Azabenzanthrone dispersion dyes - for synthetic fibres and mass colour-ing of thermoplastics

    公开(公告)号:DE2255524A1

    公开(公告)日:1974-05-16

    申请号:DE2255524

    申请日:1972-11-13

    Applicant: BASF AG

    Abstract: The dyes are of formula (I) (in which R1 and R2 are H, Cl, Br, NO2, CN, OH, amino-alkylamino with (1-4)C, phenyl, (1-4)C alkyl, (1-4)C alkoxy, (2-4)C hydroxyalkoxy or carbalkoxy, and X is H, Cl, Br, NO2 or R3 and R4 are the same as R1 and R2. Pref. R2 is H, R1 is H, Cl, Br, ethyl, methoxy or ethoxy X is H, Cl, Br or R3 is a R1 and R4 as R2. The dyes are made by reacting mono- or di-halogen azabenzthones with opt. substd. thiophenols in org. solvent in presence of an acid acceptor and opt. a catalyst. They are suitable for dyeing linear polyester fibres in strong brilliant greenish-yellow shades with good fastness and for colouring thermoplastics in strong fluorescent yellow shades.

    2,7-dichlorofluorenone - prepn by oxidn of chlorinated fluorene

    公开(公告)号:DE2111724A1

    公开(公告)日:1972-09-28

    申请号:DE2111724

    申请日:1971-03-11

    Applicant: BASF AG

    Abstract: Process for prepg. pure 2,7-dichlorofluorenone by direct chlorination of fluorene in a solvent at 100 degrees - solvent b. pt. under exclusion of sunlight then removing excess Cl2 and oxidising the product with 0.8-2.5 pref. 0.9-2.0 mol alkali dichromate/mol. fluorene at 80 degrees - solvent b. pt. Specif. solvents are glacial acetic acid or propionic acid. The cpd. is an inter. for the prepn. of dyes and drugs.

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