-
1.
公开(公告)号:JP2001058814A
公开(公告)日:2001-03-06
申请号:JP23678099
申请日:1999-08-24
Applicant: KOON SANSEI GAS KOTEIKA GIJUTS , AGENCY IND SCIENCE TECHN
Inventor: SHIBAZAKI YASUO , SUZUKI KENJI , SUZUKI MASAYA , FUJITA SATORU , OGAWA NAOYUKI , FUKUDA TOMOYUKI , NAKAYAMA KATSUHIRO
Abstract: PROBLEM TO BE SOLVED: To efficiently produce hydrogarnet in a simple process by carrying out a hydrothermal treatment of a mixture of a silica source with an alumina source and a calcium source. SOLUTION: Kaolin, silica, amorphous silica, diatomaceous earth, silica sand, quartz, etc., are cited as a silica source. Kaolin, an alumina sol, boehmite, aluminum hydroxide, aluminum oxide, etc., are cited as an alumina source. Quick lime, slaked lime, gypsum, etc., are cited as a calcium source. The raw materials are mixed in a prescribed proportion and water in an adequate amount is subsequently added thereto. The resultant mixture is then subjected to a hydrothermal treatment which is preferably carried out at 130-200 deg.C hydrothermal treating temperature for about 15 h hydrothermal treating time by using, e.g. an autoclave. The resultant hydrogarnet has a high heat-resistant temperature and is capable of efficiently absorbing and fixing an acidic waste gas at a high temperature up to about 1,000 deg.C.
-
公开(公告)号:JP2001029781A
公开(公告)日:2001-02-06
申请号:JP20870699
申请日:1999-07-23
Applicant: AGENCY IND SCIENCE TECHN
Inventor: OHASHI FUMIHIKO , MAEDA MASAKI , INUKAI KEIICHI , SUZUKI MASAYA , WATAMURA SHINJI
Abstract: PROBLEM TO BE SOLVED: To obtain a new moisture absorbing and releasing material being repeatedly usable and with steam durability and excellent autonomic moisture absorbing and releasing function by constituting a compsn. for a porous material synthesized by using a surfactant or an org. substance with a long chain alkyl group as a casting mold of a mixed compsn. of a silicon compd. and a titanium compd. SOLUTION: A moisture absorbing and releasing material comprizing a compsn. of a porous material with convergent hysteresis and an autonomic moisture absorbing and releasing function is provided. i.e., the moisture absorbing and releasing material comprising a porous material consisting of a main compsn. of a porous material synthesized so as to surround the casting mold by periodically arranging a substance wherein a surfactant whose chain length is const. or an org. substance with a long chain alkyl group as a casting mold comprises a mixed compsn. of a silicon compd. and a titanium compd. and whose mean value of the fine pore diameter is controlled to 2-6 nm, is provided. The porous material like this is obtd. by a method wherein after the periphery of the org. substance is surrounded with the silicon compd. and titanium compd. and is polymerized, incineration or extraction is performed to remove org. substance.
-
公开(公告)号:JP2000288389A
公开(公告)日:2000-10-17
申请号:JP9347399
申请日:1999-03-31
Applicant: KOON SANSEI GAS KOTEIKA GIJUTS , AGENCY IND SCIENCE TECHN
Inventor: SHIBAZAKI YASUO , SUZUKI KENJI , SUZUKI MASAYA , FUJITA SATORU , OGAWA NAOYUKI , FUKUDA TOMOYUKI , NAKAYAMA KATSUHIRO
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an adsorbent for a high temperature acidic exhaust gas and a method for removing a high temperature acidic gas. SOLUTION: In the absorbent for exhaust gas, a mixture of amorphous calcium silicate hydrate and sodium aluminate is subjected to hydrothermal treatment. In the method for removing exhaust gas, a high temperature acidic exhaust gas discharged from an incinerator and others is absorbed/fixed by the absorbent. In this way, the adsorbent for an acidic exhaust gas can be produced efficiently by a simple process. The adsorbent is useful as a fixing agent for fixing/absorbing a high temperature acidic exhaust gas discharged from the incinerator and others.
