公开(公告)号：WO2022169796A1

公开(公告)日：2022-08-11

申请号：PCT/US2022/014828

申请日：2022-02-02

Applicant: ARKEMA INC.

Inventor： YANG, Lei ,  KIM, Kyu-Jun ,  SCHNEIDER, Jeffrey A. ,  WU, Wenjun ,  CAO, Jinbao

IPC: C08L33/14 ,  C08L63/00 ,  C08L63/10

Abstract: Waterborne dispersions including crosslinkable multistage polymeric particles useful in coating compositions are provided. The multistage particles have a last-formed layer that includes a diketone functionality that is capable of crosslinking via a dihydrazide component also included in the dispersion. Another embodiment of the waterborne dispersion further includes crosslinkable latex particles having a diketone functionality that are capable of crosslinking with each other and/or the multistage particles via the dihydrazide component. An emulsion polymerization process for forming the multistage particles also is provided. Also provided are coating compositions that contain either embodiment of the waterborne dispersions.

公开(公告)号：WO2018200488A1

公开(公告)日：2018-11-01

申请号：PCT/US2018/029097

申请日：2018-04-24

Applicant: ARKEMA INC.

Inventor： KIM, Kyu-Jun ,  ARENDT, Jeffrey P.

IPC: C08G63/49 ,  C03C25/323 ,  C09D5/02

Abstract: A dispersion of an alkyd-containing polymer dispersed in water is used to form a waterborne coating composition; the alkyd-containing polymer being an acrylic-modified alkyd polymer, a silicone-acrylic-modified alkyd polymer, or a mixture thereof. The resulting waterborne coating composition includes about 2 to about 30 % by weight of one or more thermal insulating fillers with the remainder being the alkyd-containing dispersion, such that the coating composition contains about 30 to about 80% by weight of the water and about 2 to about 50% by weight of the alkyd-containing polymer. The coating applied therefrom exhibits at least one of the following properties: a thermal conductivity that is less than 100 mW/mK; a weight retention of at least 70% after being heated up to 400C as measured by thermogravimetric analysis (TGA) with a heating rate of 20C/min.; or a weight loss of less than 50% up to a temperature of 470C as measured by the TGA.

公开(公告)号：WO2015195466A1

公开(公告)日：2015-12-23

申请号：PCT/US2015/035450

申请日：2015-06-12

Applicant: ARKEMA INC.

Inventor： DEVONPORT, Wayne ,  WU, Wenjun ,  KIM, Kyu-Jun

IPC: C08F8/30 ,  C08F283/00 ,  C08G18/62

CPC classification number: C09D175/04 ,  C08F8/30 ,  C08G18/62 ,  C08G18/6254 ,  C08G18/672 ,  C08G18/6755 ,  C08G18/755 ,  C08G18/758

Abstract: A latex comprising a urethane linkage and having a high solids content and a low viscosity is described herein. Also described is a process for making the urethane linkage-containing latex wherein urethane linkage formation and emulsion polymerization take place in the same processing step.

Abstract translation: 本文描述了包含氨基甲酸酯键并且具有高固体含量和低粘度的胶乳。 还描述了制备含氨基甲酸酯键的胶乳的方法，其中在相同的加工步骤中发生氨基甲酸酯键形成和乳液聚合。

公开(公告)号：WO2015077677A1

公开(公告)日：2015-05-28

申请号：PCT/US2014/067023

申请日：2014-11-24

Applicant: ARKEMA INC.

Inventor： KIM, Kyu-Jun

IPC: C08F8/30

CPC classification number: C08F8/30 ,  C08F8/00 ,  C08G18/0823 ,  C08G18/36 ,  C08G18/4288 ,  C08G18/758 ,  C08G2150/90 ,  C08G2170/80 ,  C09D11/105 ,  C09D151/08 ,  C09D175/06

Abstract: A water-borne, urethane and acrylic modified alkyd dispersion, wherein the dispersion is substantially surfactant free and has less than 1 weight % volatile organic compounds (VOCs) is described. Additionally, a method for preparing a water-borne, substantially surfactant free, urethane and acrylic modified alkyd dispersion, with less than 1 weight % VOC, is described. In the method, an acrylic modified alkyd polymer is reacted with a basic compound in water to form an acrylic modified alkyd dispersion having a first viscosity and then a hydrophobic seed is added thereto to form a urethane and acrylic modified alkyd dispersion having a second viscosity, which is substantially less than the first viscosity.

Abstract translation: 描述了水性，氨基甲酸乙酯和丙烯酸改性醇酸树脂分散体，其中分散体基本上不含表面活性剂且具有小于1重量％的挥发性有机化合物（VOC）。 另外，描述了制备具有小于1重量％VOC的水性基本上无表面活性剂的氨基甲酸酯和丙烯酸改性醇酸树脂分散体的方法。 在该方法中，丙烯酸改性醇酸树脂聚合物与水中的碱性化合物反应形成具有第一粘度的丙烯酸改性醇酸树脂分散体，然后向其中加入疏水种子以形成具有第二粘度的氨基甲酸酯和丙烯酸改性醇酸树脂分散体， 其大大小于第一粘度。

公开(公告)号：WO2020068582A1

公开(公告)日：2020-04-02

申请号：PCT/US2019/052155

申请日：2019-09-20

Applicant: ARKEMA INC.

