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    ELECTRODE INKS CONTAINING COALESCING SOLVENTS
    4.
    发明申请
    ELECTRODE INKS CONTAINING COALESCING SOLVENTS 审中-公开
    含电解溶剂的电极墨水

    公开(公告)号：WO2009086364A1

    公开(公告)日：2009-07-09

    申请号：PCT/US2008/088145

    申请日：2008-12-23

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： HICKS, Michael T. ,  HAMROCK, Steven J. ,  HANSON, Eric J. ,  WATSCHKE, Theresa M. ,  SCHABERG, Mark S.

    IPC: H01M8/10

    CPC classification number: H01M8/1004 ,  H01M4/8828 ,  Y02P70/56

    Abstract: A catalyst ink is provided comprising: a) solids, comprising: i) a catalyst material, and ii) a polymer electrolyte; b) an aqueous solvent; and c) a coalescing solvent. In some embodiments, the coalescing solvent is selected from the group consisting of alkanes, alkenes, amines, ethers, and aromatic compounds which may optionally be substituted. In some embodiments, the coalescing solvent is selected from the group consisting of partially fluorinated alkanes, partially fluorinated tertiary amines, fully fluorinated alkanes and fully fluorinated tertiary amines. In another aspect, the present disclosure provides a fuel cell membrane electrode assembly comprising a catalyst layer comprising a coalescing solvent. In another aspect, the present disclosure provides a method of making a fuel cell membrane electrode assembly comprising a step of applying a catalyst ink according to the present disclosure to one or more of: a) a polymer electrolyte membrane, and b) a porous, electrically conductive gas diffusion layer.

    Abstract translation: 提供了一种催化剂油墨，其包括：a）固体，包括：i）催化剂材料，和ii）聚合物电解质; b）水性溶剂; 和c）聚结溶剂。 在一些实施方案中，聚结溶剂选自可任选被取代的烷烃，烯烃，胺，醚和芳族化合物。 在一些实施方案中，聚结溶剂选自部分氟化的烷烃，部分氟化的叔胺，完全氟化的烷烃和完全氟化的叔胺。 在另一方面，本公开提供了一种燃料电池膜电极组件，其包括包含聚结溶剂的催化剂层。 另一方面，本公开内容提供了制造燃料电池膜电极组件的方法，其包括将根据本公开的催化剂油墨施加到以下中的一种或多种的步骤：a）聚合物电解质膜，以及b）多孔， 导电气体扩散层。

    POLYMER ELECTROLYTE MEMBRANES CROSSLINKED BY NITRILE TRIMERIZATION
    7.
    发明申请
    POLYMER ELECTROLYTE MEMBRANES CROSSLINKED BY NITRILE TRIMERIZATION 审中-公开
    聚合物电解质膜由NITRILE TRIMERIZATION交联

    公开(公告)号：WO2005052040A1

    公开(公告)日：2005-06-09

    申请号：PCT/US2004/033808

    申请日：2004-10-13

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： YANDRASITS, Michael A. ,  HAMROCK, Steven J. ,  GROOTAERT, Werner M., A. ,  GUERRA, Miguel A. ,  JING, Naiyong

    IPC: C08J5/22

    CPC classification number: C08J5/225 ,  C08J2327/12

    Abstract: A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, by trimerization of nitrile groups contained on groups pendant from the polymer. The resulting polymer electrolyte membrane comprises a highly fluorinated polymer comprising: a perfluorinated backbone, first pendent groups which comprise sulfonic acid groups, and crosslinks comprising trivalent groups according to the formula I The first pendent groups are typically according to the formula: -R 1 -SO 3 H, where R 1 is a branched or unbranched perfluoroalkyl or perfluoroether group comprising 1-15 carbon atoms and 0-4 oxygen atoms, most typically -O-CF 2 -CF 2 -CF 2 -CF 2 -SO 3 H or O-CF 2 -CF(CF 3 )-O-CF 2 -CF 2 SO 3 H.

    Abstract translation: 提供了一种制备交联聚合物电解质的方法，通常是通过聚合物悬浮在基团上的腈基的三聚作用将聚合物电解质通常用作电解池如燃料电池中的聚合物电解质膜。 所得的聚合物电解质膜包括高度氟化的聚合物，其包含：全氟化骨架，包含磺酸基团的第一侧基和包含根据式I的三价基团的交联。第一侧基通常根据下式：-R 1 > -SO 3 H，其中R 1是包含1-15个碳原子和0-4个氧原子的支链或非支链全氟烷基或全氟醚基团，最典型的是-O-CF2-CF2-CF2-CF2-SO3H或O-CF2- CF（CF 3）-O-CF 2 -CF 2 SO 3 H.

