4.
    发明专利
    未知

    公开(公告)号:DE59801094D1

    公开(公告)日:2001-08-30

    申请号:DE59801094

    申请日:1998-08-21

    Applicant: BASF AG

    Abstract: A continuous process for preparing pigmented thermoplastic molding compositions in an extruder, comprisesI) in a first zoneA) metering in from 10 to 99.999% by weight of a thermoplastic polymer into an extruder andII) in a subsequent zone at temperatures below the respective glass transition temperature of the thermoplastic A)B) adding from 0.001 to 60% by weight of a colorant andthen heating the thermoplastic/colorant mixture in the subsequent zones, homogenizing the polymer melt and extruding the resultant mixture.

    PREPARATION OF POLYPHENYLENE ETHERS, AND AN APPARATUS FOR THIS PURPOSE

    公开(公告)号:CA1263992A

    公开(公告)日:1989-12-19

    申请号:CA495489

    申请日:1985-11-15

    Applicant: BASF AG

    Abstract: Disclosed is a process of preparation of polyphenylene ethers from monohydric phenols, which possess alkyl substituents in the two ortho-positions and, if desired, in the meta-position, but not in the para-position, by an oxidative coupling reaction with oxygen at from 15 to 50.degree.C and under from 1 to 10 bar in the presence of a catalyst complex, of a solvent and, if required, of an activator. In this process,the conversion of the phenols is carried out in two or more reaction zones. Some or all of the solvent, catalyst complex phenols and where relevant, activator are initially added to one of the reaction zones and are circulated in the other reaction zone and about 60-100% of the stoichiometric amount of oxygen required for the oxidative coupling is introduced into the first reaction zone and from 0 to about 40% of the said stoichiometric amount is introduced into the second reaction zone. This process is interesting in that it makes it possible to carry out oxidative coupling of phenols with oxygen in a very economic and reliable manner, with very high space-time yields, formation of only a small amount of by-products, and minimum emissions of gas and volatile components.

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