Inventor： KIM, Kyu-Jun

IPC: C07D493/04 ,  C07H13/06 ,  C08G63/48 ,  C08K5/053 ,  C08K5/092 ,  C09D167/08

Abstract: An alkyd polymer composition for fast-drying, low VOC applications is provided. The alkyd polymer incorporates a minimum required level of a cyclic ether- and hydroxyl-containing composition formed from a sugar alcohol during the alcoholysis step while synthesizing the alkyd polymer. The disclosure also relates to the cyclic ether- and hydroxyl-containing composition which must have a minimum required level of cyclic ether structure incorporated therein in order to produce a sufficiently fast-drying alkyd polymer. Methods of making the cyclic ether- and hydroxyl-containing composition and the alkyd polymer comprising, as polymerized units, the cyclic ether- and hydroxyl-containing composition and a poly acid and/or an anhydride compound, as well as an optional polyol, other than the sugar alcohol, are also provided. Also provided is a 13C NMR method of characterizing the necessary minimum required level of cyclic ether ring structure in the cyclic ether- and hydroxyl-containing composition and the alkyd polymer formed therefrom.

公开(公告)号：WO2016209691A1

公开(公告)日：2016-12-29

申请号：PCT/US2016/037750

申请日：2016-06-16

Applicant: ARKEMA INC.

Inventor： KIM, Kyu-Jun ,  HU, Rong ,  KAUFMAN, Michael C.

IPC: C08L79/00 ,  C08L79/02 ,  C09D179/00 ,  C09D179/02

CPC classification number: C08G73/024 ,  C08L25/08 ,  C08L57/06 ,  C08L79/02 ,  C08L2201/52 ,  C09D5/004 ,  C09D7/65 ,  C09D125/08 ,  C09D157/06 ,  C09J11/08 ,  C09J157/06 ,  C08L21/02

Abstract: A latex product composition that includes an anionicaily-stabilized latex; at least one volatile base compound; and one or more water soluble, polymers or polymeric adducts that have a backbone with a plurality of amine functional groups and hydroxyl functional groups. The polymers or polymeric adducts may be an addition product formed from at least one multifunctional amine compound reacted with one or more polyfunctional epoxy compounds, one or more monofunctional epoxy compounds, or a combination thereof. The polymers or polymeric adducts are formed by the addition reaction of the amine compound and the one or more epoxy compounds with 1.3 to 3.8 amine functional group per epoxy functional group. The addition product may be present in about 0.1 to 15.0 wt. % and the at least one volatile base compound is present in about 1.0 wt. % to 10.0 wt. % based on the weight of the particles present in the anionicaily-stabilized latex.

Abstract translation: 一种乳胶产品组合物，其包含阴离子型稳定的胶乳; 至少一种挥发性碱性化合物; 和一种或多种具有多个胺官能团和羟基官能团的骨架的水溶性聚合物或聚合物加合物。 聚合物或聚合物加合物可以是由至少一种与一种或多种多官能环氧化合物，一种或多种单官能环氧化合物或其组合反应的多官能胺化合物形成的加成产物。 通过胺化合物和一种或多种环氧化合物与每个环氧官能团具有1.3至3.8个胺官能团的环氧化合物的加成反应形成聚合物或聚合物加合物。 加成产物可以以约0.1至15.0wt。 ％，并且至少一种挥发性碱性化合物以约1.0wt。 ％〜10.0重量％ 基于阴离子稳定的胶乳中存在的颗粒的重量％。

公开(公告)号：WO2021146083A1

公开(公告)日：2021-07-22

申请号：PCT/US2021/012296

申请日：2021-01-06

Applicant: ARKEMA INC.

Inventor： KIM, Kyu-Jun

IPC: C08F20/10 ,  C08G18/42 ,  C08G18/76

Abstract: The present invention relates to a polyester-urethane composition. In particular, the invention relates to aliphatic alkyl ring-containing compositions that are useful for producing ultraviolet light resistant coatings. The invention further relates to pigmented and clear coating compositions formulated with the polyester-urethane composition of the present invention. The polyester-urethane compositions may be crosslinked.

公开(公告)号：WO2016209796A1

公开(公告)日：2016-12-29

申请号：PCT/US2016/038478

申请日：2016-06-21

Applicant: ARKEMA INC.

Inventor： KIM, Kyu-Jun ,  HU, Rong ,  GROVE, Jeremy L.

