公开(公告)号：CA1111827A

公开(公告)日：1981-11-03

申请号：CA297750

申请日：1978-02-27

Applicant: AGENCY IND SCIENCE TECHN

Inventor： SATO TOSHIO ,  OHKOSHI SUMIO ,  TAKAHASHI TOMIKI ,  SASAMORI MASATAKA

IPC: B01D59/32 ,  B01J31/06 ,  B01J31/28 ,  B01J33/00 ,  C01B4/00

Abstract: Disclosed is a catalyst for hydrogen isotopic exchange in water-hydrogen system, which utilizes as a metal carrier a porous styrene-divinyl benzene copolymer and which has a sufficient catalytic activity for manufacture of heavy water from natural water and removal of tritium from heavy water in an industrial scale.

公开(公告)号：DE2411888A1

公开(公告)日：1974-09-26

申请号：DE2411888

申请日：1974-03-12

Applicant: AGENCY IND SCIENCE TECHN

Inventor： TODO NAOYUKI ,  SATO TOSHIO ,  SUGI YOSHIHIRO

IPC: B01D53/86 ,  B01D53/94 ,  B01J23/00 ,  B01J23/70 ,  B01J23/72 ,  B01J23/86 ,  B01J37/20 ,  B01D53/34 ,  B01D53/00 ,  F01N3/14

Abstract: Catalyst for ren. of N oxides is industrial combustion gases with gaseous ammonia is selected from CuO and Fe2O3 and can be combined with an active alumina carrying Cr2O3. The catalyst system is pref. preliminarily treated with N2 or air contg. 50-2000 ppm SO2 at 200-450 degrees C, whereby the redn. of catalytic activity caused by moisture is eliminated (alternatively, the effluent gases may contain 50-1400 ppm SO2). The catalytic activity is stabe even at high temps. This catalyst system is cheaper than prior art systems.

公开(公告)号：JPH01203041A

公开(公告)日：1989-08-15

申请号：JP2592288

申请日：1988-02-05

Applicant: AGENCY IND SCIENCE TECHN

Inventor： SATO TOSHIO ,  MATSUBAYASHI NOBUYUKI ,  SHIMADA HIROMICHI ,  YOSHIMURA YUJI ,  NISHIJIMA AKIO ,  KANZAKI SHUZO ,  SHIBAZAKI YASUO

IPC: B01J21/10 ,  B01J23/74 ,  B01J23/75 ,  B01J23/85 ,  B01J23/88 ,  B01J32/00 ,  C07B61/00 ,  C07C1/00 ,  C07C4/18 ,  C07C5/11 ,  C07C13/38 ,  C07C13/48 ,  C07C15/04 ,  C07C15/06 ,  C07C67/00 ,  C10G45/02 ,  C10G45/04 ,  C10G45/06 ,  C10G45/08 ,  C10G45/46 ,  C10G45/50 ,  C10G45/60 ,  C10G47/12 ,  C10G49/04

Abstract: PURPOSE:To increase reactive selectivity by permitting a catalyst carrier consisting of spinel crystal to carry transition metal selected from among Mo, Co, Ni and W as a catalytic activate component and thereby forming a catalyst for hydrogenation. CONSTITUTION:The carrier is made from an aq. nitrate solution 2 or 3 elements selected among Al, Mg, Co, Ni and Ga, mixed them stoichiometrically so as to form the spinel crystalline structure and spray thermal decomposed it. And catalytic active elements such as Mo, Ni, Co, W are carried on the carrier and they are strongly bonded with Al in the carriers. The preferable dose of carried transition metal is 0.01-80wt.%. The catalyst obtained provides uniform mutual action between the activated metal and the carrier, as the carrier has a stable constitution and subsequently forms a uniform active site on the surface easily.

