Abstract:
Ultraviolet light shielding articles are provided. An ultraviolet light shielding article includes a flexible substrate having a major surface and a multilayer optical film disposed on the major surface of the substrate. The multilayer optical film is comprised of at least a plurality of alternating first and second inorganic optical layers collectively reflecting and absorbing at an incident light angle of at least one of 0°, 15°, 30°, 45°, 60°, or 75°, an average of at least 50, 60, 70, 80, 90, or 95 percent of incident ultraviolet light over at least a 30-nanometer wavelength reflection bandwidth in a wavelength range from 190 nanometers (nm) to 400 nm. Solar cell covers including an ultraviolet shielding articles are also provided.
Abstract:
Barrier films including a (co)polymeric substrate, at least one dyad on the substrate, each dyad made of a (co)polymer layer and an oxide layer overlaying the (co)polymer layer, and an outer (co)polymer layer overlaying the dyads. Optionally, at least one outer oxide layer overlays the outer (co)polymer layer. The barrier films transmit visible light and transmits, at an incident light angle of at least one of 0°, 30°, 45°, 60°, or 75°, at most 70 percent of incident ultraviolet light at a wavelength range from at least 100 nanometers to 400 nanometers or in a wavelength range from at least 100 nm to 350 nm. The barrier films exhibit atomic oxygen degradation of less than 1×10−20 mg/atom. The barrier films may be applied to decorative objects or electronic devices, (e.g., light receiving or emitting devices, in a satellite or aircraft. Methods of making the barrier films also are disclosed.
Abstract:
A solar cell assembly is described that comprises a barrier assembly disposed on or around a photovoltaic cell, wherein the barrier assembly comprises a barrier film and a polyurethane outer protective film layer bonded directly to exposed major surface of the barrier film, wherein the barrier assembly disposed above the photovoltaic cell and the polyurethane outer protective film layer forms a top surface of the solar cell assembly that is exposed to incoming light.
Abstract:
A solar cell is described that comprises a transparent conductor sheet having a polymeric substrate with an embedded metal grid, disposed within microchannels extending partially through a thickness of polymeric substrate from a first surface of the polymeric substrate; and a photoactive layer disposed adjacent to the first surface of the polymeric substrate. The transparent conductor sheet has a sheet resistance less than 1 Ω/□ and an average solar direct transmittance over the visible and infrared portion of the spectrum of at least about 80%.
Abstract:
A first transport system moves a web comprising a subgasketed CCM layer and an application system applies a crosslinkable resin to at least a subgasketed portion of the subgasketed CCM layer. The crosslinkable resin preferably comprises a photocurable cationic crosslinkable resin. A first curing apparatus subjects an exposed surface of the crosslinkable resin to a photo curing process to initiate curing of the crosslinkable resin. A second transport system moves a GDL into adhering contact with a partially cured exposed surface of the crosslinkable resin of the CCM layer so as to form an MEA layer. A second curing apparatus subjects the GDL, partially cured crosslinkable resin, and CCM layer structure to a thermal curing process to substantially complete curing of the crosslinkable resin. A converting system is configured to receive the MEA layer and produce a plurality of discrete MEAs from the MEA layer.
Abstract:
A fuel cell roll good subassembly is described that includes a plurality of individual electrolyte membranes. One or more first subgaskets are attached to the individual electrolyte membranes. Each of the first subgaskets has at least one aperture and the first subgaskets are arranged so the center regions of the individual electrolyte membranes are exposed through the apertures of the first subgaskets. A second subgasket comprises a web having a plurality of apertures. The second subgasket web is attached to the one or more first subgaskets so the center regions of the individual electrolyte membranes are exposed through the apertures of the second subgasket web. The second subgasket web may have little or no adhesive on the subgasket surface facing the electrolyte membrane.
Abstract:
A fuel cell roll good subassembly is described that includes a plurality of individual electrolyte membranes. One or more first subgaskets are attached to the individual electrolyte membranes. Each of the first subgaskets has at least one aperture and the first subgaskets are arranged so the center regions of the individual electrolyte membranes are exposed through the apertures of the first subgaskets. A second subgasket comprises a web having a plurality of apertures. The second subgasket web is attached to the one or more first subgaskets so the center regions of the individual electrolyte membranes are exposed through the apertures of the second subgasket web. The second subgasket web may have little or no adhesive on the subgasket surface facing the electrolyte membrane.
Abstract:
The present disclosure relates to electrode assemblies, membrane-electrode assemblies and electrochemical cells and liquid flow batteries produced therefrom. The electrode and membrane-electrode assemblies include (i) a porous electrode having a first major surface with a first surface area, Ae, an opposed second major surface and a plurality of voids; (ii) a discontinuous transport protection layer, comprising polymer, disposed on the first major surface and having a cross-sectional area, Ap, substantially parallel to the first major surface; and (iii) an interfacial region wherein the interfacial region includes a portion of the polymer embedded in at least a portion of the plurality of voids, a portion of the porous electrode embedded in a portion of the polymer or a combination thereof; and wherein 0.02Ae≤Ap≤0.85Ae and the porous electrode and discontinuous transport protection layer form an integral structure. The disclosure further provides methods of making the electrode assemblies and membrane-electrode assemblies.
Abstract:
An article comprising a first gas distribution layer (100), a first gas dispersion layer (200), or a first electrode layer, having first and second opposed major surfaces and a first adhesive layer having first and second opposed major surfaces, wherein the second major surface (102) of the first gas distribution layer (100), the second major surface (202) of the first gas dispersion layer (200), or the first major surface of the first electrode layer, as applicable, has a central area, wherein the first major surface of the first adhesive layer contacts at least the central area of the second major surface of the first gas distribution layer, the second major surface of the first gas dispersion layer, or the first major surface of the first electrode layer, as applicable, and wherein the first adhesive layer comprises a porous network of first adhesive including a continuous pore network extending between the first and second major surfaces of the first adhesive layer. The articles described herein are useful, for example, in membrane electrode assemblies, unitized electrode assemblies, and electrochemical devices (e.g., fuel cells, redox flow batteries, and electrolyzers).
Abstract:
A fuel cell membrane electrode assembly is provided comprising a polymer electrolyte membrane comprising a first polymer electrolyte and at least one manganese compound; and one or more electrode layers comprising a catalyst and at least one cerium compound. The membrane electrode assembly demonstrates an unexpected combination of durability and performance.