Abstract:
The polymerizable compound of the present invention is represented by general formula (1) below and can provide a composition that is polymerizable near ambient temperature and exists in a liquid crystal phase at low temperatures. The composition and a (co)polymer of the polymerizable compound of the present invention are liquid crystal substances useful as optically anisotropic materials. (In the formula, each of rings A 1 to A 3 represents a benzene ring, cyclohexane ring, etc.; each of X to Z represents a C 1-8 alkyl or alkoxy group, C 2-6 alkenyl group, halogen atom, cyano group, or CH 2 =CR 3 -COO-; each of R 1 to R 3 represents a hydrogen atom, methyl group, or halogen atom; each of L 1 to L 3 represents -CH 2 CH 2 COO-, -COO-, -OCO-, -CH 2 CH 2 -, -O(CH 2 ) f - (herein, f = 1-8), etc.; n represents 0 or 1; and a to c represent such numbers that the polymerizable compound has at least one or more of any of X, Y, and Z.)
Abstract:
A polymerizable compound represented by the following general formula (1). It can provide a composition which is polymerizable at around room temperature and shows a liquid-crystal phase at low temperatures. The composition and a (co)polymer of the polymerizable compound are a liquid-crystal substance useful as an optically anisotropic object. (In the formula, rings A1 to A3 each represents a benzene ring, cyclohexane ring, etc.; X to Z each represents C1-8 alkyl or alkoxy, C2-6 alkenyl, halogeno, cyano, or CH2=CR3-COO-; R1 to R3 each represents hydrogen, methyl, or halogeno; L1 to L3 each represents -CH2CH2COO-, -COO-, -OCO-, -CH2CH2-, -O(CH2)f- (wherein f is 1 to 8), etc.; n is 0 or 1; and a to c are such numbers that the polymerizable compound has one or more substituents which are at least any one of X, Y, and Z.)
Abstract:
PROBLEM TO BE SOLVED: To provide a polymer obtained by photo-curing a polymerizable composition, and to provide a polymerizable composition giving a polymer which is excellent in heat resistance, orientation control and optical characteristics, and maintains a uniform film state, even when the polymer is processed into a thin film. SOLUTION: This polymerizable compound represented by general formula (1) [A is a ring aggregate comprising at least two six-membered rings; each six-membered ring may have one or more substituents; X 1 and X 2 are each (meth)acryloyloxy; Y 1 and Y 2 are each independently a single bond, a 1 to 8C alkylene which may be branched, an ether bond, -COO-, -OCO-, a six-membered ring which may have one or more substituents, a naphthalene ring which may have one or more substituents, or their combination]. COPYRIGHT: (C)2008,JPO&INPIT
Abstract translation:解决问题的方法为了提供通过光聚合组合物的光固化而得到的聚合物,并且提供一种聚合物,其具有优异的耐热性,取向控制和光学特性并保持均匀的膜状态, 即使将聚合物加工成薄膜也是如此。 解决方案:由通式(1)表示的可聚合化合物[A是包含至少两个六元环的环骨料; 每个六元环可以具有一个或多个取代基; X 1 SB>和X 2 SB>分别为(甲基)丙烯酰氧基; Y 1 SB>和Y 2 SB>各自独立地是单键,可以是支链的1至8个亚烷基,醚键,-COO-,-OCO-,六 可以具有一个或多个取代基的萘环,可以具有一个或多个取代基的萘环或它们的组合]。 版权所有(C)2008,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a polymerizable liquid crystal compound exhibiting a liquid crystal phase at room temperature without precipitating a crystal even having high optical anisotropy, having excellent solubility in an organic solvent, excellent coatability and excellent orienting properties, and providing excellent transparency after polymerization; and to provide homo- and co-polymers of the polymerizable liquid crystal compound. SOLUTION: The polymerizable liquid crystal compound is represented by general formula (1) [wherein, R 1 and R 2 are each a hydrogen atom, a methyl group or a halogen atom; rings A to C are each a benzene ring, a naphthalene ring or the like, with the proviso that at least one of the rings A to C is a condensed ring; X to Z are each a 1-6C alkyl group or the like; L 1 to L 3 are each -COO-, -OCO-, -O(CH 2 ) j - (j is 1-8), or the like; n is 0 or 1; (a) to (c) are each a number showing that at least one of X, Y and Z is present in the polymerizable liquid crystal compound]. COPYRIGHT: (C)2007,JPO&INPIT