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公开(公告)号:DE3863311D1
公开(公告)日:1991-07-25
申请号:DE3863311
申请日:1988-03-26
Applicant: BASF AG
Inventor: BAUR RICHARD DR , RICHTER FELIX DR , BIRNBACH STEFAN DR , FIKENTSCHER ROLF DR , OFTRING ALFRED DR , WINKLER EKHARD DR , BOCHNITSCHEK WERNER DR
IPC: G01N31/00 , C07C67/00 , C07C227/16 , C07C227/18 , C07C229/22 , C07C229/24 , C07C229/76 , C07C231/00 , C07C231/12 , C07C237/06 , C07C253/00 , C07C253/30 , C07C255/18 , C07C255/24 , C07C255/26 , C09K3/00 , C11D3/33 , C11D3/39
Abstract: 2-Hydroxy-3-aminopropionic-N,N-diacetic acid and derivatives thereof are used in particular as complexing agents, bleaching agent stabilizers and builders in detergents.
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公开(公告)号:DE3914980A1
公开(公告)日:1990-12-06
申请号:DE3914980
申请日:1989-05-06
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , BIRNBACH STEFAN DR , BAUR RICHARD DR , GOUSETIS CHARALAMPOS DR , TRIESELT WOLFGANG DR
IPC: C07C229/16 , C07C229/22 , C11D3/33 , C11D3/39 , D06L1/12
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公开(公告)号:DE59005313D1
公开(公告)日:1994-05-19
申请号:DE59005313
申请日:1990-04-30
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , BIRNBACH STEFAN DR , BAUR RICHARD DR , GOUSETIS CHARALAMPOS DR , TRIESELT WOLFGANG DR
IPC: C07C229/16 , C07C229/22 , C11D3/33 , C11D3/39 , D06L1/12
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公开(公告)号:DE3868118D1
公开(公告)日:1992-03-12
申请号:DE3868118
申请日:1988-04-02
Applicant: BASF AG
Inventor: BAUR RICHARD DR , RICHTER FELIX DR , BIRNBACH STEFAN DR , FIKENTSCHER ROLF DR , OFTRING ALFRED DR , WINKLER EKHARD DR
IPC: C11D3/26 , C07C67/00 , C07C229/22 , C07C229/32 , C07C231/00 , C07C231/12 , C07C237/06 , C07C253/00 , C07C255/18 , C07C255/24 , C09K3/00 , C11D3/33 , C11D3/39
Abstract: Various new processes are claimed for the prodn. of serine N,N-diacetic acid and N,N-diacetonitrile derivs. if formula (I): (where Y is COOH (opt. in the form of an alkali metal, ammonium or substd. ammonium salt) or CH; and X is COOH (opt. in the form of an alkali metal, ammonium or substd. ammonium salts), CN or a residue CONR3R4 in which R3 and R4 are H or 1-4C alkyl; X not being CN when Y is COOH). The use of serine-N,N-diacetic acid (I,X=COOH, Y=COOH) and its Na, K, ammonium and organic amine salts as complexing agents for heavy metals and/or alkaline earth ions and an building agents and bleach stabilisers in washing and cleaning agents is now. Detergents and cleaning agents contg. 0.01-20 wt.% of (I) (X other than CN) are new and claimed. Serine-N,N-diacetonitrile (i.e. (I,X COOH, Y=CN)) is new and claimed per se.
