公开(公告)号：US3427120A

公开(公告)日：1969-02-11

申请号：US3427120D

申请日：1963-12-17

Applicant: AGENCY IND SCIENCE TECHN

Inventor： SHINDO AKIO ,  FUJII ROKURO ,  SOUMA ISAO

IPC: D01F9/21 ,  C01B31/07 ,  C23C9/08

CPC classification number: D01F9/21 ,  Y10S264/19

公开(公告)号：DE1246510B

公开(公告)日：1967-08-03

申请号：DEA0044866

申请日：1963-12-21

Applicant: AGENCY IND SCIENCE TECHN

Inventor： SHINDO AKIO ,  FUJII ROKURO ,  SOUMA ISAO

IPC: C04B35/524 ,  D01F9/21 ,  C01B31/07

公开(公告)号：JPH03164415A

公开(公告)日：1991-07-16

申请号：JP30384889

申请日：1989-11-22

Applicant: AGENCY IND SCIENCE TECHN ,  SHIKISHIMA CANVAS KK

Inventor： IKEDA SHIGERU ,  ADACHI MASAKAZU ,  SHIOYAMA HIROSHI ,  TATSUMI KUNIAKI ,  FUJII ROKURO ,  TANAMURA TAKESHI

IPC: C04B35/83 ,  C01B31/02 ,  C04B35/52 ,  D01F9/12 ,  D03D25/00 ,  D04H3/07

Abstract: PURPOSE:To produce a high strength three-dimensional fabric C-C composite capable of freely controlling the direction of heat conductivity by impregnating a carbon source into a three-dimensional fabric of carbon fibers having anisotropic heat conductivity as a reinforcing material and burning the carbon source. CONSTITUTION:A three-dimensional fabric of carbon fibers having arbitrary anisotropic heat conductivity is formed by using carbon fibers made from polyacrylonitrile, pitch, etc., and changing the constitution, orientation ratio and content. A carbon source is impregnated into the fabric, carbonized and graphitized by burning. Pitch, gaseous hydrocarbon or phenol resin may be used as the carbon source. The graphitizing temp. is properly selected within the range of about 1,200-3,000 deg.C. A C-C composite having superior mechanical strength and capable of freely controlling the direction of heat conductivity is obtd.

公开(公告)号：JPH01229874A

公开(公告)日：1989-09-13

申请号：JP5023488

申请日：1988-03-02

Applicant: AGENCY IND SCIENCE TECHN ,  SHIKISHIMA CANVAS KK

Inventor： IKEDA SHIGERU ,  SHIOYAMA HIROSHI ,  HORI SHOJI ,  ADACHI MASAKAZU ,  FUJII ROKURO ,  TANAMURA TAKESHI

IPC: D06M11/00 ,  C04B30/02 ,  D02G3/36 ,  D03D15/00 ,  D04B1/16 ,  D06M11/77 ,  D06M101/00 ,  D06M101/40

Abstract: PURPOSE:To improve physical properties such as antioxidation and mechanical strength of woven cloth by forming a silicon and/or silicon carbide coating film layer on the surface of yarn of woven and knitted cloth consisting of carbon fiber. CONSTITUTION:Woven and knitted cloth consisting of carbon fiber is maintained in vapor of silicon and/or silicon carbide, then heat-treated at 1,300-2,600 deg.C and the carbon fiber yarn is silicified to give the aimed woven and knitted cloth. For example, first Si is piled on the surface of the carbon fiber yarn and reacted with the carbon fiber yarn by the successive heat treatment to form an interfacial layer consisting of SiC between Si and C (type I). Coating films of types II, III and IV are formed by heating condition, heat-treating condition and retention time thereof. Physical properties of the woven and knitted cloth consisting of the silicon-carbon conjugated fiber thus obtained are improved and the woven and knitted cloth is useful as a reinforcing base material of composite material obtained by combining the woven and knitted cloth with ceramic (glass, etc.), metal (aluminum, etc.), etc.

公开(公告)号：JPS62246888A

公开(公告)日：1987-10-28

申请号：JP4340486

申请日：1986-02-27

Applicant: AGENCY IND SCIENCE TECHN

Inventor： IKEDA SHIGERU ,  HORI SHOJI ,  OTSUKI SHINICHI ,  EGUCHI KIYOHISA ,  FUJII ROKURO

IPC: C04B41/87 ,  C04B41/85

公开(公告)号：JPH0388705A

公开(公告)日：1991-04-15

申请号：JP22624289

申请日：1989-08-30

Applicant: AGENCY IND SCIENCE TECHN

Inventor： TATSUMI KUNIAKI ,  SHIOYAMA HIROSHI ,  FUJII ROKURO

IPC: C01B31/00 ,  C01B31/04 ,  C25D11/02

Abstract: PURPOSE:To obtain the graphite multiple intercalation compd. having high conductivity in a short reaction time by allowing graphite to react with a metal chloride in a sealed tube and anodizing the obtained intercalation compd. in perchloric acid with the compd. as a working electrode and platinum as the counter electrode. CONSTITUTION:Graphite is allowed to react with a metal chloride in an evacuated sealed tube to form an (n)th-stage graphite intercalation compd. (n=2, 3). The compd. is then anodized in perchloric acid with the compd. as a working electrode and platinum as the counter electrode to intercalate the perchloric acid into the void between the graphite layers, and the desired graphite multiple intercalation compd. is obtained. The compd. is shown by the formula (x is 7-9 and y is 0.8-1.2 when z=1). The chlorides of transition metals such as iron chloride, aluminum chloride and bismuth chloride are used as the metal chloride. Bismuth chloride is most preferably used.