MOISTURE ABSORBING AND RELEASING MATERIAL WITH SMALL HYSTERESIS AND STEAM DURABILITY

    公开(公告)号:JP2001029781A

    公开(公告)日:2001-02-06

    申请号:JP20870699

    申请日:1999-07-23

    Abstract: PROBLEM TO BE SOLVED: To obtain a new moisture absorbing and releasing material being repeatedly usable and with steam durability and excellent autonomic moisture absorbing and releasing function by constituting a compsn. for a porous material synthesized by using a surfactant or an org. substance with a long chain alkyl group as a casting mold of a mixed compsn. of a silicon compd. and a titanium compd. SOLUTION: A moisture absorbing and releasing material comprizing a compsn. of a porous material with convergent hysteresis and an autonomic moisture absorbing and releasing function is provided. i.e., the moisture absorbing and releasing material comprising a porous material consisting of a main compsn. of a porous material synthesized so as to surround the casting mold by periodically arranging a substance wherein a surfactant whose chain length is const. or an org. substance with a long chain alkyl group as a casting mold comprises a mixed compsn. of a silicon compd. and a titanium compd. and whose mean value of the fine pore diameter is controlled to 2-6 nm, is provided. The porous material like this is obtd. by a method wherein after the periphery of the org. substance is surrounded with the silicon compd. and titanium compd. and is polymerized, incineration or extraction is performed to remove org. substance.

    METHOD FOR REGENERATING ACIDIC WASTE GAS ABSORBENT

    公开(公告)号:JP2000202286A

    公开(公告)日:2000-07-25

    申请号:JP1045699

    申请日:1999-01-19

    Abstract: PROBLEM TO BE SOLVED: To regenerate an acidic waste gas absorbent containing a sodalite group compound, to enable repetitive use and to reduce waste. SOLUTION: The acidic waste gas absorbent containing a sodalite group compound is regenerated after reactions with chlorine-containing acidic waste gas as follows; the absorbent is heat-treated or hydrothermally treated, an alkali source is added and the absorbent is heat-treated or hydrothermally treated again. The former heat treatment and hydrothermal treatment are preferably carried out at 800-1,300 deg.C and 700-1,300 deg.C, respectively. The latter heat treatment and hydrothermal treatment are preferably carried out at 50-600 deg.C and 100-180 deg.C, respectively. Hydrosodalite is preferably used as the acidic waste gas absorbent and the alkali source is preferably based on sodium hydroxide.

    MOISTURE ABSORPTION-DESORPTION POROUS STRUCTURE AND MANUFACTURE THEREOF

    公开(公告)号:JP2000104353A

    公开(公告)日:2000-04-11

    申请号:JP29459798

    申请日:1998-09-30

    Abstract: PROBLEM TO BE SOLVED: To provide a method for manufacturing a porous wall material, in which molding and solidifying are conducted without reducing the steam absorption of porous powder having no moldability and which displays an autonomous humidity-conditioning function. SOLUTION: A porous wall material combining hygroscopicity and moisture absorption characteristics without damaging porosity and having pores in nanometer order is manufactured by preparing and drying molded and solidified forms by utilizing the viscosity of a silica sol. Accordingly, a functional material autonomically having a humidity-conditioning function can be supplied without imparting energy from the outside by a capillary condensation phenomenon generated in pores in nanometer order by providing an energy-conservative porous solidified-form manufacture as a molding method making the strength of porous powder having no moldability and steam absorption coexist.

    SYNTHESIS OF SPHERICAL ALUMINOSILICATE FROM HIGH-CONCENTRATION SOLUTION

    公开(公告)号:JPH1179731A

    公开(公告)日:1999-03-23

    申请号:JP28629597

    申请日:1997-09-04

    Abstract: PROBLEM TO BE SOLVED: To synthesize aluminosilicate in a large amt. in a short time while suppressing energy consumption by mixing a silicon compd. soln. of high concn. and an aluminum compd. soln., dropping an alkali soln. into the mixture to neutralize, and separating and collecting a solid content produced at room temp. SOLUTION: A silicon compd. soln. of 10 to 500 mmol, and an aluminum compd. soln. of 10 to 100 mmol are mixed with 0.5 to 2.0 molar ratio of silicon/ aluminum, and then an alkali soln. is dropped into the mixture soln. by 0.5 to 2 mol/min rate to neutralize and to produce a solid content at room temp. The produced solid content is separated by filtering and with a centrifugal separating machine, then cleaned, and dried to obtain spherical aluminosilicate. The obtd. spherical aluminosilicate is a highly functional porous material having 1 to 10 nm particle diameter, >=70 m /g specific surface area by nitrogen adsorption, and 0.5 to 2.0 silicon/aluminum ratio, and can be synthesized in a large amt. at room temp.

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