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公开(公告)号:DE1295554B
公开(公告)日:1969-05-22
申请号:DEB0076769
申请日:1964-05-14
Applicant: BASF AG
IPC: C07D209/08
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公开(公告)号:DE59809861D1
公开(公告)日:2003-11-20
申请号:DE59809861
申请日:1998-12-22
Applicant: BASF AG
Inventor: BEER DR , BEISER KLAUS , CIPRIAN DR , FRANZ DR , FRANZISCHKA DR , PALM DR , PAPE DR , PAUL DR , PESSEL ULRICH-DIETER , WECK ALEXANDER
IPC: B01J39/04 , B01J39/05 , B01J47/02 , B01J47/026 , B01J49/00 , B01J49/06 , C08F6/08 , C08G65/20 , C08G65/30 , C08G65/331 , C08J5/20
Abstract: The production of a hydroxyl group containing polymer, preferably polytetrahydrofuran, by ester exchange of the corresponding acyloxy group containing polymer with alcohol in the presence of a sodium containing catalyst involves separation of the sodium cation using a catalytic amount of water by passage through an ion exchange material.
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公开(公告)号:DE59806798D1
公开(公告)日:2003-02-13
申请号:DE59806798
申请日:1998-09-25
Applicant: BASF AG
Inventor: AUER HEINZ , BEISER KLAUS , CIPRIAN DR , FRANZ DR , FRANZISCHKA DR , PESSEL ULRICH-DIETER , WEINLE WERNER
Abstract: The foam produced during the continuous production of hydroxyl (OH) group terminated polytetrahydrofuran is removed and by transesterification of the corresponding ester group containing polymer. A process for preparing OH group containing polymers, especially for preparing polytetrahydrofuran with terminal OH groups, by transesterification of the corresponding ester group-containing polymers with alcohols. Tranesterification is carried out continuously in at least one stirred reactor (I,II,III,IV), where at least one reactor (I,II,III,IV) being connected via a line (3,3') to a generally cylindrical container (5,13'), with a diameter of about 2-4 times the diameter of the line (3,3'), to take up the foam formed in the stirred reactor(s) (I,II,III,IV) and to pass the foam tangentially into the cylindrical container (5,13) at a speed sufficient to separate the foam into a gaseous phase and a liquid phase. The gas phase is led off via a line (9) and the liquid phase is led off via a line (7,15).
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