Polyacrylonitrile solutions produced cont- - sinuously

    公开(公告)号:DE1915577A1

    公开(公告)日:1970-09-17

    申请号:DE1915577

    申请日:1969-03-27

    Applicant: BASF AG

    Abstract: Reaction temp. is kept constant by control of condensation conditions on the condenser, as is the concentration ratio of monomer(s) and DMF in the reaction mixture by control of additions of DMF as a function of the saturation vapour pressure above the reaction mixture, and also the polymer content of the reaction mixture by control of dwell time. Pref. a 35-to 45% monomer soln. is introduced in the reaction zone and polymn. is effected as 55 to 65 degrees C.

    Continuous production of polyesters

    公开(公告)号:DE1926767A1

    公开(公告)日:1970-11-26

    申请号:DE1926767

    申请日:1969-05-24

    Applicant: BASF AG

    Abstract: Polyesters containing is not 80 weight % of ethylene terephthalate and having a limit viscosity of up to 0.40, are produced by polycondensation of diglycol terephthalate or its oligomers, possible together with other polyester-forming components, at 240-320 degrees C, in thin layers and under reduced pressure, by flowing the ester or oligomer down the inside of a stationary heated tube which is constricted at intervals; the vapours which form during the polycondensation are withdrawn in the same direction as the stream of product. The apparatus is simple and involves no moving parts. Loss of terephthalic acid is reduced. The apparatus is self-cleaning. Thermal decomposition of the product as a result of long residence times is avoided.

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