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    PRODUCTION OF CONJUGATED POLYMER, POLY-2,5-PYRIDINEDIYLVINYLENE
    2.
    发明专利
    PRODUCTION OF CONJUGATED POLYMER, POLY-2,5-PYRIDINEDIYLVINYLENE 失效

    公开(公告)号：JPH0782350A

    公开(公告)日：1995-03-28

    申请号：JP24859693

    申请日：1993-09-10

    Applicant: AGENCY IND SCIENCE TECHN ,  TOHO RAYON KK

    Inventor： KAERIYAMA KYOJI ,  TANAKA SUSUMU ,  SATO HIROYUKI

    IPC: C08G61/12 ,  C08G61/10

    Abstract: PURPOSE:To provide a production process of poly-2,5-pyridinediylvinylene in which the sulfonium salt elimination process problematic in its inapplicability to industrial production is not used, a monomer stable at room temperature is used as the monomer used in the polymerization, the polymer is easily formed, and the polymer is easily purified, and which is suited for industrial production. CONSTITUTION:A 2,5-dihalomethylpyridine is polymerized in the presence of a base by a process of polymerization through dehydrohalogenation to obtain a polymer represented by the formula. The obtained polymer is subjected to heat treatment at 230-300 deg.C in a nitrogen or inert gas stream or in a vacuum to eliminate the residual halogen part of this polymer and to thereby improve the convertion into the polymer.

    PYRROLE COMPOUND AND PRODUCTION THEREOF
    4.
    发明专利
    PYRROLE COMPOUND AND PRODUCTION THEREOF 失效

    公开(公告)号：JPH02145566A

    公开(公告)日：1990-06-05

    申请号：JP29995088

    申请日：1988-11-28

    Applicant: AGENCY IND SCIENCE TECHN

    Inventor： KAERIYAMA KYOJI ,  TANAKA SUSUMU ,  YAMAUCHI AIZO ,  KITASHOJI TAKESHI

    IPC: C07D207/323 ,  C08G61/10 ,  C08G61/12

    Abstract: NEW MATERIAL:The pyrrole compound of formula (R is higher alkyl). EXAMPLE:3-Octylpyrrole. USE:The polymer of the compound is useful as an organic conductive polymer. PREPARATION:The objective compound of formula can be produced by acylating N-sulfonated pyrrole with a carboxylic acid chloride in the presence of a Friedel-Crafts catalyst, desulfonating the reaction product, separating an alkyl-3-pyrrolyl ketone from the obtained mixture of 2-substituted pyrrole and 3-substituted pyrrole and purifying and reducing the separated ketone. The Friedel-Crafts catalyst is e.g., stannic chloride or aluminum chloride and the reducing agent is aluminum lithium hydride, etc.

    ORGANIC SEMICONDUCTOR
    5.
    发明专利
    ORGANIC SEMICONDUCTOR 失效

    公开(公告)号：JPS63205316A

    公开(公告)日：1988-08-24

    申请号：JP3681687

    申请日：1987-02-19

    Applicant: AGENCY IND SCIENCE TECHN

    Inventor： TANAKA SUSUMU ,  SATO MASAAKI ,  KAERIYAMA KYOJI ,  SUDA MASAO ,  HIRAIDE TAKAO

    IPC: C08G61/00 ,  C08G61/10 ,  C08G61/12 ,  H01B1/12 ,  H01L51/05 ,  H01L51/30

    Abstract: PURPOSE:To obtain a specified thiophene polymer in a neutral state and an organic semiconductor in the form a film which is excellent in heat resistance and smoothness, stable in air and useful as a display material and can be obtained without molding, by doping said polymer with an anion. CONSTITUTION:A compound of formula I, for example, synthesized by adding a Grignard reagent obtained by, for example, reacting 2-bromothiophene with metallic Mg to 2,5-dibromothiazole and condensing the mixture together with a supporting electrolyte comprising an anion-forming substance such as tetrafluoroborate, perchlorate, hexafluorophosphate, halide, SO4 or trifluoroacetate ion is electrolytically polymerized in a polar solvent such as propylene carbonate by using gold, platinum or the like as an electrode at a controlled electric quantity in an inert atmosphere. In this way, an anion-doped thiophene of repeating units of formula II (wherein R is a group of formula III, IV or V) having an electric conductivity of 10 -10 S/cm and a desired film thickness can be obtained. If desired, this polymer is converted into a thiophene polymer in a neutral state by removing the dopant by reversing the polarity.

