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    RELEASE COMPOSITION, ARTICLES PREPARED FROM THE RELEASE COMPOSITION, AND RELATED METHODS
    2.
    发明申请
    RELEASE COMPOSITION, ARTICLES PREPARED FROM THE RELEASE COMPOSITION, AND RELATED METHODS 审中-公开

    公开(公告)号：WO2023091407A1

    公开(公告)日：2023-05-25

    申请号：PCT/US2022/049955

    申请日：2022-11-15

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： BOULOS, Marie A.

    IPC: C08G77/16 ,  C08G77/18 ,  C09D183/04 ,  C09J183/04

    Abstract: The release composition includes a siloxane polymer having a weight average molecular weight of at least 1000 grams per mole, a first crosslinker and a second crosslinker, each crosslinker independently a compound represented by formula Si(OR5)4 or R1Si(OR5)3, or a compound having at least two groups represented by formula -Si(R4)x(OR5)3-x, and a photoacid generator. The siloxane polymer includes repeating divalent units represented by formula and at least two functional groups selected from silanol, alkoxysilane, -Si(OR2)y(R")3-y, and a combination thereof. In these formulas, each R is independently alkyl, each R2 is independently hydrogen or alkyl, each R" is independently alkyl or aryl, y is 1, 2, or 3, each R4 is independently alkyl or aryl, each R1 and R5 is independently alkyl; and x is 0 or 1. An article including a cured reaction product of the release composition and a method of making the article are also described.

    ARTICLE
    3.
    发明申请
    ARTICLE 审中-公开

    公开(公告)号：WO2020201929A1

    公开(公告)日：2020-10-08

    申请号：PCT/IB2020/052814

    申请日：2020-03-25

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： PETERSON, Jeffrey A. ,  APPEANING, Maria A. ,  GERLACH, Christopher P. ,  KINNING, David J. ,  BENNETT, Madison P. ,  BOULOS, Marie A. ,  CLAUSEN, Anna M. ,  HO, Victor ,  HUSEBY, Kevin T. ,  JOHNSON, Stephen A. ,  LEBOW, Scott M.

    IPC: C09J7/50 ,  C09J7/38

    Abstract: Article comprising, in order: a first polymeric film having first and second, opposed major surfaces; a first primer layer having first and second opposed, major surfaces on the first major surface of the first polymeric film, wherein for a distance of at least 25 nm starting from the first major surface of the first 5 primer layer toward the second major surface of the first primer layer there is an average Si content, on a theoretical elemental basis, not greater than 15 atomic percent; and a first release layer having first and second opposed, major surfaces, wherein the second major surface of the first release layer is in direct contact with the first major surface of the first primer layer, wherein the first release layer comprises, on a theoretical elemental basis, Si. Articles described herein are useful, for example, as a release liner for 10 casting pressure sensitive adhesives thereon.

    RELEASE LAYERS AND ARTICLES CONTAINING THEM
    6.
    发明申请
    RELEASE LAYERS AND ARTICLES CONTAINING THEM 审中-公开

    公开(公告)号：WO2020128729A1

    公开(公告)日：2020-06-25

    申请号：PCT/IB2019/060659

    申请日：2019-12-11

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： BOULOS, Marie A. ,  RATHORE, Jitendra S. ,  APPEANING, Maria A. ,  TEVEROVSKIY, Georgiy ,  LEBOW, Scott M. ,  STEINER, Michael L. ,  TANLEY, Chris J.

