Abstract:
Article comprising, in order: a first polymeric film having first and second, opposed major surfaces; a first primer layer having first and second opposed, major surfaces on the first major surface of the first polymeric film, wherein for a distance of at least 25 nm starting from the first major surface of the first 5 primer layer toward the second major surface of the first primer layer there is an average Si content, on a theoretical elemental basis, not greater than 15 atomic percent; and a first release layer having first and second opposed, major surfaces, wherein the second major surface of the first release layer is in direct contact with the first major surface of the first primer layer, wherein the first release layer comprises, on a theoretical elemental basis, Si. Articles described herein are useful, for example, as a release liner for 10 casting pressure sensitive adhesives thereon.
Abstract:
A coextruded ribbon. The coextruded ribbon includes a first layer and an opposed second layer. The first layer includes a first side optionally having an adhesive thereon. The first layer further includes an opposed second side having a plurality of protrusions extending therefrom. The second layer includes a repellant material contacting the plurality of protrusions.
Abstract:
Presently described are components of a spray application system. At least one component comprises a liquid repellent surface layer. The liquid repellent surface (e.g. layer) comprises a siloxane material. The component is typically a liquid reservoir, a liquid reservoir liner, a lid for a liquid reservoir or liner, or a combination thereof. In some embodiments, the component comprises a thermoplastic polymeric material. In some favored embodiments, the component is a removable liquid reservoir or liner. In some favored embodiments, the component is a collapsible liquid reservoir or liner. The spray application system typically further comprises a gravity-fed spray gun. Also described are spray application systems, methods of using a spray application system, as well as methods of making a component of a spray application system wherein the component has a liquid repellent surface.
Abstract:
The present disclosure generally relates to adhesive compositions and articles including at least one of polydiorganosiloxane polyoxamide copolymer, silicone polyurea block copolymer, and/or an addition cure silicone, a silicate tackifying resin, and inorganic particle filler. The filler is typically fumed silica. Some embodiments of the adhesive composition include at least one of a polydiorganosiloxane polyoxamide copolymer, a silicate tackifying resin in an amount of between about 10 wt% and about 70 wt%, and inorganic particle filler in between about 0.1 wt% and about 20 wt%; a silicone polyurea block copolymer, a silicate tackifying resin in an amount of between about 10 wt% and about 70 wt%, and inorganic particle filler in an amount between about 0.1 wt% and about 20 wt%; and an addition cure silicone, a silicate tackifying resin in an amount of between about 10 wt% and about 70 wt%, and inorganic particle filler in an amount between about 0.1 wt% and about 20 wt%.
Abstract:
An adhesive article includes a pressure-sensitive adhesive layer with a release liner releasably adhered thereto. The release liner comprises a thermoplastic polymer and a first release agent represented by the formula: Each R 1 represents a hydrocarbylene group having from 2 to 40 carbon atoms; each R f independently represents a perfluorinated alkyl group of having 3 to 5 carbon atoms; and each X 1 is -NH- or a covalent bond. Methods of making the adhesive articles are also disclosed.
Abstract:
A method of making an adhesive article comprises three steps. First, a backing is provided having first and second opposed major surfaces with respective first and second silicone release layers disposed thereon. The second silicone release layer further comprises organic solvent and a compound represented by the formula: R 1 represents a monovalent, divalent, or trivalent hydrocarbon radical having from 2 to 40 carbon atoms or covalent bond. R f represents a perfluorinated group having from 3 to 5 carbon atoms. X 1 represents -NH- or a covalent bond. Second, an adhesive layer is disposed onto the first silicone release layer. Third, the adhesive layer is exposed to E-beam radiation within a process chamber containing oxygen to provide a crosslinked adhesive layer. An adhesive article made by the method and the compound are also disclosed.
Abstract:
The present invention comprises adhesive articles, adhesive compositions, and release liners. The release liners include silicone-based release formulations that can provide average and static release forces desirable for converting and handling soft adhesives, particularly adhesives of the type used in the electronics industry. In one embodiment, the silicone-based formulations include addition-cure silicone-based release formulations.
Abstract:
A coextruded ribbon. The coextruded ribbon includes a first layer and an opposed second layer. The first layer includes a first side optionally having an adhesive thereon. The first layer further includes an opposed second side having a plurality of protrusions extending therefrom. The second layer includes a repellant material contacting the plurality of protrusions.
Abstract:
A method of making an adhesive article comprises three steps. First, a backing is provided having first and second opposed major surfaces with respective first and second, silicone release layers disposed thereon. The second silicone release layer comprises an at least partially crosslinked silicone and from 5 to 20 percent by weight of inert flowable silicone. The inert flowable silicone has a number average molecular weight between 1000 grams/mole and 100,000 grams/mole. Second, an adhesive layer is disposed onto the first silicone release layer. Third, at least the adhesive layer is exposed to E-beam radiation within a process chamber thereby providing a crosslinked adhesive layer. The process chamber contains oxygen. The second silicone release layer is exposed to the oxygen during crosslinking of the adhesive layer.
Abstract:
A method of making an adhesive article comprises three steps. First, a backing is provided having first and second opposed major surfaces with respective first and second silicone release layers disposed thereon. The second silicone release layer further comprises a compound represented by the formula: R 1 represents a divalent hydrocarbon radical having from 2 to 40 carbon atoms or covalent bond. R 2 represents a monovalent or divalent poly(dimethylsiloxane) moiety. X represents -NH- or a covalent bond. R f represents a perfluorinated group having from 3 to 5 carbon atoms. y is 1 or 2. Second, an adhesive layer is disposed onto the first silicone release layer. Third, the adhesive layer is exposed to E-beam radiation within a process chamber containing oxygen to provide a crosslinked adhesive layer. An adhesive article made by the method and the compound are also disclosed.
Abstract translation:制造粘合制品的方法包括三个步骤。 首先,提供具有第一和第二相对主表面的背衬,其上设置有相应的第一和第二有机硅释放层。 第二有机硅剥离层还包含由下式表示的化合物:R 1表示具有2至40个碳原子或共价键的二价烃基。 R 2表示一价或二价聚(二甲基硅氧烷)部分。 X代表-NH-或共价键。 R f表示具有3至5个碳原子的全氟化基团。 y是1或2.第二,将粘合剂层设置在第一有机硅剥离层上。 第三,将粘合剂层暴露于含氧的处理室内的电子束辐射,以提供交联的粘合剂层。 还公开了由该方法和化合物制成的粘合剂制品。 p>