公开(公告)号：EP1117466A4

公开(公告)日：2003-02-26

申请号：EP99940797

申请日：1999-07-02

Applicant: ARCH DEV CORP ,  UNIV TENNESSEE RES CORP

Inventor： SPIRO ALEXANDRATOS ,  SHELLEY CHRISTOPHER A ,  HORWITZ E PHILIP ,  CHIARIZIA RENATO ,  GULA MICHAEL J ,  SUI XUE

IPC: B01J39/04 ,  B01J39/20 ,  B01J49/00 ,  C02F1/42 ,  C08F2/00 ,  C08J5/20 ,  B01J39/12 ,  C22B3/00

CPC classification number: C02F1/42 ,  B01J39/05 ,  B01J39/20 ,  B01J49/06 ,  C08J5/20

Abstract: A cross-linked water-insoluble ion exchange resin comprised of polymerized monomers having a phenyl ring is disclosed. A contemplated resin contains: (i) polymerized phenyl ring-containing monomers having a phosphonic acid ligand linked to the phenyl ring; (ii) about 2 to about 5 millimoles per gram (mmol/g) of phosphorous as phosphonic acid ligands; and (iii) a sufficient amount of a sulfonic acid ligand such that the ratio of mmol/g of phosphonic acid to mmol/g sulfonic acid is up to 3:1. A process for removing polyvalent metal cations from aqueous solution, and a process for removing iron (III) cations from acidic copper (II) cation-containing solutions that utilize the contemplated resin or other resins are disclosed.

Abstract translation: 由具有苯基环聚合的单体的交联的水不溶性离子交换树脂是游离缺失盘。 甲设想树脂含有：（i）聚合含环苯基具有链接到所述苯基环的膦酸配体单体，（ii）约2至磷作为膦酸配位体的每克约5毫摩尔（毫摩尔/克），和（iii ）检测磺酸配位体足够量做毫摩尔的比例/ g的膦酸的至毫摩尔/克的磺酸是至多3:1。 一种用于去除从wässrige溶液多价金属阳离子的方法，以及用于除去铁的工序（III）从酸性铜阳离子（II）含阳离子的溶液并利用所设想的树脂或其它树脂是游离缺失盘。

公开(公告)号：EP0988634A4

公开(公告)日：2002-11-20

申请号：EP98925207

申请日：1998-06-03

Applicant: ARCH DEV CORP

Inventor： HORWITZ E PHILIP ,  HINES JOHN J ,  CHIARIZIA RENATO ,  DIETZ MARK L

IPC: A61K51/12 ,  G21F9/00 ,  G21F9/12 ,  G21G4/08 ,  A61K51/00 ,  C01G29/00

CPC classification number: A61K51/1282 ,  G21F9/007 ,  G21F9/12 ,  G21G4/08

Abstract: A process for producing substantially impurity-free Bi-213 cations is disclosed. An aqueous acid feed solution containing Ac-225 cations is contacted with an ion exchange medium to bind the Ac-225 cations and form an Ac-225-laden ion exchange medium. The bound Ac-225 incubates on the ion exchange medium to form Bi-213 cations by radioactive decay. The Bi-213 cations are then recovered from the Ac-225-laden ion exchange medium to form a substantially impurity-free aqueous Bi-213 cation acid solution. An apparatus for carrying out this process is also disclosed.

公开(公告)号：EP0830190A4

公开(公告)日：1999-01-13

申请号：EP96916966

申请日：1996-06-03

Applicant: ARCH DEV CORP

Inventor： HORWITZ E PHILIP ,  CHIARIZIA RENATO ,  DIETZ MARK L

IPC: B01D15/08 ,  B01J20/32 ,  G21F9/06 ,  G21F9/12 ,  G21F9/30

CPC classification number: B01D15/08 ,  B01D15/36 ,  B01J20/286 ,  B01J20/3092 ,  B01J20/3204 ,  B01J20/321 ,  B01J20/3212 ,  B01J20/3246 ,  B01J2220/54 ,  B01J2220/56 ,  G21F9/06 ,  G21F9/12 ,  G21F9/30

Abstract: An extraction chromatographic material for extracting metal cations from a liquid stream. The extraction chromatographic material is prepared by adsorbing a diesterified methanediphosphonic acid on an inert particulate support.