IPC: C08G59/18

CPC classification number: C08G59/5006 ,  C08G59/223 ,  C08G59/226 ,  C08G65/2624 ,  C08L63/00 ,  C08L2201/54

Abstract: A water soluble polymer or polymeric adduct has a backbone comprising a plurality of segments with amine functional groups and hydroxyl functional groups with a number average molecular weight in the range of about 500 to about 1,000,000 Daltons. The polymeric adduct may be formed as an addition product by reacting at least one multifunctional amine compound reacted with a one or more polyfunctional epoxy compounds and/or one or more monofunctional epoxy compounds, such that there are 1.3 to 3.8 reactive amine functional groups per reactive epoxy functional group. An aqueous solution of the polymer or polymeric adduct has a viscosity in the range of about 100 centipoise to about 100,000 centipoise and a pH value of about 8 to about 12 when the solution comprises 70 wt.% of the polymer or polymeric adduct dissolved in water. The polymeric adducts are useful fast setting additives for an emulsion product due to excellent stability when blended with an anionically stabilized latex.

Abstract translation: 水溶性聚合物或聚合物加合物具有主链，其包含具有胺官能团的多个链段和数均分子量在约500至约1,000,000道尔顿范围内的羟基官能团。 聚合加合物可以通过使至少一种与一种或多种多官能环氧化合物和/或一种或多种单官能环氧化合物反应的多官能胺化合物反应形成为加成产物，使得每个反应性有1.3-3.8个反应性胺官能团 环氧官能团。 聚合物或聚合物加合物的水溶液的粘度范围为约100厘泊至约100,000厘泊，pH值为约8至约12，当溶液包含70重量％的溶于水中的聚合物或聚合物加合物 。 当与阴离子稳定的胶乳混合时，由于优异的稳定性，聚合加合物是用于乳液产品的有用的快速固化添加剂。

公开(公告)号：WO2016209692A1

公开(公告)日：2016-12-29

申请号：PCT/US2016/037753

申请日：2016-06-16

Applicant: ARKEMA INC.

Inventor： GROVE, Jeremy L. ,  KIM, Kyu-Jun ,  HU, Rong ,  DEVONPORT, Wayne

IPC: C08L79/00 ,  C08L79/02 ,  C09D179/00 ,  C09D179/02

CPC classification number: C08G73/024 ,  C08G65/2624 ,  C08L25/14 ,  C08L33/04 ,  C08L33/08 ,  C08L35/02 ,  C08L79/02 ,  C09D179/02 ,  C09J7/38 ,  C09J179/02

Abstract: A latex product composition that includes an anionically-stabilized latex and one or more water soluble, polymers or polymeric adducts that have a backbone with a plurality of amine functional groups and hydroxyl functional groups. The polymers or polymeric adducts may be an addition product formed from at least one multifunctional amine compound reacted with one or more polyfunctional epoxy compounds, one or more monofunctional epoxy compounds, or a combination thereof. The amine compound and the one or more epoxy compounds are reacted to form polymers or polymeric adducts with the molar equivalent ratio of 1.3 to 3.8 amine functional group per epoxy functional group. The addition product may be present in about 0.1 to 15.0 wt. % and the at least one volatile base compound is present in about 1.0 wt. % to 10.0 wt. % based on the weight of the particles present in the anionically-stabilized latex.

Abstract translation: 一种乳胶产品组合物，其包含阴离子稳定的胶乳和一种或多种具有多个胺官能团和羟基官能团的骨架的水溶性聚合物或聚合物加合物。 聚合物或聚合物加合物可以是由至少一种与一种或多种多官能环氧化合物，一种或多种单官能环氧化合物或其组合反应的多官能胺化合物形成的加成产物。 胺化合物和一种或多种环氧化合物反应形成聚合物或聚合物加合物，其摩尔当量比为每个环氧官能团1.3-3.8胺官能团。 加成产物可以以约0.1至15.0wt。 ％，并且至少一种挥发性碱性化合物以约1.0wt。 ％〜10.0重量％ 基于存在于阴离子稳定的胶乳中的颗粒的重量％。

公开(公告)号：WO2016073260A1

公开(公告)日：2016-05-12

申请号：PCT/US2015/057929

申请日：2015-10-29

Applicant: ARKEMA INC.

Inventor： KIM, Kyu-Jun ,  STARK, Daniel E. ,  ARENDT, Jeffrey P.

IPC: C08F283/00 ,  C08F2/44 ,  C09D167/00 ,  C08J3/02

CPC classification number: C08F283/01 ,  C08F2/24 ,  C09D167/00 ,  C09D167/06 ,  C09D167/08

Abstract: A latex particle comprises an interior core and an outer shell. The core comprises an acrylic or vinyl polymer, and the shell comprises a water soluble alkyd polymer and at least one surfactant. Substantially all or all of the alkyd polymer is present in the shell of the latex particle and substantially none or none or the alkyd polymer is present in the core of the latex particle. Also described is a process for making the latex particle wherein the water soluble alkyd polymer is present as a co-surfactant during polymerization.

Abstract translation: 胶乳颗粒包括内芯和外壳。 芯包含丙烯酸或乙烯基聚合物，壳包含水溶性醇酸聚合物和至少一种表面活性剂。 基本上全部或全部醇酸聚合物存在于胶乳颗粒的壳体中，基本上没有或没有或醇酸聚合物存在于胶乳颗粒的芯中。 还描述了制备胶乳颗粒的方法，其中在聚合期间水溶性醇酸聚合物作为助表面活性剂存在。