2.
    发明专利
    未知

    公开(公告)号:DE3109950A1

    公开(公告)日:1982-09-23

    申请号:DE3109950

    申请日:1981-03-14

    Applicant: BASF AG

    Abstract: Water-emulsifiable hard waxes consisting of homogeneous terpolymers of ethylene with-based on weight of terpolymer-from 1 to 8% by weight of C3-C8-olefinically unsaturated carboxylic acids and from 0.5 to 10% by weight of C1-C12-alkyl esters of such unsaturated carboxylic acids and having a Staudinger index, determined according to DIN 53,728, of from 5 to 55, an acid number of from 8 to 62 and a Höppler hardness, measured by DFG standard method M-III-9a(57), at 23 DEG C., of from 250 to 800 bar, are obtained by copolymerizing ethylene with olefinically unsaturated C3-C8-carboxylic acids and esters of such acids with C1-C12-alkanols in a continuous process in the presence of a free radical initiator at from 150 DEG to 300 DEG C. under a pressure of from 1,000 to 3,000 bar, using a weight ratio of ethylene:acid:acrylate of from 500:1:1 to 20:1:1, in a one-phase polymerization medium in which the monomers are soluble, in the presence of from 0.01 to 8% by weight, based on the sum of the monomers, of a regulator, from 3 to 25% by weight of the ethylene being converted and the copolymer formed being removed continuously from the reaction zone.

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