公开(公告)号：US20240317967A1

公开(公告)日：2024-09-26

申请号：US18262521

申请日：2022-01-25

Applicant: ADEKA CORPORATION

Inventor： Takeshi ENDO ,  Yasuyuki MORI ,  Ken-ichi TAMASO ,  Ryo OGAWA ,  Junji UEYAMA

IPC: C08K5/3415 ,  C08G59/50

CPC classification number: C08K5/3415 ,  C08G59/5073

Abstract: A curing resin composition well balanced in curing properties and storage stability. The composition contains (A) an epoxy resin, (B) a curing agent, and (C) at least one of imide compounds represented by formulae (1-1), (1-2), and (1-3), wherein R11 represents an optionally substituted alkyl group with 1 to 10 carbon atoms, etc.; R1, R2, R3, and R4 each independently represent a hydrogen atom, an alkyl group with 1 to 10 carbon atoms, etc.; and R12 and R13 each independently represent a hydrogen atom, an optionally substituted alkyl group with 1 to 10 carbon atoms, etc.

公开(公告)号：US20180037014A1

公开(公告)日：2018-02-08

申请号：US15547090

申请日：2016-01-26

Applicant: ADEKA CORPORATION

Inventor： Takeshi ENDO ,  Kozo MATSUMOTO ,  Ken-ichi TAMASO ,  Chihiro ASAKURA ,  Ryo OGAWA

IPC: B32B27/38 ,  C08L63/00 ,  C08G59/40 ,  C08K5/5313 ,  B32B27/26 ,  C08K5/00

Abstract: A flame-retardant epoxy resin composition wherein (A) epoxy resin, (B) a curing agent and (C) a phosphorous-containing compound expressed by the following general formula (1) are contained; a prepreg using the same and a laminated plate using said prepreg; wherein m expresses an integer from 2 to 10, R1 and R2 each independently express an alkyl group or an aryl group, R3 expresses a hydrocarbon group that may contain an oxygen atom, a sulfur atom or a nitrogen atom, X expresses an oxygen atom or a sulfur atom, Y expresses an oxygen atom, a sulfur atom or —NR4—, and in this regard, R4 expresses a hydrogen atom, an alkyl group or an aryl group.

公开(公告)号：US20250109240A1

公开(公告)日：2025-04-03

申请号：US18834870

申请日：2023-03-03

Applicant: ADEKA CORPORATION

Inventor： Takuya MIWA ,  Yui HASEGAWA ,  Ken-ichi TAMASO

IPC: C08G59/22 ,  C08G59/50 ,  C09J163/00

Abstract: An objective of the present invention is to provide an epoxy resin composition containing a reactive diluent capable of reducing viscosity while maintaining the epoxy resin's original properties as much as possible, and also capable of imparting novel additional effects such as adhesiveness, storage stability, etc. The invention relates to a one-pack type epoxy resin composition containing: component (A): a compound represented by general formula (1); component (B): an epoxy resin; and component (C): an amine-based curing agent. In the general formula (1), R1 represents a hydrogen atom or a methyl group; R2 and R3 each independently represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms; and n represents an integer of 1 to 3.

公开(公告)号：US20240409681A1

公开(公告)日：2024-12-12

申请号：US18698296

申请日：2022-10-17

Applicant: ADEKA CORPORATION

Inventor： Shota KOBAYASHI ,  Ken-ichi TAMASO

IPC: C08G59/62 ,  C08G59/40 ,  C08K5/13 ,  C08K5/3445

Abstract: A clathrate compound obtained by mixing an imidazole compound (A) and a polyhydric phenol compound (B), wherein the clathrate compound has an average particle size (X) of 7 μm or less, and a maximum particle size (Y) of 40 μm or less. The imidazole compound (A) is preferably at least one selected from compounds represented by the following formula (1), where R1, R2, R3, and R4 each independently represent a hydrogen atom, an alkyl group that has 1 to 20 carbon atoms and may have a substituent, or an aryl group that has 6 to 20 carbon atoms and may have a substituent, and the substituent is at least one selected from a halogen atom, a hydroxy group, and a nitrile group.

公开(公告)号：US20240301128A1

公开(公告)日：2024-09-12

申请号：US18565337

申请日：2022-06-22

Applicant: ADEKA CORPORATION

Inventor： Sho SUZUKI ,  Ippei OKANO ,  Ken-ichi TAMASO

IPC: C08G59/22 ,  C08G59/24 ,  C08G59/50 ,  C08G59/66

CPC classification number: C08G59/223 ,  C08G59/245 ,  C08G59/50 ,  C08G59/66

Abstract: An epoxy material that provides a cured product having a reduced modulus of elasticity and thereby maintaining reliability even under conditions of wide environmental variation. The epoxy resin composition provided includes (A) an epoxy compound A of formula (1) below, (B) phenyl glycidyl ether substituted with a C6-20 hydrocarbon group, and (C) a curing agent. In formula (1), R1 and R2 each independently represent C2-4 alkylene; R3 represents methylene or —C(CH3)2—; and a and b each independently represent a number of 1 to 10.

公开(公告)号：US20220185946A1

公开(公告)日：2022-06-16

申请号：US17436498

申请日：2020-03-27

Applicant: ADEKA CORPORATION

Inventor： Shota KOBAYASHI ,  Ken-ichi TAMASO ,  Ryo OGAWA ,  Tamotsu NAGAMATSU

IPC: C08G59/24 ,  C08G59/40 ,  C08G59/56 ,  C08G59/66 ,  C08G59/68 ,  B29C71/02 ,  C08J7/12

Abstract: Disclosed is a curable resin composition that has excellent curability by irradiation of light and heating and that is suitable for such applications as liquid encapsulants, liquid adhesives, adhesives for camera modules, and liquid crystal sealants. The curable resin composition contains (A) an aromatic epoxy resin having an allyl group, (B) a thiol-based curing agent, (C) a photoradical initiator, and (D) a thermally latent curing agent. Preferably, (A) the compound having an allyl group and an epoxy group is an aromatic epoxy resin having an allyl group. Preferably, the thiol-based curing agent, which is component (B), is in liquid form at 25° C.