    IPC: C09D183/04 ,  C09J7/40

    Abstract: Release layers that can be included in various adhesive tape products and release liners for adhesive layers are provided. The release layer is a cured reaction product of a curable release composition that contains i) a siloxane polymer having at least two hydrolyzable groups and having a weight average molecular weight of at least 1000 Daltons, ii) a crosslinker, iii) a silane additive, iv) a photoacid generator, and v) an optional silicate resin. The crosslinker is a compound of formula Si(OR 5 ) 4 or is a compound having at least two silyl groups of formula -Si(R 4 )x(OR 5 ) 3 -x where R 4 is alkyl or aryl, R 5 is alkyl, and the variable x is an integer equal to 0 or 1. The silane additive is a compound having two silyl groups of formula -Si(R 6 ) 2 (OR 7 ) or a single silyl group of formula -Si(R 10 )(OR 9 ) 2 where R 6 is alkyl or aryl, R 7 is alkyl, R 9 is alkyl, and R 10 is alkyl or aryl.

    ADHESIVE ARTICLE AND METHODS OF MAKING THE SAME
    8.
    发明申请
    ADHESIVE ARTICLE AND METHODS OF MAKING THE SAME 审中-公开

    公开(公告)号：WO2018093623A1

    公开(公告)日：2018-05-24

    申请号：PCT/US2017/060518

    申请日：2017-11-08

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： APPEANING, Maria A. ,  BOULOS, Marie A. ,  KINNING, David J. ,  TEVEROVSKIY, Georgiy ,  JARIWALA, Chetan P. ,  STEINER, Michael L. ,  VANG, Sai

    IPC: C09J7/20 ,  C09J7/40

    Abstract: A method of making an adhesive article comprises three steps. First, a backing is provided having first and second opposed major surfaces with respective first and second silicone release layers disposed thereon. The second silicone release layer further comprises organic solvent and a compound represented by the formula: R 1 represents a monovalent, divalent, or trivalent hydrocarbon radical having from 2 to 40 carbon atoms or covalent bond. R f represents a perfluorinated group having from 3 to 5 carbon atoms. X 1 represents -NH- or a covalent bond. Second, an adhesive layer is disposed onto the first silicone release layer. Third, the adhesive layer is exposed to E-beam radiation within a process chamber containing oxygen to provide a crosslinked adhesive layer. An adhesive article made by the method and the compound are also disclosed.

    TRANSFER TAPES AND RELATED METHODS
    10.
    发明申请
    TRANSFER TAPES AND RELATED METHODS 审中-公开
    传输带和相关方法

    公开(公告)号：WO2016182803A1

    公开(公告)日：2016-11-17

    申请号：PCT/US2016/030646

    申请日：2016-05-04

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： STEINER, Michael L. ,  BOULOS, Marie A. ,  APPEANING, Maria A.

    IPC: C09J7/00 ,  C09J7/02

    CPC classification number: C09J7/403 ,  C09J7/10 ,  C09J7/30 ,  C09J7/401 ,  C09J123/06 ,  C09J127/12 ,  C09J143/04 ,  C09J183/06 ,  C09J2400/24 ,  C09J2423/045 ,  C09J2427/005 ,  C09J2483/005

    Abstract: Provided are methods of making a transfer tape in which first and second release coatings are disposed onto respective first and second major surfaces of a backing to provide a release liner, the first release coating comprising wax particles at least partially embedded in a polymeric layer. An adhesive precursor is coated onto the first release coating and the adhesive precursor and the release liner collectively irradiated with an electron beam to convert the adhesive precursor into an adhesive layer. Advantageously, the provided transfer tape can be wound into a roll and stored for long periods without exhibiting degradation of release properties attributable to either blocking or electron beam degradation of the liner release coating.

    Abstract translation: 提供了制备转移带的方法，其中第一和第二剥离涂层设置在背衬的相应的第一和第二主表面上以提供剥离衬垫，第一剥离涂层包含至少部分地嵌入聚合物层中的蜡颗粒。 将粘合剂前体涂覆到第一剥离涂层上，并将粘合剂前体和释放衬片共同照射电子束以将粘合剂前体转化为粘合剂层。 有利地，所提供的转移带可以卷绕成卷并长期储存，而不会由于衬垫剥离涂层的阻塞或电子束降解而引起的剥离性能降低。

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