MOISTURE ABSORBING AND RELEASING MATERIAL WITH SMALL HYSTERESIS AND STEAM DURABILITY

    公开(公告)号:JP2001029781A

    公开(公告)日:2001-02-06

    申请号:JP20870699

    申请日:1999-07-23

    Abstract: PROBLEM TO BE SOLVED: To obtain a new moisture absorbing and releasing material being repeatedly usable and with steam durability and excellent autonomic moisture absorbing and releasing function by constituting a compsn. for a porous material synthesized by using a surfactant or an org. substance with a long chain alkyl group as a casting mold of a mixed compsn. of a silicon compd. and a titanium compd. SOLUTION: A moisture absorbing and releasing material comprizing a compsn. of a porous material with convergent hysteresis and an autonomic moisture absorbing and releasing function is provided. i.e., the moisture absorbing and releasing material comprising a porous material consisting of a main compsn. of a porous material synthesized so as to surround the casting mold by periodically arranging a substance wherein a surfactant whose chain length is const. or an org. substance with a long chain alkyl group as a casting mold comprises a mixed compsn. of a silicon compd. and a titanium compd. and whose mean value of the fine pore diameter is controlled to 2-6 nm, is provided. The porous material like this is obtd. by a method wherein after the periphery of the org. substance is surrounded with the silicon compd. and titanium compd. and is polymerized, incineration or extraction is performed to remove org. substance.

    MOISTURE ABSORPTION-DESORPTION POROUS STRUCTURE AND MANUFACTURE THEREOF

    公开(公告)号:JP2000104353A

    公开(公告)日:2000-04-11

    申请号:JP29459798

    申请日:1998-09-30

    Abstract: PROBLEM TO BE SOLVED: To provide a method for manufacturing a porous wall material, in which molding and solidifying are conducted without reducing the steam absorption of porous powder having no moldability and which displays an autonomous humidity-conditioning function. SOLUTION: A porous wall material combining hygroscopicity and moisture absorption characteristics without damaging porosity and having pores in nanometer order is manufactured by preparing and drying molded and solidified forms by utilizing the viscosity of a silica sol. Accordingly, a functional material autonomically having a humidity-conditioning function can be supplied without imparting energy from the outside by a capillary condensation phenomenon generated in pores in nanometer order by providing an energy-conservative porous solidified-form manufacture as a molding method making the strength of porous powder having no moldability and steam absorption coexist.

    MANUFACTURE OF LAMINAR PARTICLE FILM

    公开(公告)号:JPH0857406A

    公开(公告)日:1996-03-05

    申请号:JP3098994

    申请日:1994-02-02

    Abstract: PURPOSE: To make a laminar inorganic compound having a complicated structure and composition into a film, arrange the thin laminar particles correctly and manufacture a laminar particle film by turning the surfaces of the laminar particles hydrophobic, dispersing the particles on a water surface and making the particles adhere to a substrate. CONSTITUTION: The surfaces of laminar particles are turned into hydrophobic and dispersed on a water surface, and then made to adhere to a substrate to manufacture a laminar particles film. On the other hand, the manufacturing processes are repeated to control the thickness of laminar particle film. In the manufacture, for example, a film manufacturing device composed of a trough 1, a movable barrier 2, a vertical immersion plate 3 and a surface pressure sensor 4 is used. At that time, the formation status and reproducibility of the film are presumed based on the measurement (π-A curve) of surface pressure (π) and development area (A). As a result, when the ratio between the dispersed liquid volume and the maximum development area is too large, the particles on a development surface are brought into contact with one another to form weakly composite particles, which is not preferable as it takes a long time to form desired monolayer particles.

    METHOD FOR RECOVERING HIGH-TEMPERATURE CARBON DIOXIDE IN WASTE GAS AND APPARATUS THEREFOR

    公开(公告)号:JPH07277718A

    公开(公告)日:1995-10-24

    申请号:JP8803994

    申请日:1994-03-31

    Abstract: PURPOSE:To efficiently separate and recover CO2, discharged by burning petroleum, coal, a gas, etc., in a state of a high concentration and a high temperature before discharging into the air. CONSTITUTION:The method for recovering high-temperature carbon dioxide in a waste gas is to feed a prescribed amount of the waste gas still kept at a high temperature due to combustion into a separating cylinder 3 to which a carrier gas is fed at a constant flow rate at a prescribed time interval, bring the waste gas into contact with a ceramic separating agent, filled in the separating cylinder 3 and having a larger retention time from adsorption of CO2 thereon to the desorption thereof than that of other gases, discharge the gases other than the CO2 by the carrying away with the carrier gas in a housing chamber 6 for the separating agent, then change over a discharge port from the separating cylinder 3 to the side of a bypass flow passage 9 with a changeover valve 7, separate and recover the CO2 in the bypass flow passage 9.

    SILICA-ALUMINA-BASED MINERAL EXHIBITING PLASTICITY AND ITS PRODUCTION

    公开(公告)号:JPH06157024A

    公开(公告)日:1994-06-03

    申请号:JP13724591

    申请日:1991-05-13

    Abstract: PURPOSE:To produce the subject mineral moldable without requiring addition of an organic additive by applying a hydrothermal treatment to a powdery two-component system mineral of silica-alumina in an acidic or neutral solution and forming a thin kaolinite film. CONSTITUTION:A powdery two-component system mineral of silica-alumina such as mullite and an acidic or neutral solution is tightly sealed in a pressure tank such as an autoclave. A hydrothermal reaction is carried out by heating to convert the surface of the powdery mineral into a clay-like material exhibiting plasticity. The particle size of the powdery mineral is not especially restricted and about 3 to 10mum is preferable. As the condition of the hydrothermal reaction, the reaction temperature is preferably 200 to 250 deg.C in the case of 7 day reaction period and the most favorable result can be obtained especially at about 230 deg.C. Further, an acidic solution is preferably used as the solution and a 0.1 N to 0.01 N hydrochloric acid solution is especially preferable. As the result of this hydrothermal treatment, a thin kaolinite film can be formed on the surface of a mineral such as mullite.

    METHOD FOR IMPROVING THERMAL STABILITY OF SEPIOLITE

    公开(公告)号:JPH08253311A

    公开(公告)日:1996-10-01

    申请号:JP7981095

    申请日:1995-03-10

    Abstract: PURPOSE: To provide a method for stable holding a sepiolite crystal structure even at a high temperature. CONSTITUTION: Sepiolite is well dispersed in a mineral acid and the sepiolite is recovered with centrifugation, filtration, etc., after being well dispersed and still standing. Subsequently, the recovered sepiolite is again dispersed in a solution of a divalent cation to carry out an ion-exchanging treatment and then the objective sepiolite is recovered by centrifugation, filtration, etc.

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