公开(公告)号：US20240084065A1

公开(公告)日：2024-03-14

申请号：US18260554

申请日：2022-01-25

Applicant: ADEKA CORPORATION

Inventor： Ken-ichi TAMASO

IPC: C08F283/10 ,  C07D405/12 ,  C08G59/14

CPC classification number: C08F283/10 ,  C07D405/12 ,  C08G59/145

Abstract: An objective of the invention is to provide a material capable of obtaining a curable resin composition having an excellent balance between curability and storage stability. The invention is a compound represented by formula (1).




In the formula, R1 to R4 each independently represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, a halogen atom, a hydroxy group, a nitro group, or a nitrile group; R5 to R7 each independently represent a hydrogen atom or a methyl group; and ring A represents (a1) or (a2) and forms a fused ring with the imide ring at *.

公开(公告)号：US20180051167A1

公开(公告)日：2018-02-22

申请号：US15560773

申请日：2016-03-22

Applicant: ADEKA CORPORATION

Inventor： Takeshi ENDO ,  Kozo MATSUMOTO ,  Ken-ichi TAMASO ,  Chihiro ASAKURA ,  Ryo OGAWA

IPC: C08L63/00 ,  C08J5/24 ,  C08K5/5399 ,  C08K5/00

CPC classification number: C08L63/00 ,  C08J5/24 ,  C08K5/0066 ,  C08K5/5399 ,  C08L2201/02

Abstract: An epoxy resin composition comprising an epoxy resin (A), a curing agent (B) and a phosphorous-containing compound (C) indicated by the following general formula (1) and also, if necessary, a flame retardant (D), and a laminated plate comprising said resin composition; wherein m indicates an integer from 2 to 10, R1 to R4 each independently indicate a hydrogen atom, an alkyl group or an aryl group, R5 indicates a hydrocarbon group that may contain an oxygen atom, a sulfur atom or a nitrogen atom, X indicates an oxygen atom or a sulfur atom, Y indicates an oxygen atom, a sulfur atom or —NR6—, and R6 indicates a hydrogen atom, an alkyl group or an aryl group.

公开(公告)号：US20160200747A1

公开(公告)日：2016-07-14

申请号：US14915766

申请日：2014-11-10

Applicant: ADEKA CORPORATION

Inventor： Takeshi ENDO ,  Kozo MATSUMOTO ,  Ken-ichi TAMASO ,  Ryo OGAWA

IPC: C07F9/24 ,  C08G59/40 ,  C08G59/44

CPC classification number: C07F9/242 ,  C07F9/224 ,  C07F9/2404 ,  C07F9/2458 ,  C08G59/1488 ,  C08G59/4071 ,  C08G59/446

Abstract: Provided is a novel phosphorus-containing compound represented by general formula (I). The compound has reactivity with a glycidyl group and is therefore capable of providing a curing epoxy resin composition that is expected to achieve flame retardation and reduction of dielectric constant. wherein m is a number of 1 to 10; R1, R2, R3, and R4 are each hydrogen, alkyl, or aryl; R5 is alkyl, alkanediyl, alkanetriyl, alkanetetrayl, or an aromatic group; X is oxygen or sulfur; Y is oxygen, sulfur, or ═NR′; and R′ is hydrogen, alkyl, or aryl.

Abstract translation: 提供通式（I）表示的新型含磷化合物。 该化合物与缩水甘油基具有反应性，因此能够提供期待实现阻燃和降低介电常数的固化环氧树脂组合物。 其中m为1至10的数; R 1，R 2，R 3和R 4各自为氢，烷基或芳基; R5是烷基，烷二基，链烷三基，烷基乙基或芳基; X是氧或硫; Y是氧，硫或= NRR; 和R'是氢，烷基或芳基。

公开(公告)号：US20160152643A1

公开(公告)日：2016-06-02

申请号：US14900844

申请日：2014-08-21

Applicant: ADEKA CORPORATION

Inventor： Takeshi ENDO ,  Kozo MATSUMOTO ,  Ken-ichi TAMASO ,  Ryo OGAWA

IPC: C07F9/32

CPC classification number: C07F9/3282 ,  C07F9/3264 ,  C07F9/36 ,  C08K5/5313 ,  C08L63/00 ,  C09K21/12 ,  C09K21/14

Abstract: The purpose of the present invention is to provide a phosphorus-containing compound having reactivity with a glycidyl group, specifically a phosphorus-containing compound represented by general formula (I). (In the formula, m represents a numerical value of 1 to 10; R1 and R2 independently represent a hydrogen atom, an alkyl group or an aryl group; R3 represents an alkyl group, an alkanediyl group, an alkanetriyl group, an alkanetetrayl group or an aromatic group; X represents an oxygen atom or a sulfur atom; Y represents an oxygen atom, a sulfur atom or —NR4—; and R4 represents a hydrogen atom, an alkyl group or an aryl group.)

Abstract translation: 本发明的目的是提供一种与缩水甘油基具有反应性的含磷化合物，特别是由通式（I）表示的含磷化合物。 （式中，m表示1〜10的数值，R 1和R 2分别表示氢原子，烷基或芳基，R 3表示烷基，烷二基，烷三甲酰基，烷基四氟乙基， 芳基; X表示氧原子或硫原子; Y表示氧原子，硫原子或-NR4-，R4表示氢原子，烷基或芳基）。