公开(公告)号：CA2126222C

公开(公告)日：2003-01-28

申请号：CA2126222

申请日：1992-12-18

Applicant: ARCH DEV CORP ,  UNIV TENNESSEE RES CORP THE

Inventor： HORWITZ E PHILIP ,  ALEXANDRATOS SPIRO D ,  CHIARIZIA RENATO ,  GATRONE RALPH C

IPC: B01D15/04 ,  B01J39/12 ,  B01J39/20 ,  C08F230/02 ,  C08F8/36 ,  C08F220/14 ,  C08F220/44 ,  C08F220/56

Abstract: An ion exchange resin for extracting metal ions from a liquid waste stream. An ion excahnge resin is prepared by copolymerizing a vinylidene disphosphonic acid with styrene, acrylonitrile a nd divinylbenzene.

公开(公告)号：CA2292621C

公开(公告)日：2002-12-10

申请号：CA2292621

申请日：1998-06-03

Applicant: ARCH DEV CORP

Inventor： CHIARIZIA RENATO ,  HINES JOHN J ,  HORWITZ E PHILIP ,  DIETZ MARK L

IPC: A61K51/12 ,  G21F9/00 ,  G21F9/12 ,  G21G4/08 ,  C01G29/00 ,  A61K51/00

Abstract: A process for producing substantially impurity-free Bi-213 cations is disclosed. An aqueous acid feed solution containing Ac-225 cations is contacted with an ion exchange medium to bind the Ac-225 cations and form an Ac-225-laden ion exchange medium. The bound Ac-225 incubates on the ion exchange medium to form Bi-213 cations by radioactive decay. The Bi-213 cations are then recovered from the Ac-225-laden ion exchange medium to form a substantially impurity-free aqueous Bi-213 cation acid solution. An apparatu s for carrying out this process is also disclosed.

公开(公告)号：AU5457999A

公开(公告)日：2000-01-24

申请号：AU5457999

申请日：1999-07-02

Applicant: ARCH DEV CORP ,  UNIVERSITY OF TENNESSEE RESEARCH CORPORATION THE

Inventor： SPIRO ALEXANDRATOS ,  SHELLEY CHRISTOPHER A ,  HORWITZ E PHILIP ,  CHIARIZIA RENATO ,  GULA MICHAEL J ,  SUI XUE

IPC: B01J39/04 ,  B01J39/20 ,  B01J49/00 ,  C02F1/42 ,  C08F2/00 ,  C08J5/20 ,  B01D11/00

Abstract: A cross-linked water-insoluble ion exchange resin comprised of polymerized monomers having a phenyl ring is disclosed. A contemplated resin contains (i) polymerized phenyl ring-containing monomers having a phosphonic acid ligand linked to the phenyl ring, (ii) about 2 to about 5 millimoles per gram (mmol/g) of phosphorus as phosphonic acid ligands, and (iii) a sufficient amount of a sulfonic acid ligand such that the ratio of mmol/g of phosphonic acid to mmol/g sulfonic acid is up to 3:1. A process for removing polyvalent metal cations from aqueous solution, and a process for removing iron(III) cations from acidic copper(II) cation-containing solutions that utilize the contemplated resin or other resins are disclosed.

