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公开(公告)号:DE2722034A1
公开(公告)日:1978-11-23
申请号:DE2722034
申请日:1977-05-16
Applicant: BASF AG
IPC: C08F6/00 , C08F2/34 , C08F6/04 , C08F6/06 , C08F10/00 , C08F10/02 , C08F110/02 , C08F212/02 , C08F2/36
Abstract: A process for the continuous high pressure polymerization Or ethylene in a polymerization system which comprises a polymerization zone (A) a high pressure product isolation zone (B), a throttling and control system (C), a low pressure product isolation zone (D), a second throttling and control system (E) and a discharge extruder (F), and wherein, according to the invention, the level Or the ethylene polymer in the high pressure product isolation zone (B) and in the low pressure product isolation zone (D) is carried periodically. The process gives an ethylene polymer Or improved homogeneity, which when used to manufacture films does not tend to form specks or fisheyes.
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2.
公开(公告)号:DE2442230A1
公开(公告)日:1976-03-18
申请号:DE2442230
申请日:1974-09-04
Applicant: BASF AG
Inventor: BUECHNER OSKAR DIPL CHEM DR , GIERTH VOLKER DIPL CHEM DR , POHL WALTER ING GRAD , MUELLER SIEGFRIED ING GRAD
Abstract: Polyethylene film is prepd. by homogenising polyethylene of density 0.916-0.932 g/cm3 and melt index 0.05-1g/10, mins. with 50-400 ppm peroxide in an extruder having sepn. of 0.1-0.5 mm between the screw(s) (themselves) and the stationary part. the ratio of minimal sepn. between moving part(s) and stationary or other moving parts:length of area of narrow slit regions in the flow direction lies in the range of 10-2-10-5. The films have high strength and low blocking props. and may be used in the sack making industry.
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公开(公告)号:DE2608023A1
公开(公告)日:1977-09-08
申请号:DE2608023
申请日:1976-02-27
Applicant: BASF AG
Inventor: BUECHNER OSKAR DIPL CHEM DR , GIERTH VOLKER DIPL CHEM DR , MUELLER SIEGFRIED ING GRAD , WENDLER KLAUS ING GRAD , POHL WALTER ING GRAD
Abstract: Film for making heavy duty sacks 150-300 mu thick is made from (a) polyethylene with a density of 0.915-0.935 g/cm3 and a melt index of 0.05-50g/10 min. and (b) 0.05-0.5 wt.% (on a) of calcium sulphate powder with an av. particle size of >10 (10-90)mu. Pref. the calcium sulphate contains at most 1/2 mol. water of crystallisation per mol calcium sulphate. The films have good anti-blocking properties and pleasant texture, and can be used in packing equipment without breakdown in prodn. Compared with SiO2-filled films, they have reduced tendency to yellowing and optical defects.
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