control device and method of the silver deposition alumina catalyst is provided to improve the fuel economy by controlling the optimum C1/NOx ratio according to temperature and spraying the reducing agent on the front of a catalyst. A reducing agent control device of the silver deposition alumina catalyst comprises a temperature and the NOx sensor(11) sensing the exhaust temperature and NOx; a controller(12) controlling amount of the reducing agent calculated through the C1/NOx ratio according to the exhaust temperature; a reducing agent tank(14) storing the reducing agent for returning the NOx to the nitrogen; a nozzle(16) spraying the reducing agent on front of the catalyst; and a flow controlling valve(19) supplying the reducing agent of the reducing agent tank to the nozzle.