    IONIC POLYMER MEMBRANE FOR A CARBON DIOXIDE ELECTROLYZER
    8.
    发明申请
    IONIC POLYMER MEMBRANE FOR A CARBON DIOXIDE ELECTROLYZER 审中-公开
    用于二氧化碳电解液的离子聚合物膜

    公开(公告)号：WO2016039999A1

    公开(公告)日：2016-03-17

    申请号：PCT/US2015/047198

    申请日：2015-08-27

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： MATTHEWS, Tyler S. ,  HAMROCK, Steven J. ,  KAPLUN, Marina M. ,  LEWINSKI, Krzysztof A. ,  LUOPA, Sean M.

    IPC: C25B13/00 ,  C25B13/04 ,  C25B13/08 ,  C25B1/00 ,  C25B11/04

    CPC classification number: C25B13/08 ,  B01J41/13 ,  C08J5/2231 ,  C08J2339/04 ,  C25B1/00 ,  C25B3/04 ,  C25B9/08 ,  C25B13/02

    Abstract: Described herein is a process for the reduction of carbon dioxide comprising: providing an electrochemical device comprising an anode, a cathode, and a polymeric anion exchange membrane therebetween, wherein the polymeric anion exchange membrane comprises an anion exchange polymer, wherein the anion exchange polymer comprises at least one positively charged group selected from a guanidinium, a guanidinium derivative, an N-alkyl conjugated heterocyclic cation, or combinations thereof; introducing a composition comprising carbon dioxide to the cathode; and applying electrical energy to the electrochemical device to effect electrochemical reduction of the carbon dioxide.

    Abstract translation: 本文描述的是减少二氧化碳的方法，包括：提供包括阳极，阴极和其间的聚合阴离子交换膜的电化学装置，其中所述聚合阴离子交换膜包含阴离子交换聚合物，其中所述阴离子交换聚合物包含 至少一种选自胍，胍衍生物，N-烷基共轭杂环阳离子或其组合的带正电基团; 将包含二氧化碳的组合物引入阴极; 并向电化学装置施加电能以实现二氧化碳的电化学还原。

    FUEL CELL ELECTRODES WITH CONDUCTION NETWORKS
    9.
    发明申请
    FUEL CELL ELECTRODES WITH CONDUCTION NETWORKS 审中-公开
    具有导电网络的燃料电池电极

    公开(公告)号：WO2012009142A1

    公开(公告)日：2012-01-19

    申请号：PCT/US2011/041937

    申请日：2011-06-27

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： HAUG, Andrew T. ,  HAMROCK, Steven J. ,  HAUGEN, Gregory M. ,  SCHONEWILL, Mark A.

    IPC: H01M4/86 ,  H01M4/88

    CPC classification number: H01M8/1044 ,  H01M4/8652 ,  H01M4/8668 ,  H01M4/8673 ,  H01M4/8828 ,  H01M4/886 ,  H01M4/9075 ,  H01M8/1004 ,  H01M8/1067 ,  H01M2008/1095 ,  H01M2300/0082 ,  H01M2300/0091 ,  Y02E60/521

    Abstract: A fuel cell electrode layer may include a catalyst, an electronic conductor, and an ionic conductor. Within the electrode layer are a plurality of electronic conductor rich networks and a plurality of ionic conductor rich networks that are interspersed with the electronic conductor rich networks. A volume ratio of the ionic conductor to the electronic conductor is greater in the ionic conductor rich networks than in the electronic conductor rich networks. During operation of a fuel cell that includes the electrode layer, conduction of electrons occurs predominantly within the electronic conductor rich networks and conduction of ions occurs predominantly within the ionic conductor rich networks.

    Abstract translation: 燃料电池电极层可以包括催化剂，电子导体和离子导体。 在电极层内是多个电子导体富集网络和多个富含离子导体的网络，它们与电子导体富集网络分散。 在离子导体富集网络中，离子导体与电子导体的体积比大于电子导体富集网络中的体积比。 在包括电极层的燃料电池的操作期间，电子传导主要在电子导体富集网络内，并且离子的传导主要发生在离子导体富集网络内。

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