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公开(公告)号:DE3925727A1
公开(公告)日:1991-02-07
申请号:DE3925727
申请日:1989-08-03
Applicant: BASF AG
Inventor: BAUR RICHARD DR , GOUSETIS CHARALAMPOS DR , BIRNBACH STEFAN DR , KNEIP MICHAEL DR , OFTRING ALFRED DR
IPC: C07H5/04 , C07C229/22 , C11D3/33 , C11D3/37 , C11D3/39
Abstract: The use of 2-hydroxy-3-aminopropionic acid derivatives of the general formula I … … in which X is hydrogen, an alkali metal or ammonium which can be substituted by C1-C4-alkyl groups or C1-C4-hydroxyalkyl groups, and in which the groups Y and Y have the following meanings …… A) omega -substituted alkyl groups of the general formula… -(CH2)m-R … in which R is hydrogen, a hydroxyl group or the groups -COOX, -NH-CH(COOX)-CH2-COOX or -NY Y , and m has values from 1 to 20, with the exception of the value m = 1 in the case where Y and Y are identical and R is the group -COOX, … B) polyether groups of the general formula… -(CH2CH2O)m-R … in which R is hydrogen or a C1-C4-alkyl group, … C) beta -hydroxy-substituted groups of the general formula … … in which R is the groups -COOX, -CH2OH and -CH2-NY Y and n has values from 1 to 5, … D) alpha -carboxy-substituted groups of the general formula … … in which R is hydrogen, a methyl group or a hydroxymethyl group, and R is a hydroxymethyl group or the groups -CH(OH)-COOX or -(CH2)p-COOX where p is 1 or 2, … E) pyranosyl or furanosyl groups of the general formula … … in which q has the value 3 or 2, or … F) polymer residues of polyvinylamine or polyethyleneimine as complexing agents, bleach stabilisers and builders in detergents and cleaners. …
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公开(公告)号:DE3901613A1
公开(公告)日:1990-08-16
申请号:DE3901613
申请日:1989-01-20
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , BIRNBACH STEFAN DR , FIKENTSCHER ROLF DR , BAUR RICHARD DR , KUD ALEXANDER DR , GOECKEL ULRICH DR , PERNER JOHANNES DR
IPC: C11D1/72 , C07C229/24 , C07C309/13 , C09K3/00 , C09K23/28 , C09K23/42 , C11D3/33
Abstract: Glycerol aminocarboxylates of the formula (I) where n is from 0 to 10 and R is where L is iminodiacetate, aspartate, glutamate, sarcosinate, glycinate, serinate, hydroxyaspartate, ethanolaminoacetate, diethanolamino, alanate or taurinate and X is hydrogen, an alkali metal, ammonium or substituted ammonium, are prepared by esterifying glycerol or polyglycerols which contain up to 10 glycerol units with maleic anhydride or itaconic anhydride and addition of compound L-H where L is as defined above to the double bonds of the esters, and are used as complexing agents.
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公开(公告)号:DE59010804D1
公开(公告)日:1998-03-12
申请号:DE59010804
申请日:1990-07-24
Applicant: BASF AG
Inventor: BAUR RICHARD DR , GOUSETIS CHARALAMPOS DR , BIRNBACH STEFAN DR , KNEIP MICHAEL DR , OFTRING ALFRED DR
IPC: C07H5/04 , C07C229/22 , C11D3/33 , C11D3/37 , C11D3/39
Abstract: The use of 2-hydroxy-3-aminopropionic acid derivatives of the general formula I … … in which X is hydrogen, an alkali metal or ammonium which can be substituted by C1-C4-alkyl groups or C1-C4-hydroxyalkyl groups, and in which the groups Y and Y have the following meanings …… A) omega -substituted alkyl groups of the general formula… -(CH2)m-R … in which R is hydrogen, a hydroxyl group or the groups -COOX, -NH-CH(COOX)-CH2-COOX or -NY Y , and m has values from 1 to 20, with the exception of the value m = 1 in the case where Y and Y are identical and R is the group -COOX, … B) polyether groups of the general formula… -(CH2CH2O)m-R … in which R is hydrogen or a C1-C4-alkyl group, … C) beta -hydroxy-substituted groups of the general formula … … in which R is the groups -COOX, -CH2OH and -CH2-NY Y and n has values from 1 to 5, … D) alpha -carboxy-substituted groups of the general formula … … in which R is hydrogen, a methyl group or a hydroxymethyl group, and R is a hydroxymethyl group or the groups -CH(OH)-COOX or -(CH2)p-COOX where p is 1 or 2, … E) pyranosyl or furanosyl groups of the general formula … … in which q has the value 3 or 2, or … F) polymer residues of polyvinylamine or polyethyleneimine as complexing agents, bleach stabilisers and builders in detergents and cleaners. …
