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公开(公告)号:JP2001029781A
公开(公告)日:2001-02-06
申请号:JP20870699
申请日:1999-07-23
Applicant: AGENCY IND SCIENCE TECHN
Inventor: OHASHI FUMIHIKO , MAEDA MASAKI , INUKAI KEIICHI , SUZUKI MASAYA , WATAMURA SHINJI
Abstract: PROBLEM TO BE SOLVED: To obtain a new moisture absorbing and releasing material being repeatedly usable and with steam durability and excellent autonomic moisture absorbing and releasing function by constituting a compsn. for a porous material synthesized by using a surfactant or an org. substance with a long chain alkyl group as a casting mold of a mixed compsn. of a silicon compd. and a titanium compd. SOLUTION: A moisture absorbing and releasing material comprizing a compsn. of a porous material with convergent hysteresis and an autonomic moisture absorbing and releasing function is provided. i.e., the moisture absorbing and releasing material comprising a porous material consisting of a main compsn. of a porous material synthesized so as to surround the casting mold by periodically arranging a substance wherein a surfactant whose chain length is const. or an org. substance with a long chain alkyl group as a casting mold comprises a mixed compsn. of a silicon compd. and a titanium compd. and whose mean value of the fine pore diameter is controlled to 2-6 nm, is provided. The porous material like this is obtd. by a method wherein after the periphery of the org. substance is surrounded with the silicon compd. and titanium compd. and is polymerized, incineration or extraction is performed to remove org. substance.
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公开(公告)号:JP2000189789A
公开(公告)日:2000-07-11
申请号:JP61299
申请日:1999-01-05
Applicant: AGENCY IND SCIENCE TECHN , YKK CORP
Inventor: MAEDA MASAKI , SUZUKI MASAYA , OHASHI FUMIHIKO , INUKAI KEIICHI , WATAMURA SHINJI , SHIBAZAKI YASUO , FUKUSHIMA KYOKO , AIKAWA KAZUO
Abstract: PROBLEM TO BE SOLVED: To provide the moisture regulating material useful as the repeatedly usable moisture regulating material for dew condensation regulation and to provide its production method. SOLUTION: The composite of a porous metal hydroxide and a by-product having hydroscopicity is produced, by precipitating a metal hydroxide by adjusting the hydrogen ion concn. of a metal chloride aq. soln. with ammonia water, etc., and subjecting the hydroxide gel obtained by agitating the hydroxide in a hot water bath to heat treatment at the temp. at which a hygroscopic by-product is not thermally decomposed. In this way, the moisture regulating material for dew condensation usable repeatedly by absorbing the water vapor more than 60% of one's weight under the high humidity condition of >=80% relative humidity and easily releasing the water vapor under the usual humidity condition of
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公开(公告)号:JP2000104353A
公开(公告)日:2000-04-11
申请号:JP29459798
申请日:1998-09-30
Applicant: AGENCY IND SCIENCE TECHN
Inventor: WATAMURA SHINJI , MAEDA MASAKI , INUKAI KEIICHI , OHASHI FUMIHIKO , SUZUKI MASAYA , SHIBAZAKI YASUO
Abstract: PROBLEM TO BE SOLVED: To provide a method for manufacturing a porous wall material, in which molding and solidifying are conducted without reducing the steam absorption of porous powder having no moldability and which displays an autonomous humidity-conditioning function. SOLUTION: A porous wall material combining hygroscopicity and moisture absorption characteristics without damaging porosity and having pores in nanometer order is manufactured by preparing and drying molded and solidified forms by utilizing the viscosity of a silica sol. Accordingly, a functional material autonomically having a humidity-conditioning function can be supplied without imparting energy from the outside by a capillary condensation phenomenon generated in pores in nanometer order by providing an energy-conservative porous solidified-form manufacture as a molding method making the strength of porous powder having no moldability and steam absorption coexist.
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公开(公告)号:JPH11147037A
公开(公告)日:1999-06-02
申请号:JP31488297
申请日:1997-11-17
Applicant: AGENCY IND SCIENCE TECHN , MRC KK , OZEKI TOSHIYA
Inventor: WATAMURA SHINJI , MAEDA MASAKI , SUZUKI MASAYA , MIZUGUCHI HIROYOSHI , OZEKI TOSHIYA
Abstract: PROBLEM TO BE SOLVED: To manufacture a new material of high humidity control effect for controlling humidity in an optional narrow range. SOLUTION: A humidity control material is composed of an inorganic porous body, and provided with through-holes of 500 nm pore diameter or larger connected together in the three-dimensional network and pores of pore diameter of 30 nm or less formed on the inner wall faces of the through-holes, and the total volume of pores is 10 m /t or less, and the volume ratio of through-holes to the whole body is 20-90% and the volume ratio of pores in the total voids is 10% or more.
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公开(公告)号:JPH0857406A
公开(公告)日:1996-03-05
申请号:JP3098994
申请日:1994-02-02
Applicant: AGENCY IND SCIENCE TECHN
Inventor: INUKAI KEIICHI , WATAMURA SHINJI , SUZUKI KENJI , YAMAGISHI AKIHIKO
Abstract: PURPOSE: To make a laminar inorganic compound having a complicated structure and composition into a film, arrange the thin laminar particles correctly and manufacture a laminar particle film by turning the surfaces of the laminar particles hydrophobic, dispersing the particles on a water surface and making the particles adhere to a substrate. CONSTITUTION: The surfaces of laminar particles are turned into hydrophobic and dispersed on a water surface, and then made to adhere to a substrate to manufacture a laminar particles film. On the other hand, the manufacturing processes are repeated to control the thickness of laminar particle film. In the manufacture, for example, a film manufacturing device composed of a trough 1, a movable barrier 2, a vertical immersion plate 3 and a surface pressure sensor 4 is used. At that time, the formation status and reproducibility of the film are presumed based on the measurement (π-A curve) of surface pressure (π) and development area (A). As a result, when the ratio between the dispersed liquid volume and the maximum development area is too large, the particles on a development surface are brought into contact with one another to form weakly composite particles, which is not preferable as it takes a long time to form desired monolayer particles.
