公开(公告)号：DE4344211A1

公开(公告)日：1995-06-29

申请号：DE4344211

申请日：1993-12-23

Applicant: BASF AG

Inventor： BAKLENHOHL FRIEDHELM DR ,  HAUER BERNHARD DR ,  LADNER WOLFGANG DR ,  PRESSLER UWE DR ,  RETTENMAIER HANSJOERG DR ,  ADAM GEO DR

IPC: C12N9/20 ,  C12N9/96 ,  C07B41/12 ,  C07C53/126 ,  C07C69/22 ,  C12N9/14 ,  C12N9/18

公开(公告)号：DE4407985A1

公开(公告)日：1994-09-22

申请号：DE4407985

申请日：1994-03-10

Applicant: BASF AG

Inventor： ADAM GEO DR ,  MUNDINGER KLAUS DR

IPC: C07C51/373 ,  C07C67/313 ,  C07C69/738 ,  C07C59/84 ,  C07C67/303

Abstract: Process for the preparation of benzylpyruvic acids and their esters of the general formula I in which R represents hydrogen, an aliphatic, cycloaliphatic or aromatic radical, X represents an inert substituent and n can denote 0 to 5, it being possible for the substituents X to be different if n > 1, by reacting alpha -hydroxy- beta , gamma -unsaturated carboxylic acids or their esters of the general formula II in the presence of noble metals of Groups 8 to 10 of the Periodic Table to give I.

公开(公告)号：DE4308078A1

公开(公告)日：1994-09-15

申请号：DE4308078

申请日：1993-03-13

Applicant: BASF AG

Inventor： RIECHERS HARTMUT DR ,  ADAM GEO DR ,  MUENTER KLAUS DR ,  HAFNER MATHIAS DR

IPC: C07C237/22 ,  C07C317/44 ,  C07D295/215 ,  A61K31/195 ,  C07C315/04

公开(公告)号：DE4243030A1

公开(公告)日：1994-06-23

申请号：DE4243030

申请日：1992-12-18

Applicant: BASF AG

Inventor： RITTER KURT DR ,  ADAM GEO DR ,  HELMCHEN GUENTER PROF DR ,  SPRINZ JUERGEN

IPC: B01J31/18 ,  B01J31/22 ,  C07C67/343 ,  C07F9/653 ,  C07F9/6539 ,  C07F9/6558 ,  C07F15/00 ,  C07D207/20 ,  C07D233/20 ,  C07D263/10 ,  C07D277/10 ,  C07D403/04 ,  C07D405/04 ,  C07D409/04 ,  C07D413/04 ,  C07D417/04 ,  C07F9/6506

Abstract: New cyclic imine derivs useful as ligands for complexing metals are of formula (I). A= O, S, CR4R5 or NR6; B= an opt inertly substd 1-3C bridging gp, opt forming part of a ring system, opt including X when X= NR4; m= 0-4; n= 0 or 1; R1 = 1-8C alkyl (opt interrupted by O or S atoms), 3-7C cycloalkyl, 1-6C aminoalkyl, 6-10C aryl (opt with inert substits), 7-10C aralkyl, p-methoxybenzyl and/or Y; Y= the residue of a natural aminoacid of formula YCH(NH2)COOH; R2 and R3= 1-8C alkyl, 3-7C cycloalkyl, 1-5C perfluoroalkyl, 1-6C alkoxy, 4-7C cycloalkoxy, 2-10C dialkylamino or 6-10C aryl, these gps opt being linked to form a ring and opt bearing inert substits; R4 and R5= H, 1-4C alkyl, 1-4C alkoxy, Ph or CH2Ph; R6= R4, COOR7 or SOOR7; R7= 1-4C alkyl, Ph, tolyl or CH2Ph; X= O or NR4; Z= N, P, As or Sb. Also claimed are transition metal complexes of formula (II). D= a non-coordinating anion; L= an organic ligand; M= a transition metal; p and q= 0-4.