-
公开(公告)号:JP2000202286A
公开(公告)日:2000-07-25
申请号:JP1045699
申请日:1999-01-19
Applicant: AGENCY IND SCIENCE TECHN , KOON SANSEI GAS KOTEIKA GIJUTS
Inventor: SHIBAZAKI YASUO , SUZUKI KENJI , SUZUKI MASAYA , KUDO YOSHIKO , OGAWA NAOYUKI , FUKUDA TOMOYUKI , FUJITA SATORU
Abstract: PROBLEM TO BE SOLVED: To regenerate an acidic waste gas absorbent containing a sodalite group compound, to enable repetitive use and to reduce waste. SOLUTION: The acidic waste gas absorbent containing a sodalite group compound is regenerated after reactions with chlorine-containing acidic waste gas as follows; the absorbent is heat-treated or hydrothermally treated, an alkali source is added and the absorbent is heat-treated or hydrothermally treated again. The former heat treatment and hydrothermal treatment are preferably carried out at 800-1,300 deg.C and 700-1,300 deg.C, respectively. The latter heat treatment and hydrothermal treatment are preferably carried out at 50-600 deg.C and 100-180 deg.C, respectively. Hydrosodalite is preferably used as the acidic waste gas absorbent and the alkali source is preferably based on sodium hydroxide.
-
公开(公告)号:JP2000189789A
公开(公告)日:2000-07-11
申请号:JP61299
申请日:1999-01-05
Applicant: AGENCY IND SCIENCE TECHN , YKK CORP
Inventor: MAEDA MASAKI , SUZUKI MASAYA , OHASHI FUMIHIKO , INUKAI KEIICHI , WATAMURA SHINJI , SHIBAZAKI YASUO , FUKUSHIMA KYOKO , AIKAWA KAZUO
Abstract: PROBLEM TO BE SOLVED: To provide the moisture regulating material useful as the repeatedly usable moisture regulating material for dew condensation regulation and to provide its production method. SOLUTION: The composite of a porous metal hydroxide and a by-product having hydroscopicity is produced, by precipitating a metal hydroxide by adjusting the hydrogen ion concn. of a metal chloride aq. soln. with ammonia water, etc., and subjecting the hydroxide gel obtained by agitating the hydroxide in a hot water bath to heat treatment at the temp. at which a hygroscopic by-product is not thermally decomposed. In this way, the moisture regulating material for dew condensation usable repeatedly by absorbing the water vapor more than 60% of one's weight under the high humidity condition of >=80% relative humidity and easily releasing the water vapor under the usual humidity condition of
-
公开(公告)号:JP2000104353A
公开(公告)日:2000-04-11
申请号:JP29459798
申请日:1998-09-30
Applicant: AGENCY IND SCIENCE TECHN
Inventor: WATAMURA SHINJI , MAEDA MASAKI , INUKAI KEIICHI , OHASHI FUMIHIKO , SUZUKI MASAYA , SHIBAZAKI YASUO
Abstract: PROBLEM TO BE SOLVED: To provide a method for manufacturing a porous wall material, in which molding and solidifying are conducted without reducing the steam absorption of porous powder having no moldability and which displays an autonomous humidity-conditioning function. SOLUTION: A porous wall material combining hygroscopicity and moisture absorption characteristics without damaging porosity and having pores in nanometer order is manufactured by preparing and drying molded and solidified forms by utilizing the viscosity of a silica sol. Accordingly, a functional material autonomically having a humidity-conditioning function can be supplied without imparting energy from the outside by a capillary condensation phenomenon generated in pores in nanometer order by providing an energy-conservative porous solidified-form manufacture as a molding method making the strength of porous powder having no moldability and steam absorption coexist.
-
公开(公告)号:JPH11147037A
公开(公告)日:1999-06-02
申请号:JP31488297
申请日:1997-11-17
Applicant: AGENCY IND SCIENCE TECHN , MRC KK , OZEKI TOSHIYA
Inventor: WATAMURA SHINJI , MAEDA MASAKI , SUZUKI MASAYA , MIZUGUCHI HIROYOSHI , OZEKI TOSHIYA
Abstract: PROBLEM TO BE SOLVED: To manufacture a new material of high humidity control effect for controlling humidity in an optional narrow range. SOLUTION: A humidity control material is composed of an inorganic porous body, and provided with through-holes of 500 nm pore diameter or larger connected together in the three-dimensional network and pores of pore diameter of 30 nm or less formed on the inner wall faces of the through-holes, and the total volume of pores is 10 m /t or less, and the volume ratio of through-holes to the whole body is 20-90% and the volume ratio of pores in the total voids is 10% or more.
