1.
    发明专利
    未知

    公开(公告)号:DE2524204A1

    公开(公告)日:1976-12-16

    申请号:DE2524204

    申请日:1975-05-31

    Applicant: BASF AG

    Abstract: A process for the manufacture of ethylene polymers by high pressure polymerization of ethylene, if desired mixed with other compounds copolymerizable with ethylene, and isolation of the reaction product in a multi-stage isolation zone. The molecular weight of the ethylene polymer can be varied by varying the mean product residence time in the isolation zone. The isolation zone preferably consists of two stages, with a higher pressure prevailing in the first stage than in the second stage.

    8.
    发明专利
    未知

    公开(公告)号:DE2802866A1

    公开(公告)日:1979-07-26

    申请号:DE2802866

    申请日:1978-01-24

    Applicant: BASF AG

    Abstract: A continuous process for the manufacture of ethylene copolymers under high pressure and at high temperature in a polymerization zone, with transfer of the reaction mixture into a high pressure product isolation zone and from there into a low pressure product isolation zone, and recycling of the unconverted gas from the high pressure product isolation zone into the polymerization zone and from the low pressure product isolation zone into a low temperature separator, from where the comonomer separated off is recycled to the polymerization process, while the ethylene is discharged as off-gas. The gas taken off the low pressure product isolation zone is preferably compressed to from 10 to 20 bar and cooled to from -10 DEG to -30 DEG C. before it is fed into the low temperature separator. There is a substantial improvement in the efficiency of separating off the comonomer.

    9.
    发明专利
    未知

    公开(公告)号:DE2557653A1

    公开(公告)日:1977-06-30

    申请号:DE2557653

    申请日:1975-12-20

    Applicant: BASF AG

    Abstract: Ethylene polymers are manufactured in a tubular reactor under high pressure and at high temperatures in the presence of polymerization initiators. The polymerization is carried out in two different zones of the reactor, a mixture of ethylene, oxygen and regulator being fed into the first zone and a co-initiator having a half-life temperature, measured in benzene, of above 140 DEG C being additionally fed into the second zone. The co-initiator may be a peroxide or a hydroperoxide. The melt index, or the haze and gloss of a film produced from the resulting ethylene polymer, can be varied advantageously through the choice of the co-initiator.

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