    ELECTRICALLY CONDUCTIVE POLYMER COMPOSITION AND PRODUCTION THEREOF
    6.
    发明专利
    ELECTRICALLY CONDUCTIVE POLYMER COMPOSITION AND PRODUCTION THEREOF 失效

    公开(公告)号：JPS61209223A

    公开(公告)日：1986-09-17

    申请号：JP4681685

    申请日：1985-03-09

    Applicant: AGENCY IND SCIENCE TECHN

    Inventor： SATO MASAAKI ,  TANAKA SUSUMU ,  KAERIYAMA KYOJI ,  SUDA MASAO

    IPC: C08G61/00 ,  C08G61/10 ,  C08G61/12 ,  H01B1/12

    Abstract: PURPOSE:To obtain an electrically conductive polymer composition having high electrical conductivity and composed of poly-[2,5-(3-ethylthienylene)] doped with an anion and obtained by the electrolytic polymerization of 3-ethylthiophene in a medium containing an anion-containing supporting electrolyte. CONSTITUTION:An electrically conductive polymer composition composed of poly[2,5-(3-ethylthienylene)] doped with an anion (preferably hexafluorophosphoric acid ion, etc.) and having an electrical conductivity of 150-270S/cm can be produced by the electrolytic polymerization of 3- ethylthiophene in a medium (preferably propylene carbonate) containing an anion-containing supporting electrolyte, preferably in an inert atmosphere. USE:Electronic device, polymeric material, etc.

    NEW PHENYLENE POLYMER, ITS PRODUCTION AND ORGANIC CONDUCTIVE MATERIAL USING THE POLYMER
    7.
    发明专利
    NEW PHENYLENE POLYMER, ITS PRODUCTION AND ORGANIC CONDUCTIVE MATERIAL USING THE POLYMER 失效

    公开(公告)号：JPH0967429A

    公开(公告)日：1997-03-11

    申请号：JP24511995

    申请日：1995-08-31

    Applicant: AGENCY IND SCIENCE TECHN ,  IBARAKI PREF GOV

    Inventor： TANAKA SUSUMU ,  ISO TOMOAKI

    IPC: C08G61/10 ,  C08G61/06 ,  H01B1/12

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject polymer consisting of a specific recurring unit, soluble in a solvent such as N,N-dimethylformamide, easily formed into a film, etc., capable of being reduced at a mild condition and useful as a substrate for an organic conductive material. SOLUTION: This polymer is a poly(benzonitrile) consisting of a recurring unit of formula I, and obtained e.g. by the polycondensation of a compound of formula II (X is Cl, Br or I) in the presence of a nickel halide, a substituted phosphine (e.g. triarylphosphine or trialkylphosphine) and zinc in a reaction solvent such as N,N-dimethylformamide or N,N-dimethylacetamide at 40-120 deg.C, especially at 50-80 deg.C under the atmosphere of an inert gas such as nitrogen or argon.

    ORGANIC SEMICONDUCTOR AND PRODUCTION THEREOF
    8.
    发明专利
    ORGANIC SEMICONDUCTOR AND PRODUCTION THEREOF 失效

    公开(公告)号：JPH02218716A

    公开(公告)日：1990-08-31

    申请号：JP4011189

    申请日：1989-02-20

    Applicant: AGENCY IND SCIENCE TECHN

    Inventor： TANAKA SUSUMU ,  KAERIYAMA KYOJI ,  YAMAUCHI AIZO

    IPC: C08G61/12 ,  C08G61/10 ,  H01B1/12

    Abstract: PURPOSE:To obtain an organic semiconductor, having specific recurring units and useful as electrode and display materials by carrying out electrolytic polymerization of a naphthalene compound having 2 thiophene rings and doping the resultant polymer with anions. CONSTITUTION:The objective semiconductor obtained by carrying out electrolytic polymerization of a naphthalene compound, expressed by formula I (thienyl groups are present on the same benzene ring or different benzene rings) and having 2 thiophene rings and doping the resultant polymer consisting of recurring units expressed by formula II with anions (preferably tetrafluoroborate ions, perchlorade ions, hexafluorophosphate ions, hexafluoroarsenate ions, iodide ions, bromide ions, chloride ions, fluoride ions, sulfate ions, hydrogensulfate ions, trifluoroacetate ions or p-toluenesulfonate ions).

    THIOPHENE POLYMER AND PRODUCTION THEREOF
    9.
    发明专利
    THIOPHENE POLYMER AND PRODUCTION THEREOF 失效

    公开(公告)号：JPS61209224A

    公开(公告)日：1986-09-17

    申请号：JP4681885

    申请日：1985-03-09

    Applicant: AGENCY IND SCIENCE TECHN

    Inventor： SATO MASAAKI ,  TANAKA SUSUMU ,  KAERIYAMA KYOJI ,  SUDA MASAO

    IPC: C08G61/00 ,  C08G61/10 ,  C08G61/12 ,  H01B1/12

    Abstract: PURPOSE:To produce novel poly-[2,5-(3-ethylthienylene)] useful as electronic devices, polymeric materials, optical materials, etc., by carrying out the electrolytic polymerization of 3-ethylthiophene, and subjecting the product to electrolytic reduction. CONSTITUTION:3-Ethylthiophene is subjected to the electrolytic polymerization in a solvent (e.g. propylene carbonate, etc.) containing supporting electrolyte (e.g. hexafluorophosphoric acid ion) and the product is subjected to the electrolytic reduction to obtain the objective polymer.

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