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公开(公告)号:NO920601L
公开(公告)日:1992-08-17
申请号:NO920601
申请日:1992-02-14
Applicant: BASF AG
Inventor: KONRAD GERD , HARTMANN HEINRICH , ELFERS GUENTHER , RAUBENHEIMER HANS-JUERGEN , VOGEL HANS-HENNING
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公开(公告)号:NO920601A
公开(公告)日:1992-08-17
申请号:NO920601
申请日:1992-02-14
Applicant: BASF AG
Inventor: KONRAD GERD , HARTMANN HEINRICH , ELFERS GUENTHER , RAUBENHEIMER HANS-JUERGEN , VOGEL HANS-HENNING
CPC classification number: C08F8/30 , B01D17/047 , C08F8/14
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公开(公告)号:FI915127A
公开(公告)日:1992-05-15
申请号:FI915127
申请日:1991-10-30
Applicant: BASF AG
Inventor: KONRAD GERD , WENDEROTH BERND , BARTHOLD KLAUS , SCHWARTZ ERICH , RAUBENHEIMER HANS-JUERGEN , HARTMANN HEINRICH
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公开(公告)号:DE59407061D1
公开(公告)日:1998-11-12
申请号:DE59407061
申请日:1994-07-28
Applicant: BASF AG
Inventor: FAUL DIETER , ROSER JOACHIM , HARTMANN HEINRICH , VOGEL HANS-HENNING , SLOTMAN WILHELMUS , KONRAD GERD
IPC: B01D17/04 , C08F8/14 , C08F220/26 , C08F290/06 , C08G63/676 , C08G65/32 , C08G65/332 , C09K8/36 , C10G33/04
Abstract: PCT No. PCT/EP94/02487 Sec. 371 Date Feb. 7, 1996 Sec. 102(e) Date Feb. 7, 1996 PCT Filed Jul. 28, 1994 PCT Pub. No. WO95/04771 PCT Pub. Date Feb. 16, 1995Reaction products which are suitable as demulsifiers for crude oil emulsions, comprise olefinically unsaturated carboxylic acids and polyetherols and are obtainable by A) condensation of one or more unsaturated C3-C10-carboxylic acids or their derivatives of the general formula I I where R1 and R2 are each hydrogen, C1-C4-alkyl or carboxyl, R3 is hydrogen or methyl and R1 together with the carboxyl group may form a 5-membered or 6-membered anhydride ring, with a polyetherol of the general formula II II where R4 is a radical of a monohydric or polyhydric alcohol or of a phenol or of an alkylphenol of 7 to 30 carbon atoms or a radical of an alkylphenol/formaldehyde or alkylphenol/acetaldehyde condensate, R5 is a branched or straight-chain C2-C4-alkylene group, where different units [R5-O] may be present within a polyalkylene oxide chain, and X is an integer of from 5 to 120, in a molar ratio of compounds II to I of from 2:1 to 10:1 and in a weight ratio of from 25:1 to 1,000:1, B) polymerization of the resulting condensate with one or more unsaturated carboxylic acids I and, if required, further olefinically unsaturated monomers copolymerizable with the carboxylic acids I, the amount of the carboxylic acids I being from 50 to 100 mol %, based on the amount of the olefinically unsaturated monomers, and the molar ratio of the polyetherol II to the sum of the olefinically unsaturated monomers used in process steps A) and B) being from 1:5 to 1:200, and subsequent C) condensation of the resulting reaction mixture, with the proviso that not all hydroxyl groups are converted, and a process for their preparation, mixtures of the reaction products with organic solvents and the use of the reaction products and of the mixtures as demulsifiers for crude oil emulsions.
