Abstract:
Methods for controlling the grain structure of a polycrystalline Si-containing film involve depositing the film in stages so that the morphology of a first film layer deposited in an initial stage favorably influences the morphology of a second film layer deposited in a later stage. In an illustrated embodiment, the initial stage includes an anneal step. In another embodiment, the later stage involves depositing the second layer under different deposition conditions than for the first layer.
Abstract:
Multiple sequential processes 140 are conducted in a reaction chamber to form ultra high quality silicon-containing compound layers, including silicon nitride layers. In a preferred embodiment, a silicon layer is deposited 100 on a substrate using trisilane as the silicon precursor. The silicon precursor is removed 110 from the reaction chamber. A silicon nitride layer is then formed by nitriding 120 the silicon layer. The nitrogen reactant is removed 110 from the reaction chamber. By repeating these steps 100, 110, 120 and 130, a silicon nitride layer of a desired thickness is formed.