-
公开(公告)号:JP2001330519A
公开(公告)日:2001-11-30
申请号:JP2000147220
申请日:2000-05-19
Applicant: NAT INST OF ADVANCED IND SCIEN , YAMAGUCHI TECH LICENSING , OZAWA KAGAKU KK , AGENCY IND SCIENCE TECHN
Inventor: MIZOTA TADAHITO , MAEDA AKIRA , INUKAI KEIICHI , SUZUKI MASAYA
IPC: G01K17/02
Abstract: PROBLEM TO BE SOLVED: To provide a batch adiabatic type adsorption heat measuring device allowing simultaneous measurement of adsorption heat and equilibrium vapor pressure at gas adsorption time. SOLUTION: A pressure sensor part is connected to a system for measuring the adsorption heat for coupling a solution reservoir for storing solution that evaporates and is adsorbed by a sample to a sample vessel for storing the sample. Thus, the batch adiabatic type adsorption heat measuring device can simultaneously measure adsorption heat and equilibrium vapor pressure.
-
9.
公开(公告)号:JP2000271432A
公开(公告)日:2000-10-03
申请号:JP8043999
申请日:1999-03-24
Applicant: KOON SANSEI GAS KOTEIKA GIJUTS , AGENCY IND SCIENCE TECHN
Inventor: SHIBAZAKI YASUO , SUZUKI KENJI , SUZUKI MASAYA , FUJITA SATORU , OGAWA NAOYUKI , FUKUDA TOMOYUKI , KUDO YOSHIKO
Abstract: PROBLEM TO BE SOLVED: To improve the heat resisting temp. of a high temp. acidic gas immobilizing agent by incorporating a cation substituted hydrosodalite prepared by hydrothermally treating a mixture of hydrosodalite with a cation to replace Na in the hydrosodalite by the cation. SOLUTION: The high temp. acidic gas immobilizing agent is prepared by using the cation substituted hydrosodalite (e.g. (Ca or Na)4-8Al6Si6O24(OH)2) obtained by hydrothermally treating the mixture of the hydrosodalite and the cation to replace a part or the whole of Na in the β-cage of hydrosodalite (Na8Al6Si6O24(OH)2) by the cation of an alkali metal and/or an alkaline earth metal. The cation is one kind of a cation selected from K, Rb, Ca, Sr, Ba and a compound of the alkali metal (K or Rb), a compound of the alakline earth metal (Ca, Sr or Ba), for example the acetate thereof is suitably used.
-
公开(公告)号:JPH1179731A
公开(公告)日:1999-03-23
申请号:JP28629597
申请日:1997-09-04
Applicant: AGENCY IND SCIENCE TECHN
Inventor: SUZUKI MASAYA , WATAMURA SHINJI , MAEDA MASAKI , INUKAI KEIICHI , OHASHI FUMIHIKO , SHIBAZAKI YASUO
Abstract: PROBLEM TO BE SOLVED: To synthesize aluminosilicate in a large amt. in a short time while suppressing energy consumption by mixing a silicon compd. soln. of high concn. and an aluminum compd. soln., dropping an alkali soln. into the mixture to neutralize, and separating and collecting a solid content produced at room temp. SOLUTION: A silicon compd. soln. of 10 to 500 mmol, and an aluminum compd. soln. of 10 to 100 mmol are mixed with 0.5 to 2.0 molar ratio of silicon/ aluminum, and then an alkali soln. is dropped into the mixture soln. by 0.5 to 2 mol/min rate to neutralize and to produce a solid content at room temp. The produced solid content is separated by filtering and with a centrifugal separating machine, then cleaned, and dried to obtain spherical aluminosilicate. The obtd. spherical aluminosilicate is a highly functional porous material having 1 to 10 nm particle diameter, >=70 m /g specific surface area by nitrogen adsorption, and 0.5 to 2.0 silicon/aluminum ratio, and can be synthesized in a large amt. at room temp.
-
-
-
-
-
-
-
-
-