公开(公告)号：JP2001029792A

公开(公告)日：2001-02-06

申请号：JP32706999

申请日：1999-11-17

Applicant: AGENCY IND SCIENCE TECHN ,  YOSHIMURA YUJI ,  YASUDA HIROYUKI ,  SATO TOSHIO ,  KIJIMA MICHIHITO

Inventor： YOSHIMURA YUJI ,  YASUDA HIROYUKI ,  SATO TOSHIO ,  KIJIMA MICHIHITO

IPC: B01J29/12 ,  B01J32/00 ,  C10G45/54 ,  C10G49/08

Abstract: PROBLEM TO BE SOLVED: To obtain a hydrogenating catalyst having high hydrogenating function for an aromatic or heterocyclic ring, resistance against a sulfur compd. and a nitrogen compd. and long life by supporting palladium and platinum on an ultra-stabilized Y-type zeolite carrier modified by heavy rare earth elements. SOLUTION: As a carrier for supporting Pd and Pt components, an ultra- stabilized Y-type zeolite (carrier zeolite) modified by heavy rare earth elements is used. The SiO2/Al2O3 molar ratio of this carrier zeolite is about 5.0-1,000, pref., about 10-20 and, as the heavy rare earth elements, there are four elements, that is, ytterbium(Yb), gadolinium(Gd), terbium(Tb) and dysprosium(Dy). In order to modify the ultra-stabilized Y-type zeolite, at least one element selected from these heavy rare earth elements is used. Only one of palladium and platinum may be supported on the carrier zeolite but both of them are pref. supported thereon.

公开(公告)号：JPH1157482A

公开(公告)日：1999-03-02

申请号：JP23901897

申请日：1997-08-20

Applicant: AGENCY IND SCIENCE TECHN ,  YOSHIMURA YUJI ,  YASUDA HIROYUKI ,  SATO TOSHIO

Inventor： YOSHIMURA YUJI ,  YASUDA HIROYUKI ,  SATO TOSHIO

IPC: B01J29/068 ,  B01J29/12 ,  C10G45/54

Abstract: PROBLEM TO BE SOLVED: To provide a highly active aromatic ring hydrogenation catalyst and a hydrogenation treatment method of light oil using the same. SOLUTION: In an aromatic ring hydrocarbon catalyst comprising a catalyst carrying (i) palladium, (ii) platinum and (iii) at least one kind of metal selected from the group consisting of cerium, lanthanum, magnesium, calcium, strontium and barium and under the presence of the catalyst, light oil is subjected to hydrogenation treatment to reduce an aromatic ring hydrocarbon constituent in the light oil.

公开(公告)号：JPH10130111A

公开(公告)日：1998-05-19

申请号：JP30097496

申请日：1996-10-25

Applicant: AGENCY IND SCIENCE TECHN

Inventor： ONODERA YOSHIRO ,  SATO TOSHIO ,  IWASAKI TAKASHI ,  HAYASHI HIROMICHI ,  EBINA TAKEO ,  TORII KAZUO ,  SUZUKI TAKASHI

IPC: A01N25/00 ,  A01N59/06 ,  A01N59/16 ,  A01N61/00 ,  A62B18/02

Abstract: PROBLEM TO BE SOLVED: To obtain a bactericidal agent which can simply and safely killing bacteria in water by using a specific allophane as an active ingredient. SOLUTION: This bactericide contains, as an active ingredient, a silver- containing allophane prepared by substituting the H atom in the OH group in allophane represented by the formula ((a), (b) and (c) are each mole number, H binds to the oxygen in the structure to form OH, a/b=1-2; c/b=2.5-3). In addition, a part of OH on the surface of allophane particles may be substituted with a phosphoric acid group and a part of H of the OH may be substituted with silver ion, namely may contain a phosphorus and silver-containing allophane. This composition-modified allophane bactericide is brought into contact with water or a moisture-containing gas to be treated whereby the water or moisture-containing gas is disinfected by the surface of the bactericide.

公开(公告)号：JP2000328067A

公开(公告)日：2000-11-28

申请号：JP13624899

申请日：1999-05-17

Applicant: AGENCY IND SCIENCE TECHN ,  CATALYSTS & CHEM IND CO ,  NISHIJIMA AKIO ,  SATO TOSHIO ,  YOSHIMURA YUJI ,  SHIMADA HIROMICHI

Inventor： NISHIJIMA AKIO ,  SATO TOSHIO ,  YOSHIMURA YUJI ,  SHIMADA HIROMICHI ,  KAMEOKA TAKASHI ,  YANASE KANJI ,  MASUDA KOJI

IPC: B01J23/84 ,  B01J35/02 ,  C10G45/04

Abstract: PROBLEM TO BE SOLVED: To obtain a hydrogenation catalyst which exhibits an excellent denitrification activity, a high degradation resistance, and a long life by causing a fibrous alumina carrier having a specified average length to carry a metal selected from among metals of the groups VIA and VIII. SOLUTION: The medium-gravity distillate of a coal liquefaction oil is a coal-derived hydrocarbon oil having a b.p. in the range of 100-350 deg.C, and heavy naphtha, kerosene, a gas oil distillate, etc., belong to this category. The fibrous alumina carrier is bundles of fibrous alumina particles having an average length of 5-15 nm, The hydrogenation catalyst is prepared by causing the fibrous alumina carrier to carry a metal selected from among metals of the groups VIA and VIII by a conventional method such as impregnation, immersion or kneading. The metal is e.g. molybdenum, tungsten, cobalt or nickel, tungsten or nickel being especially preferable. The amount of a metal (as an oxide) carried is preferably 20-35 wt.% in the case of a group VIA metal and 3-5 wt.% in the case of a group VIII metal.