公开(公告)号：AU7816198A

公开(公告)日：1998-12-21

申请号：AU7816198

申请日：1998-06-04

Applicant: ARCH DEV CORP

Inventor： DIETZ MARK L ,  HORWITZ E PHILIP ,  CHIARIZIA RENATO ,  BARTSCH RICHARD A

IPC: C22B60/00 ,  G21F9/12 ,  B01D39/00 ,  B01D39/18 ,  C02F1/42

Abstract: A process for preconcentrating and separating radium from a contaminated solution containing at least water and radium includes the steps of adding a quantity of a water-soluble macrocyclic polyether to the contaminated solution to form a combined solution. An acid is added to the combined solution to form an acidic combined solution having an [H+] concentration of about 0.5M. The acidic combined solution is contacted with a sulfonic acid-based strong acid cation exchange medium or a organophilic sulfonic acid medium having a plurality of binding sites thereon to bind the radium thereto and to form a radium-depleted solution. The radium-depleted solution is separated from the strong acid cation exchange medium or organophilic sulfonic acid medium. The radium remaining bound to the exchange medium or organophilic reagent is then stripped from the exchange medium or organophilic medium and the activity of the radium is measured.

公开(公告)号：PE20000981A1

公开(公告)日：2000-09-29

申请号：PE00062199

申请日：1999-07-02

Applicant: ARCH DEV CORP ,  UNIV TENNESSEE RES CORP

Inventor： GULA MICHAEL J ,  ALEXANDRATOS SPIRO ,  CHIARIZIA RENATO ,  HARVEY JAMES T ,  XUE SUI ,  SHELLY CHRISTOPHER A ,  HORWITZ E PHILIP

IPC: B01J39/04 ,  B01J39/20 ,  B01J49/00 ,  C02F1/42 ,  C08J5/20

Abstract: EN DONDE DICHA RESINA COMPRENDE : i) MONOMEROS POLIMERIZADOS QUE CONTIENEN UN ANILLO DE FENILO Y QUE TIENEN UN LIGANDO DE ACIDO FOSFONICO ENLAZADO AL ANILLO DE FENILO; ii) ENTRE 2 mmol/g Y 5 mmol/g DE FOSFORO COMO LIGANDOS DE ACIDO FOSFONICO; Y iii) UNA CANTIDAD SUFICIENTE DE UN LIGANDO DE ACIDO SULFONICO DE MANERA QUE LA RELACION DE mmol/g DE ACIDO FOSFONICO A mmol/g DE ACIDO SULFONICO ES HASTA 3:1. ADEMAS SE REFIERE A UN PROCESO PARA RETIRAR CATIONES DE METALES POLIVALENTES A PARTIR DE UNA SOLUCION ACUOSA, Y UN PROCESO PARA RETIRAR CATIONES DE HIERRO (III) A PARTIR DE SOLUCIONES ACIDAS QUE CONTIENEN CATIONES DE COBRE (II) UTILIZANDO LA RESINA O RESINAS CONTEMPLADAS EN EL MISMO

公开(公告)号：AU5967496A

公开(公告)日：1996-12-24

申请号：AU5967496

申请日：1996-06-03

Applicant: ARCH DEV CORP

Inventor： HORWITZ E PHILIP ,  CHIARIZIA RENATO ,  DIETZ MARK L

IPC: B01D15/08 ,  B01J20/32 ,  G21F9/06 ,  G21F9/12 ,  G21F9/30

Abstract: An extraction chromatographic material for extracting metal cations from a liquid stream. The extraction chromatographic material is prepared by adsorbing a diesterified methanediphosphonic acid on an inert particulate support.

公开(公告)号：CA2081767A1

公开(公告)日：1991-10-31

申请号：CA2081767

申请日：1991-04-26

Applicant: ARCH DEV CORP

Inventor： HORWITZ EARL P ,  CHIARIZIA RENATO

IPC: C01B17/66 ,  B09C1/02 ,  C01G49/02 ,  C02F1/70 ,  C02F1/72 ,  C02F5/00 ,  C02F5/08 ,  C02F5/10 ,  C02F5/12 ,  C02F5/14 ,  C02F101/10 ,  C02F101/20 ,  C09K3/00 ,  C11D3/36 ,  C22B3/00 ,  C23G1/08 ,  D06L1/12 ,  G21F9/00 ,  C23F1/16

Abstract: A mixture of a di- or polyphosphonic acid and a reductant wherein each is present in a sufficient amount to provide a synergistic effect with respect to the dissolution of metal ozides and optionally containing corrosion inhibitors and pH adjusting agents.