MODIFIED POLYAMINOAMIDES
    1.
    发明申请
    MODIFIED POLYAMINOAMIDES 审中-公开
    改性聚氨酯

    公开(公告)号:WO2005090442A9

    公开(公告)日:2005-12-01

    申请号:PCT/EP2005002918

    申请日:2005-03-18

    Abstract: The present invention relates to novel modified polyaminoamides which are useful as dispersing agents for particulate inorganic solids, especially for inorganic pigments such as clay minerals. The new polyamides are also useful as graying inhibiting additives and detergency boosting additives in washing composition for laundry. In the modified polyaminoamide according to the invention at least a part of the amino nitrogens of the polymer carry both a hydrocarbon radical R which is selected from C1-C6-alkyl, C6-C16-aryl-C1-C4-alkyl and a group AIk-O-A, wherein A is hydrogen or an acidic group selected from B -PO(OH)2, B - S(O)2OH and B -COOH which may be present in the acidic or anionic form, wherein B is a single bond or C1-C6-alkanediyl, and B is C1-C6-alkanediyl and Alk is C2-C6-alkane-1,2-diyl, and a moiety of the formula (I) -(CH2-CR R -O-)PA ,wherein A is as defined above R is independently selected from hydrogen, C1-C12-alkyl, C2-C8-alkenyl, C6-C16-aryl or C6-Ct6-aryl-C1-C4-alkyl, R is independently selected from hydrogen or methyl and p is an integer provided that p has a number average of at least 10.

    Abstract translation: 本发明涉及可用作颗粒状无机固体分散剂的新型改性聚氨基酰胺,特别是无机颜料如粘土矿物。 新的聚酰胺也可用作用于洗衣的洗涤组合物中的抑灰添加剂和助洗助洗添加剂。 在根据本发明的改性聚氨基酰胺中,聚合物的至少一部分氨基氮携带选自C 1 -C 6 - 烷基,C 6 -C 16 - 芳基-C 1 -C 4烷基和基团AI k的烃基R -OA,其中A是氢或选自B 1 -PO(OH)2,B 1 -S(O)2 OH和B 2 -COOH的酸性基团,其可以存在于酸性或阴离子 形式,其中B 1是单键或C 1 -C 6烷二基,B 2是C 1 -C 6烷二基,Alk是C 2 -C 6烷烃-1,2-二基,式 (I) - (CH 2 -CR 1 R 2 -O-)PA,其中A如上定义R 1独立地选自氢,C 1 -C 12 - 烷基,C 2 -C 8 - 烯基,C 6 -C16-芳基或C6-Ct6-芳基-C1-C4-烷基,R 2独立地选自氢或甲基,p是整数,条件是p的数均等于至少10。

    TREATMENT METHOD, WHICH PROMOTES THE REMOVAL OF DIRT, FOR THE SURFACES OF TEXTILES AND NON-TEXTILES
    3.
    发明申请
    TREATMENT METHOD, WHICH PROMOTES THE REMOVAL OF DIRT, FOR THE SURFACES OF TEXTILES AND NON-TEXTILES 审中-公开
    方法污物分离促进纺织品表面与非纺织材料处理

    公开(公告)号:WO02103105A3

    公开(公告)日:2003-05-01

    申请号:PCT/EP0206628

    申请日:2002-06-14

    Abstract: The invention relates to a treatment method, which promotes the removal of dirt, for the surfaces of textiles and non-textiles. According to said method, cationically modified, hydrophilic nanoparticles, based on cross-linked polymers, are applied from an aqueous dispersion to the surface of the materials. Said cross-linked polymers consist of (a) between 60 and 99.99 wt. % of one or more ethylenically unsaturated monomers containing carboxyl groups, or the salts thereof, (b) between 0 and 40 wt. % of one or more water-insoluble, monoethylenically unsaturated monomers, (c) between 0.01 and 30 wt. % of one or more ethylenically polyunsaturated monomers, (d) between 0 and 25 wt. % of one or more monomers containing sulphonic acid and/or phosphonic acid, or the salts thereof, (e) between 0 and 30 wt. % of one or more water-soluble, non-ionic monomers. The dispersion of the hydrophilic nanoparticles can be stabilised with anionic, non-anionic and/or betainic emulsifiers and/or protective colloids. The hydrophilic nanoparticles have a particle size of between 10 and 2 mu m and are modified cationically by covering their surface with one or more cationic polymers, one or more polyvalent metallic ions and/or one or more cationic surfactants.

