Abstract:
A method for preparing a catalytic composition for the olefin polymerization in the form of a dispersion of catalyst particles in a semi-fluid matrix, characterized in that it comprises the steps of: a) forming a suspension of catalyst particles in oil by loading under a continuous stirring dry catalyst powder into a tank containing said oil, the load velocity of the catalyst powder per m 2 of oil interface being less of 800 kg/h*m 2 ; b) adding under stirring a molten thickening agent having a melting point in a range from 30 to 70°C, while maintaining the catalyst suspension in oil at a temperature such that said thickening agent solidifies on contact with said suspension.
Abstract translation:制备催化剂颗粒在半流体基质中的分散体形式的用于烯烃聚合的催化组合物的方法,其特征在于其包括以下步骤:a)在催化剂颗粒在油中形成悬浮液, 将连续搅拌的干燥催化剂粉末连续搅拌到含有所述油的罐中,每m 2油界面的催化剂粉末的负载速度小于800kg / h * m 2; b)在搅拌下加入熔点为30-70℃的熔融增稠剂,同时将催化剂悬浮液保持在使所述增稠剂与所述悬浮液接触时固化的温度。
Abstract:
Prepolymerized catalyst component for the polymerization of olefins CH 2 =CHR, wherein R is hydrogen or a C 1 -C 12 hydrocarbyl group, comprising a solid catalyst component characterized by comprising Mg, Ti halogen and an electron donor (ID) selected from the alkyl esters of aromatic dicarboxylic acids in such an amount that the molar ratio ID/Mg ranges from 0.025 to 0.07 and the Mg/Ti molar ratio is higher than 13, said prepolymerized catalyst component containing an amount of ethylene pre-polymer up to 5Og per g of said solid catalyst component.
Abstract:
A Prepolymerized catalyst component for the polymerization of olefins comprising a solid catalyst component which comprises Mg, Ti, and chlorine atoms and an electron donor (ID) said prepolymerized catalyst component being characterized by the fact that: - the electron donor (ID) is constituted by at least 80%mol of 1,3 diethers with respect to the total molar amount of electron donor compounds; -the prepolymerized catalyst has a porosity due to pores with diameters up to Ιμιη of less than 0.2 cm3/g; -it contains an amount of ethylene prepolymer of less than 45% with respect to the total weight of prepolymerized catalyst.
Abstract:
Prepolymerized catalyst component for the polymerization of olefins CH 2 =CHR, wherein R is hydrogen or a C 1 -C 12 hydrocarbyl group, comprising a solid catalyst component characterized by comprising Mg, Ti halogen and an electron donor (ID) selected from the alkyl esters of aromatic dicarboxylic acids in such an amount that the molar ratio ID/Mg ranges from 0.025 to 0.07 and the Mg/Ti molar ratio is higher than 13, said prepolymerized catalyst component containing an amount of ethylene pre-polymer up to 5Og per g of said solid catalyst component.
Abstract:
A gas-phase process for the homopolymerization or copolymerization of propylene with other olefins, including carrying out the polymerization in the presence of a catalyst system made from or containing: (a) a solid catalyst component made from or containing Mg, Ti, halogen, an electron donor selected from 1.3-diethers and an olefin polymer in a specific amount; (b) an aluminum alkyl compound and (c) an external electron donor (ED) compound, wherein components (b) and (c) being employed in amounts such that the Al/(ED) molar ratio ranges from about 2 to about 200.
Abstract:
A method for preparing a catalytic composition for the olefin polymerization in the form of a dispersion of catalyst particles in a semi-fluid matrix, characterized in that it comprises the steps of: a) forming a suspension of catalyst particles in oil by loading under a continuous stirring dry catalyst powder into a tank containing said oil, the load velocity of the catalyst powder per m2 of oil interface being less of 800 kg/h*m2; b) adding under stirring a molten thickening agent having a melting point in a range from 30 to 70°C, while maintaining the catalyst suspension in oil at a temperature such that said thickening agent solidifies on contact with said suspension.