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    EMULSION POLYMER COMPOSITION AND USE THEREOF IN LOW ODOR WATERPROOFING COATINGS
    2.
    发明申请
    EMULSION POLYMER COMPOSITION AND USE THEREOF IN LOW ODOR WATERPROOFING COATINGS 审中-公开

    公开(公告)号：WO2019100235A1

    公开(公告)日：2019-05-31

    申请号：PCT/CN2017/112269

    申请日：2017-11-22

    Applicant: ARKEMA FRANCE ,  ARKEMA INC. ,  ZHOU, Hua

    Inventor： ZHOU, Hua ,  CHEN, Haiming ,  WU, Wenjun ,  MENG, Xiangling ,  SAIJA, Leo-Mario ,  LUGLI, Mario

    IPC: C08F220/18 ,  C08F212/08 ,  C08F220/06 ,  C08F222/02 ,  C09D133/08

    Abstract: An aqueous polymer dispersion, said polymer comprises polymerized units issued from the following monomers with related weight proportions based on 100 parts of weight of a) +b) : a) 50 to 90% of a monoethylenically unsaturated non-ionic monomer, b) 10 to 50% of a vinyl aromatic monomer or of methyl methacrylate, c) 1 to 5% of a hydroxy-containing (meth) acrylate, d) 0.1 to 3% of an acid monomer selected from d1) an acid monomer selected from a monocarboxylic or dicarboxylic acid monomers and d2) an acid monomer selected from phosphorous-based or sulfur-based strong acid monomers or/and their salts, or from the mixtures of d1) and d2), e) 0.001 to 0.5% of a chain transfer agent, and f) 0 to 1% one of an internal crosslinker bearing at least two copolymerisable ethylenic unsaturations, the said polymer has a Tg measured by DSC from -30 to 0 ℃ and a gel content of 0 to 60%, formed during the polymerization. In addition, a specific process of preparation of said dispersion, a coating composition comprising said dispersion, uses of said dispersion in waterproofing cementitious waterproofing coatings and the final waterproofing coating resulting therefrom were provided.

    STORAGE STABLE LATEX-SILICATE DISPERSION
    5.
    发明申请
    STORAGE STABLE LATEX-SILICATE DISPERSION 审中-公开

    公开(公告)号：WO2022251186A1

    公开(公告)日：2022-12-01

    申请号：PCT/US2022/030687

    申请日：2022-05-24

    Applicant: ARKEMA INC.

    Inventor： LI, Yang ,  WU, Wenjun ,  SCHNEIDER, Jeffrey A.

    IPC: C09D1/02 ,  C09D133/04 ,  C09D125/02

    Abstract: A one-part composition includes by wt% of total weight of the composition: a) 5 to 70 wt% of at least one emulsified polymeric binder, the binder comprising one or more of (meth)acrylamide or derivatives thereof as a polymerized monomer; b) 1 to 55 wt% of at least one silicate; c) 0.01 to 10 wt% of at least one alkyl siliconate; d) water, and e) optional additives. The binder a) includes (meth)acrylamide or derivative thereof as a polymerized monomer and is in the form of emulsified polymeric particles having a volume average particle size of 50 nm - 500 nm.

    COATING COMPOSITION WITH IMPROVED BLOCK AND HUMIDITY RESISTANCE, DIRECT TO METAL ADHERENCE AND LOW VOC CONTENT
    6.
    发明申请
    COATING COMPOSITION WITH IMPROVED BLOCK AND HUMIDITY RESISTANCE, DIRECT TO METAL ADHERENCE AND LOW VOC CONTENT 审中-公开

    公开(公告)号：WO2022051168A1

    公开(公告)日：2022-03-10

    申请号：PCT/US2021/047755

    申请日：2021-08-26

    Applicant: ARKEMA INC.

    Inventor： LI, Yuting ,  EISENHARDT, Robert P. ,  WU, Wenjun ,  DREWERY, Michael ,  ARDENT, Jeffrey P.

    IPC: C08F265/06 ,  C08K5/523 ,  C09D151/00 ,  C09D151/06

    Abstract: Multi-stage polymeric particles are prepared as a water-borne emulsion, including a first-formed lower Tg soft stage and a second-formed higher Tg hard stage. The polymeric particles include, in both stages: one or more free radical polymerizable ethylenically unsaturated monomers; 0 to 3 wt% of free radical polymerizable surfactant monomer; 0 to 4 wt% of free radical polymerizable monomer having a beta dicarbonyl functionality; 0 to 2 wt% of monomer selected from acrylamide, diacetone acrylamide, 2-hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylates, and hydroxybutyl (meth)acrylates and mixtures thereof; 0-1.9 wt% of free radical polymerizable polyethylenically unsaturated monomers; 0.1 to 1.9% of free radical polymerizable monomer containing phosphorus acid or a salt thereof in the first stage, and 0.1 to 5 wt% of a free radical polymerizable monomer containing phosphorus acid or salt thereof in the second stage. Multi-stage polymeric-particle-based-resin is formulated into direct to metal coatings, having good block, corrosion and excellent humidity resistance.