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公开(公告)号:DE3885670D1
公开(公告)日:1993-12-23
申请号:DE3885670
申请日:1988-08-04
Applicant: BASF AG
Inventor: BIRNBACH STEFAN DR , MUELLER JOSEF DR , WULZ KLAUS DR , HOUBEN JOCHEN DR
Abstract: Etherified polyoxyalkylene derivatives of the formula where R1 is hydrogen, C1-C20-alkyl or C3-C5-alkenyl, R2 and R3 independently of one another are each hydrogen, methyl or ethyl, R4 is C1-C4-alkyl and m and n are identical or different and are each greater than or equal to 0, with the proviso that the sum of m and n is from 3 to 300, are prepared by reacting the corresponding hydroxyl-containing polyoxyalkylene derivative with a dialkyl sulfate in the presence of an alkali metal hydroxide by a process in which the reaction is carried out at from 20 DEG to 60 DEG C. in the presence of an aqueous solution of an alkali metal hydroxide, the concentration of alkali metal hydroxide during the entire duration of the reaction being not less than 35% by weight, based on the aqueous phase, and not less than 1 mole of dialkyl sulfate and not less than one mole of alkali metal hydroxide are used per mole equivalent of organic hydroxyl groups.
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公开(公告)号:DK0379109T3
公开(公告)日:1993-11-15
申请号:DK90100696
申请日:1990-01-13
Applicant: BASF AG
Inventor: FIKENTSCHER ROLF DR , PERNER JOHANNES DR , BAUR RICHARD DR , KUD ALEXANDER DR , BIRNBACH STEFAN DR , OFTRING ALFRED DR , GOECKEL ULRICH DR
IPC: C07C229/24 , C07C309/13 , C11D1/72 , C09K3/00 , C09K23/28 , C09K23/42 , C11D3/33
Abstract: Glycerol aminocarboxylates of the formula (I) where n is from 0 to 10 and R is where L is iminodiacetate, aspartate, glutamate, sarcosinate, glycinate, serinate, hydroxyaspartate, ethanolaminoacetate, diethanolamino, alanate or taurinate and X is hydrogen, an alkali metal, ammonium or substituted ammonium, are prepared by esterifying glycerol or polyglycerols which contain up to 10 glycerol units with maleic anhydride or itaconic anhydride and addition of compound L-H where L is as defined above to the double bonds of the esters, and are used as complexing agents.
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公开(公告)号:DE59001816D1
公开(公告)日:1993-07-29
申请号:DE59001816
申请日:1990-01-13
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , BIRNBACH STEFAN DR , FIKENTSCHER ROLF DR , BAUR RICHARD DR , KUD ALEXANDER DR , GOECKEL ULRICH DR , PERNER JOHANNES DR
IPC: C11D1/72 , C07C229/24 , C07C309/13 , C09K3/00 , C09K23/28 , C09K23/42 , C11D3/33
Abstract: Glycerol aminocarboxylates of the formula (I) where n is from 0 to 10 and R is where L is iminodiacetate, aspartate, glutamate, sarcosinate, glycinate, serinate, hydroxyaspartate, ethanolaminoacetate, diethanolamino, alanate or taurinate and X is hydrogen, an alkali metal, ammonium or substituted ammonium, are prepared by esterifying glycerol or polyglycerols which contain up to 10 glycerol units with maleic anhydride or itaconic anhydride and addition of compound L-H where L is as defined above to the double bonds of the esters, and are used as complexing agents.
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