公开(公告)号：JPH04210240A

公开(公告)日：1992-07-31

申请号：JP34105390

申请日：1990-11-30

Applicant: AGENCY IND SCIENCE TECHN

Inventor： SATO TOSHIO ,  YOSHIMURA YUJI ,  MATSUBAYASHI NOBUYUKI ,  SHIMADA HIROMICHI ,  NISHIJIMA AKIO ,  KAMEOKA TAKASHI ,  YANASE KANJI

IPC: B01J27/051 ,  C10G45/04 ,  C10G47/12 ,  C10G49/04

Abstract: PURPOSE:To obtain a highly active hydrogenation catalyst by depositing a catalytic metal on a carrier and dry-sulfurating the metal without calcining it. CONSTITUTION:Catalytic metals such as molybdenum, cobalt and nickel are singly or plurally deposited on a carrier of gamma-alumina, etc. The metals are heated, dehydrated and sulfurated in a reducing atmosphere without being calcined and without the metal salts depositing on the catalyst surface being converted to their oxides to obtain different surface structures. Heavy hydrocarbons are hydrogenated and efficiently reformed or cracked by the catalyst thus obtained.

公开(公告)号：JPH04114746A

公开(公告)日：1992-04-15

申请号：JP23059790

申请日：1990-09-03

Applicant: AGENCY IND SCIENCE TECHN ,  SUMITOMO METAL MINING CO

Inventor： KANEHARA NAOTO ,  NISHIJIMA AKIO ,  SATO TOSHIO ,  YOSHIMURA YUJI ,  SHIMADA HIROMICHI ,  MATSUBAYASHI NOBUYUKI

IPC: B01J29/16 ,  C10G45/04 ,  C10G45/12

Abstract: PURPOSE:To obtain a catalyst capable of keeping stable activity over a long period of time by using zeolite having one or more metal atom in its cage and allyl mercaptan or thioglycolic acid being a sulfiding agent. CONSTITUTION:Zeolite containing one or more metal atom of the Group V1a of the Periodic Table in its cage and alumina are kneaded and molded. Subsequently, the molded one is dried to be baked and impregnated with allyl mercaptan or thioglycolic acid in an amount necessary for converting said metal atom to oxide and dried to obtain in a hydrogenating catalyst for hydrocarbon oil. As the alumina source, there are gamma-alumina or alumina hydrate. As a metal of the Group V1a of the Periodic Table, there are molybdenum or tungsten but molybdenum is proper from the aspect of catalytic activity or cost. When molybdenum is introduced into the cage of zeolite to form molybdenum disulfide or a precursor thereof in the cage, the flocculation of molybdenum disulfide during the hydrotreatment of hydrocarbon oil can be prevented and activity stable over a long period of time can be kept.

公开(公告)号：JPH11309372A

公开(公告)日：1999-11-09

申请号：JP13468098

申请日：1998-04-28

Applicant: AGENCY IND SCIENCE TECHN ,  CATALYSTS & CHEM IND CO ,  YOSHIMURA YUJI ,  YASUDA HIROYUKI ,  SATO TOSHIO

Inventor： YOSHIMURA YUJI ,  YASUDA HIROYUKI ,  SATO TOSHIO ,  KAMEOKA TAKASHI

IPC: B01J21/02 ,  B01J23/44 ,  C10G45/52

Abstract: PROBLEM TO BE SOLVED: To have resistance to sulfur compounds and to reduce the deterioration of activity by supporting a noble metal selected from the group VIII noble metals in the periodic table on an almina-boric carrier. SOLUTION: The component of a noble metal such as ruthenium, rhodium, palladium, osmium, and platinum selected from the group III noble metals in the periodic table is supported on an alumina-boria carrier produced by a method in which alumina or an alumina precursor is mixed with boric acid ammonium borate, or the like as boron compounds, and the mixture is molded, dried, and burned. In this way, its use in the hydrogenation of hydrocarbons contained in catalytic cracking oil, thermal cracking oil, direct distillation light oil, coker gas oil, hydrogenated light oil, desulfurized light oil, and or the like is made possible, resistance to sulfur compounds is exhibited, the activity deterioration is reduced, and the life is extended.