    STORAGE STABLE PIGMENTED COATING COMPOSITION
    7.
    发明申请
    STORAGE STABLE PIGMENTED COATING COMPOSITION 审中-公开

    公开(公告)号：WO2022251190A1

    公开(公告)日：2022-12-01

    申请号：PCT/US2022/030693

    申请日：2022-05-24

    Applicant: ARKEMA INC.

    Inventor： YANG, Lei ,  WU, Wenjun ,  SCHNEIDER, Jeffrey A.

    IPC: B05D3/10 ,  B05D7/00 ,  B05D7/14

    Abstract: A method of coating a cementitious and/or masonry substrate includes applying an aqueous coating composition to the cementitious and/or masonry substrate. The aqueous coating composition includes at least one pigment, optionally at least one filler, at least one emulsified polymeric binder, at least one water-soluble silicate, and optionally at least one additive. The emulsified polymeric binder includes at least one of: a) (meth)acrylamide or derivative thereof as a polymerized monomer; or b) 1 weight % or more of at least one surfactant based on the total dry weight of the total monomer in the emulsified polymeric binder. The aqueous coating composition has a weight ratio of emulsified polymeric binder to the water-soluble silicate from 65:35 to 95:5 on a dry weight basis. The aqueous coating composition also has a pigment volume concentration (PVC) from 5% to 85.

    POLYMER LATEX BINDERS USEFUL IN ZERO OR LOW VOC COATING COMPOSITIONS
    9.
    发明申请
    POLYMER LATEX BINDERS USEFUL IN ZERO OR LOW VOC COATING COMPOSITIONS 审中-公开
    POLYMER LATEX BINDERS有用的零或低VOC涂料组合物

    公开(公告)号：WO2013119523A1

    公开(公告)日：2013-08-15

    申请号：PCT/US2013/024700

    申请日：2013-02-05

    Applicant: ARKEMA INC.

    Inventor： WU, Wenjun ,  GUO, Jihiu ,  SCHNEIDER, Jeffrey A.

    IPC: C08F283/00

    CPC classification number: C08F265/06 ,  C08F2/26 ,  C08F220/14 ,  C08F283/065 ,  C08F290/062 ,  C09D113/02 ,  C09D151/003 ,  C09D151/08 ,  C08F2220/1825 ,  C08F220/18

    Abstract: Polymer latex binders useful for preparing coating compositions containing low levels of, or which are substantially free of, volatile organic compounds (VOCs) such as volatile freeze-thaw additives are prepared by multistage emulsion polymerization, wherein one stage provides a copolymer having a relatively high glass transition temperature and containing an oxyalkylene-containing (meth)acrylate comonomer.

    Abstract translation: 可用于制备含有低含量或基本上不含挥发性有机化合物（VOC）的挥发性冻融添加剂的涂料组合物的聚合物胶乳粘合剂通过多阶段乳液聚合制备，其中一个阶段提供具有相对较高的共聚物 玻璃化转变温度并含有含氧化烯的（甲基）丙烯酸酯共聚单体。

    HYBRID PAINT COMPOSITIONS INCLUDING INORGANIC AND ORGANIC BINDERS
    10.
    发明申请
    HYBRID PAINT COMPOSITIONS INCLUDING INORGANIC AND ORGANIC BINDERS 审中-公开

    公开(公告)号：WO2022251192A1

    公开(公告)日：2022-12-01

    申请号：PCT/US2022/030696

    申请日：2022-05-24

    Applicant: ARKEMA INC.

    Inventor： YANG, Lei ,  WU, Wenjun ,  SCHNEIDER, Jeffrey A.

    IPC: C09D1/02 ,  C09D5/02 ,  C09D7/43

    Abstract: An aqueous composition for coating cementitious or masonry substrates is provided. When dried, the coating composition has high gloss and low dirt pick-up. The composition includes at least one emulsified polymeric binder; at least one water-soluble silicate; at least one alkyl siliconate; at least one pigment, optionally at least one filler; optionally at least one paint additive; and water. The pigment volume concentration (PVC) of the aqueous composition is 40 weight % or less.

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