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公开(公告)号:NO304077B1
公开(公告)日:1998-10-19
申请号:NO914443
申请日:1991-11-13
Applicant: BASF AG
Inventor: KONRAD GERD , WENDEROTH BERND , BARTHOLD KLAUS , SCHWARTZ ERICH , RAUBENHEIMER HANS-JUERGEN , HARTMANN HEINRICH
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公开(公告)号:NO300780B1
公开(公告)日:1997-07-21
申请号:NO920601
申请日:1992-02-14
Applicant: BASF AG
Inventor: KONRAD GERD , HARTMANN HEINRICH , ELFERS GUENTHER , RAUBENHEIMER HANS-JUERGEN , VOGEL HANS-HENNING
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公开(公告)号:NO960524A
公开(公告)日:1996-02-09
申请号:NO960524
申请日:1996-02-09
Applicant: BASF AG
Inventor: FAUL DIETER , ROSER JOACHIM , HARTMANN HEINRICH , VOGEL HANS-HENNING , SLOTMAN WILHELMUS , KONRAD GERD
IPC: B01D17/04 , C08F220/26 , C08G63/676 , C08G65/332 , C09K8/36 , C10G33/04 , C08F290/06 , C08G65/32
CPC classification number: B01D17/047 , C08F220/26 , C08G63/676 , C08G65/3322 , C08G2650/20 , C08L2312/00 , C09K8/36 , C10G33/04
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公开(公告)号:NO914443D0
公开(公告)日:1991-11-13
申请号:NO914443
申请日:1991-11-13
Applicant: BASF AG
Inventor: KONRAD GERD , WENDEROTH BERND , BARTHOLD KLAUS , SCHWARTZ ERICH , RAUBENHEIMER HANS-JUERGEN , HARTMANN HEINRICH
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公开(公告)号:NO900866D0
公开(公告)日:1990-02-23
申请号:NO900866
申请日:1990-02-23
Applicant: BASF AG
Inventor: KONRAD GERD , HARTMANN HEINRICH , ZARATE JACOBO
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公开(公告)号:NO960524D0
公开(公告)日:1996-02-09
申请号:NO960524
申请日:1996-02-09
Applicant: BASF AG
Inventor: FAUL DIETER , ROSER JOACHIM , HARTMANN HEINRICH , VOGEL HANS-HENNING , SLOTMAN WILHELMUS , KONRAD GERD
IPC: B01D17/04 , C08F8/14 , C08F220/26 , C08F290/06 , C08G63/676 , C08G65/32 , C08G65/332 , C09K8/36 , C10G33/04 , C08F , C10G
Abstract: PCT No. PCT/EP94/02487 Sec. 371 Date Feb. 7, 1996 Sec. 102(e) Date Feb. 7, 1996 PCT Filed Jul. 28, 1994 PCT Pub. No. WO95/04771 PCT Pub. Date Feb. 16, 1995Reaction products which are suitable as demulsifiers for crude oil emulsions, comprise olefinically unsaturated carboxylic acids and polyetherols and are obtainable by A) condensation of one or more unsaturated C3-C10-carboxylic acids or their derivatives of the general formula I I where R1 and R2 are each hydrogen, C1-C4-alkyl or carboxyl, R3 is hydrogen or methyl and R1 together with the carboxyl group may form a 5-membered or 6-membered anhydride ring, with a polyetherol of the general formula II II where R4 is a radical of a monohydric or polyhydric alcohol or of a phenol or of an alkylphenol of 7 to 30 carbon atoms or a radical of an alkylphenol/formaldehyde or alkylphenol/acetaldehyde condensate, R5 is a branched or straight-chain C2-C4-alkylene group, where different units [R5-O] may be present within a polyalkylene oxide chain, and X is an integer of from 5 to 120, in a molar ratio of compounds II to I of from 2:1 to 10:1 and in a weight ratio of from 25:1 to 1,000:1, B) polymerization of the resulting condensate with one or more unsaturated carboxylic acids I and, if required, further olefinically unsaturated monomers copolymerizable with the carboxylic acids I, the amount of the carboxylic acids I being from 50 to 100 mol %, based on the amount of the olefinically unsaturated monomers, and the molar ratio of the polyetherol II to the sum of the olefinically unsaturated monomers used in process steps A) and B) being from 1:5 to 1:200, and subsequent C) condensation of the resulting reaction mixture, with the proviso that not all hydroxyl groups are converted, and a process for their preparation, mixtures of the reaction products with organic solvents and the use of the reaction products and of the mixtures as demulsifiers for crude oil emulsions.
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