Orange-violet fluorescent 2H-chromene dyes - dyeing polyamides, poly-esters, cellulose esters, polyacrylonitrile and plastics

    公开(公告)号:DE2328146A1

    公开(公告)日:1975-01-30

    申请号:DE2328146

    申请日:1973-06-02

    Applicant: BASF AG

    Abstract: Title cpds., which are of the benzpyrane type, are of formula (I): (where m is 1 or 2; n is 0 or 1, B is O, NH or (NX)mZ4, X being CO or SO2 and Z4 being, if m = 1, opt. subst. alkyl, cycloalkyl, aralkyl, aryl or vinyl, or alkoxy, phenoxy or amino, or if m = 2, methylene, ethylene, phenylene or a gp. of formula: Z is opt. substd. alkyl or aralkyl; Z' and Z2 are each H or opt. substd. alkyl, cycloalkyl or aryl; or Z1 and Z2 together with the N atom may form a heterocycle, or satd. ring linked in the o- pos. to the N atom and contg. 5-6 opt. substd. numbers; Z3 is, halogen, alkyl, alkoxy, CN, NO2, opt. substd. carbamoyl or sulphamoyl, or carbalkoxy; Z5 is H, carbalkoxy, NO2, CN, alkanelsulphonyl, opt. substd. carbamoyl or sulphanoyl, or phenyl, arenesulphonyl, benzionidazolyl, being thiazolyl or quinazolinyl; Z6 is H or Me; A encircled negative is an anion).

    Orange-violet fluorescent benzpyran dyes - for polyamides, cellulose esters, polyesters and acrylics

    公开(公告)号:DE2253538A1

    公开(公告)日:1974-05-09

    申请号:DE2253538

    申请日:1972-11-02

    Applicant: BASF AG

    Abstract: Title cpds. of formula (I): (where Z is opt. substd. alkyl or aralkyl; Z1 and Z2 are H, opt. substd. alkyl, cycloalkyl, aralkyl or aryl; or -NZ1Z2 forms part of a heterocycle, or a satd., opt. substd. 5-6 membered ring condensed in the o-posn. w.r.t. the N atom; Z3 is H, alkyl, alkoxy, halogen, CN, NO2, opt. substd. carbamoyl. or sulphamoyl or carbalkoxy; n is 0 or 1; Z4 is 0 or NH; Z5 is H, carbalkoxy, NO2, CN, alkyl-sulphonyl, opt. substd. carbamoyl, sulphamoyl, phenyl, arylsulphonyl, benzthiazolyl, benzoxazolyl or quinazolinonyl; A + is an anion). They are by reacting the corresp. imino-coumarine with cpds. of formula H2C (B) Z5 (where B CN or carbalkoxy) and opt. quaternising the cpd. (I) obtd. when n is 0.

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