公开(公告)号：CZ9702089A3

公开(公告)日：1998-04-15

申请号：CZ208997

申请日：1995-06-27

Applicant: BASF AG

Inventor： WARZELHAN VOLKER DR ,  SCHORNICK GUNNAR DR ,  BAUMANN EDWIN DR ,  SEELIGER URSULA DR ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD DR

IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30

CPC classification number: C08G69/44 ,  C08G18/606 ,  Y02W30/43

公开(公告)号：CZ292656B6

公开(公告)日：2003-11-12

申请号：CZ208997

申请日：1995-06-27

Applicant: BASF AG

Inventor： WARZELHAN VOLKER DR ,  SCHORNICK GUNNAR DR ,  BAUMANN EDWIN DR ,  SEELIGER URSULA DR ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD DR

IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30

Abstract: In the present invention there are disclosed biologically degradable polyester amides P1 that are prepared from a reaction mixture containing /a1/ a mixture comprising 35 to 95 mole percent of adipic acid or its ester-forming derivative or a mixture thereof, 5 to 65 mole percent of terephthalic acid or its ester-forming derivative or a mixture thereof, and 0 to 5 mole percent of a compound containing a sulfonate group, whereby the sum of the individual mole percentages is 100 mole percent, and /a2/ a mixture comprising /a21/ 99.5 to 0.5 mole percent of dihydroxy compounds being selected from the group comprising alkanediols having 2 to 6 carbon atoms and cycloalkane diols containing 5 to 10 carbon atoms, /a22/ 0.5 to 99.5 mole percent of aminoalkanol having 2 to 12 carbon atoms in the alkanol moiety or amino cycloalkanol containing 5 to 10 carbon atoms in the cycloalkanol moiety, and /a23/ 0 to 50 mole percent of diamino alkane containing 1 to 8 carbon atoms in the alkane moiety, /a24/ 0 to 50 mole percent of 2,2 -bisoxazoline of the general formula I, wherein Re1 represents a single bond, /CHi2/iq-alkylene group where q = 2, 3 or 4, or a phenylene group, whereby the sum of the individual mole percentages is 100 mole percent, and wherein the molar ratio of /a1/ to /a2/ is selected within the range of 0.4 : 1 to 1.5 : 1, with the proviso that the polyester amide P1 exhibits molecular weight /Min/ within the range of 4000 to 40 000 g/mole, viscosity number ranges within 30 to 350 g/ml (as measured in o-dichlorobenzene/phenol (weight ratio 50/50) at concentration of 0.5 percent by weight of the polyester amide P1 at a temperature of 25 degC) and melting temperature ranges within 50 to 220 degC, and with another proviso that 0 to 5 mole percent, based on molar amount of the component /a1/used, of the compound D having at least three groups capable of ester bond is used in the preparation of the P1 polyester amide. Described are also other biologically degradable polymers and molding thermoplastic materials, further process of their preparation, their use in the manufacture of biologically degradable shaped products, as well as adhesives, foams and starch-containing mixtures.

公开(公告)号：CZ208997A3

公开(公告)日：1998-04-15

申请号：CZ208997

申请日：1995-06-27

Applicant: BASF AG

Inventor： WARZELHAN VOLKER DR ,  SCHORNICK GUNNAR DR ,  BAUMANN EDWIN DR ,  SEELIGER URSULA DR ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD DR

IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30

Abstract: Biodegradable polyesteramides as defined in the specification are obtained by reacting a mixture consisting essentially ofa1) a mixture consisting essentially of35 to 95 mol % of adipic acid or ester-forming derivatives thereof,5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof, and0 to 5 mol % of a compound containing sulfonate groups,a2) a mixture consisting essentially of95.5 to 0.5 mol % of a dihydroxy compound,0.5 to 99.5 mol % of an amino-C2-C12-alkanol or an amino-C5-C10-cycloalkanol,0 to 50 mol % of a diamino-C1-C8-alkane, and0 to 50 mol % of a 2,2'-bisoxazoline of the formula I wherein R1 is as set forth in the specification, anda3) 0 to 5 mol %, based on a1), of a compound D as set forth in the specification;and other biodegradable polymers and thermoplastic molding compositions, their manufacture and their use for producing biodegradable moldings, adhesives, foams, and coatings.