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公开(公告)号:JPH07277718A
公开(公告)日:1995-10-24
申请号:JP8803994
申请日:1994-03-31
Applicant: AGENCY IND SCIENCE TECHN
Inventor: OZAKI TOSHIHIKO , SUZUKI KENJI , HORIO MASAKAZU , WATAMURA SHINJI , MORI TOSHIAKI
Abstract: PURPOSE:To efficiently separate and recover CO2, discharged by burning petroleum, coal, a gas, etc., in a state of a high concentration and a high temperature before discharging into the air. CONSTITUTION:The method for recovering high-temperature carbon dioxide in a waste gas is to feed a prescribed amount of the waste gas still kept at a high temperature due to combustion into a separating cylinder 3 to which a carrier gas is fed at a constant flow rate at a prescribed time interval, bring the waste gas into contact with a ceramic separating agent, filled in the separating cylinder 3 and having a larger retention time from adsorption of CO2 thereon to the desorption thereof than that of other gases, discharge the gases other than the CO2 by the carrying away with the carrier gas in a housing chamber 6 for the separating agent, then change over a discharge port from the separating cylinder 3 to the side of a bypass flow passage 9 with a changeover valve 7, separate and recover the CO2 in the bypass flow passage 9.
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公开(公告)号:JPH06157024A
公开(公告)日:1994-06-03
申请号:JP13724591
申请日:1991-05-13
Applicant: AGENCY IND SCIENCE TECHN
Inventor: SHIBAZAKI YASUO , WATAMURA SHINJI , ITO HIROSHI , TONE YUKIHITO , KUMAGAI NOBUFUMI
IPC: C01B33/26 , C04B35/00 , C04B35/18 , C04B35/628
Abstract: PURPOSE:To produce the subject mineral moldable without requiring addition of an organic additive by applying a hydrothermal treatment to a powdery two-component system mineral of silica-alumina in an acidic or neutral solution and forming a thin kaolinite film. CONSTITUTION:A powdery two-component system mineral of silica-alumina such as mullite and an acidic or neutral solution is tightly sealed in a pressure tank such as an autoclave. A hydrothermal reaction is carried out by heating to convert the surface of the powdery mineral into a clay-like material exhibiting plasticity. The particle size of the powdery mineral is not especially restricted and about 3 to 10mum is preferable. As the condition of the hydrothermal reaction, the reaction temperature is preferably 200 to 250 deg.C in the case of 7 day reaction period and the most favorable result can be obtained especially at about 230 deg.C. Further, an acidic solution is preferably used as the solution and a 0.1 N to 0.01 N hydrochloric acid solution is especially preferable. As the result of this hydrothermal treatment, a thin kaolinite film can be formed on the surface of a mineral such as mullite.
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公开(公告)号:JPH0578118A
公开(公告)日:1993-03-30
申请号:JP13077891
申请日:1991-03-22
Applicant: AGENCY IND SCIENCE TECHN , FUJI CHEM IND CO LTD
Inventor: SHIBAZAKI YASUO , ODA KIICHI , WATAMURA SHINJI , MACHIMURA HITOSHI , MURAKAMI TATSUO
Abstract: PURPOSE:To provide an inorganic powder substance carrying metal hydroxide ion and resistant to the dissolution of metal ion. CONSTITUTION:Amorphous magnesium silicate aluminate is added to and suspended in a weakly acidic aqueous solution of a water-soluble salt of a metal selected from Cu, Mn, Ni, Zn, Ag and Co. In the above process, the magnesium in the magnesium silicate aluminate is subjected to ion-exchange reaction with the above metal and the suspension of the obtained product is aged, filtered, washed with water and dried to obtain the objective inorganic powder substance. The obtained inorganic powder substance is new substance.
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公开(公告)号:JPH08253311A
公开(公告)日:1996-10-01
申请号:JP7981095
申请日:1995-03-10
Applicant: AGENCY IND SCIENCE TECHN
Inventor: SUZUKI KENJI , INUKAI KEIICHI , WATAMURA SHINJI
Abstract: PURPOSE: To provide a method for stable holding a sepiolite crystal structure even at a high temperature. CONSTITUTION: Sepiolite is well dispersed in a mineral acid and the sepiolite is recovered with centrifugation, filtration, etc., after being well dispersed and still standing. Subsequently, the recovered sepiolite is again dispersed in a solution of a divalent cation to carry out an ion-exchanging treatment and then the objective sepiolite is recovered by centrifugation, filtration, etc.
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公开(公告)号:JPH0833824A
公开(公告)日:1996-02-06
申请号:JP30593393
申请日:1993-11-10
Applicant: AGENCY IND SCIENCE TECHN
Inventor: HORIO MASAKAZU , SUZUKI KENJI , MORI TOSHIAKI , INUKAI KEIICHI , WATAMURA SHINJI
Abstract: PURPOSE:To separate nitrogen from carbon dioxide in a high temp. state by using a heat treated sepiolite as a separating material. CONSTITUTION:Nitrogen is separated from carbon dioxide in the high temp. state by using the sepiolite heat-treated at
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