    Abstract translation: 一种用于纺织和非纺织材料表面的土壤分离促进治疗,其中所述阳离子改性的基于(a)的60〜99.99重量%的一种或多种含羧基的烯属不饱和单体或其盐的%交联聚合物的亲水性纳米颗粒物,方法( b)0至40重量%的一种或多种水不溶性的单烯属不饱和单体的%,(C)0.01至30重量的一种或多种多烯属不饱和单体的%,(D)0至25重量的一个或多个% 含有单体或其盐磺酸膦酸,(E)0至30由水分散体施加重量%的一种或多种水溶性非离子单体的到材料的表面上,和/或其中与阴离子,非离子型的亲水性纳米颗粒的分散 和/或甜菜碱的乳化剂和/或保护性胶体可以稳定,并且其中所述HY drophilen纳米颗粒具有10纳米至2微米的颗粒尺寸和通过与一种或多种阳离子聚合物,一种或多种多价金属离子和/或一种或多种阳离子表面活性剂涂覆在其表面被阳离子改性。

    AMPHIPHILIC WATER-SOLUBLE ALKOXYLATED POLYALKYLENIMINES WITH AN INTERNAL POLYETHYLENE OXIDE BLOCK AND AN EXTERNAL POLYPROPYLENE OXIDE BLOCK
    6.
    发明申请
    AMPHIPHILIC WATER-SOLUBLE ALKOXYLATED POLYALKYLENIMINES WITH AN INTERNAL POLYETHYLENE OXIDE BLOCK AND AN EXTERNAL POLYPROPYLENE OXIDE BLOCK 审中-公开
    两亲烷氧基化水溶性与心脏和聚环氧乙烷聚丙烯外聚亚烷基亚胺

    公开(公告)号:WO2006108856A3

    公开(公告)日:2007-01-18

    申请号:PCT/EP2006061552

    申请日:2006-04-12

    CPC classification number: C11D3/3723 C08G73/0206

    Abstract: The invention relates to amphiphilic water-soluble alkoxylated polyalkylenimines of general formula (I), where the variables have the following meanings: R independently = linear or branched C 2 -C 6 alkylenes, B = a branching, E = an alkylenoxy of formula (II), R 1 = 1,2-propylene, 1, 2-butylene and/or 1, 2-isobutylene, R 2 = ethylene, R 3 = 1,2-propylene, R 4 independently = H, C 1 -C 4 alkyl, x, y, z each = 2 to 150, where the sum x+y+z indicates a number of alkylenimine units, the mean molecular weight Mw of the polyalkylenimine before alkoxylation is 300 to 10,000, m = a whole number from 0 to 2, n = a whole number from 6 to 18, p = a whole number from 3 to 12, where 0.8 =n/p =1.0 (x+y+z) 1/2 and the quaternisation products thereof.

    Abstract translation: 通式(I)的两亲性的水溶性烷氧基化聚亚烷基亚胺,其中各变量具有以下含义:R相同或不同,直链或支链的C 2 -C 6 亚烷基; B是一个分支; E是具有下式的亚烷基氧基单元(II)R 1 1,2-丙烯,1-,2-丁烯和/或1-,2-异丁烯; [R 2 乙烯; [R 3 1,2-丙烯; [R 4 是相同的或不同的基团:氢; ç 1 -C 4 烷基; 的x,y,z各为数为2〜150,总和X + Y + Z表示数烯化亚胺单元的对应于烷氧基化之前300-10000的平均分子量Mw为聚亚烷基亚胺的; m是从0至2的有理数; n为6〜18的有理数; p为有理数的3至12,其中0.8 = N / P = 1,0(X + Y + Z) 1/2 ,以及它们的季铵化产物。

    WATER-SOLUBLE COPOLYMERS OF MONOETHYLENICALLY UNSATURATED POLYALKYLENE OXIDE MONOMERS AND DIPOLAR MONOMERS CONTAINING AT LEAST ONE NITROGEN ATOM

    公开(公告)号:CA2544053C

    公开(公告)日:2011-08-16

    申请号:CA2544053

    申请日:2004-11-16

    Applicant: BASF AG

    Abstract: Water-soluble copolymers which comprise, in copolymerized form, (a) 60 to 99% by weight of at least one monoethylenically unsaturated polyalkylene oxide monomer of the formula I (see formula I) in which the variables have the following meanings: X is -CH2- or -C(O)-, if Y is -O-; is -C(O)-, if Y is -NH-; is -O- or -O-(CH2)4-, if Y is a chemical bond; Y is -O-, -NH- or a chemical bond; R1 is hydrogen or methyl; R2 is C2-C4-alkylene radicals, which may be identical or different and also linear or branched, but where at least 50% of the radicals R2 are ethylene; R3 is C1-C22-alkyl, phenyl, p-(C1-C12-alkyl)phenyl or hydrogen; n is an integer from 6 to 50, (b) 1 to 40% by weight of at least one nonquaternized dipolar monomer comprising at least one nitrogen atom, (c) 0 to 39% by weight of other nonionic monoethylenically unsaturated monomers and (d) 0 to 10% by weight of other anionic monoethylenically unsaturated monomers and have an average molecular weight M w of from 2000 to 500 000 D, and the use of the copolymers as dispersants and sequestrants for pigmented materials, as additive for detergents, laundry pretreatment compositions, cleaners for hard surfaces, dentifrices and bodycare compositions, and as auxiliaries for textile processes, paper making and paper processing and deinking processes.

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