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公开(公告)号:WO03097630A8
公开(公告)日:2004-12-16
申请号:PCT/EP0304968
申请日:2003-05-13
Applicant: BASF AG , FRIESE KATRIN , RAULS MATTHIAS , FREYHOF REINHARD , FRIESE THORSTEN , ARMBRUSTER HARALD , ZEINER HARTMUT , EGBERS GITTA , STROEFER ECKHARD , HECK LUDWIG , HILDENBRAND PETER
Inventor: FRIESE KATRIN , RAULS MATTHIAS , FREYHOF REINHARD , FRIESE THORSTEN , ARMBRUSTER HARALD , ZEINER HARTMUT , EGBERS GITTA , STROEFER ECKHARD , HECK LUDWIG , HILDENBRAND PETER
IPC: C07D323/06
CPC classification number: C07D323/06
Abstract: The invention relates to a method for producing trioxane by the trimerization of formaldehyde in an aqueous acidic solution and by subsequently separating out trioxane from a mixture (trioxane raw product) essentially consisting of trioxane, water and formaldehyde. The invention is characterized in that: a) the trioxane raw product from the trimerization is distilled; b) the trioxane is crystallized out; c) is separated out from the mother liquor; d) is subsequently melted, and; e) additional byproducts are removed by distillation.
Abstract translation: 一种用于通过在三聚酸性水溶液甲醛选自基本上由三恶烷,水和甲醛的混合物(三恶烷的粗产物)的组,其特征在于:a)三恶烷的粗产物从三聚制备三恶烷和随后除去三恶烷处理 蒸馏,b)将结晶化的三恶烷和c)从所述母液以及d分离)随后熔化和e)蒸馏除去其它副产物。
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公开(公告)号:AU2002356750A1
公开(公告)日:2003-06-10
申请号:AU2002356750
申请日:2002-11-28
Applicant: BASF AG
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公开(公告)号:DE10295499D2
公开(公告)日:2004-10-28
申请号:DE10295499
申请日:2002-11-28
Applicant: BASF AG
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公开(公告)号:AU2003232760A1
公开(公告)日:2003-12-02
申请号:AU2003232760
申请日:2003-05-13
Applicant: BASF AG
Inventor: FRIESE KATRIN , RAULS MATTHIAS , FREYHOF REINHARD , FRIESE THORSTEN , ARMBRUSTER HARALD , ZEINER HARTMUT , EGBERS GITTA , STROFER ECKHARD , HECK LUDWIG , HILDENBRAND PETER
IPC: C07D323/06
Abstract: Production of trioxane by trimerization of formaldehyde in aqueous acid solution followed by separation of trioxane from a crude trioxane product mixture of trioxane, water and formaldehyde comprises: distillation of the crude trioxane; crystallization of the trioxane and; separation from the mother liquor followed by melting and distillation of other byproducts. A process for the production of trioxane by trimerization of formaldehyde in aqueous acid solution followed by separation of trioxane from a crude trioxane product mixture of trioxane, water and formaldehyde comprises: (a) distillation of the crude trioxane; (b) crystallization of the trioxane and; (c) separation from the mother liquor followed by; (d) melting and; (e) distillation of other byproducts.
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公开(公告)号:DE10158813A1
公开(公告)日:2003-06-12
申请号:DE10158813
申请日:2001-11-30
Applicant: BASF AG
Inventor: STROEFER ECKHARD , ARMBRUSTER HARALD , EGBERS GITTA , FREYHOF REINHARD , FRIESE THORSTEN , HECK LUDWIG E , HILDENBRAND PETER , ZEINER HARTMUT , SCHOLL STEPHAN , GOERTZ HANS-HELMUT
Abstract: According to the invention, the production of oxymethylene homo- or co-polymers from an aqueous solution of formaldehyde and polyoxymethylene glycols is achieved, whereby 1) in a separation stage, water and formaldehyde are at least partly separated out from the aqueous solution, such that a phase containing polyoxymethylene glycols is obtained, in which the molar ratio of polyoxymethylene glycols to formaldehyde is greater than 1:0.6 and 2) the polyoxymethylene glycols obtained in stage 1) are reacted in the presence of polycondensation catalysts with abstraction of water to give oxymethylene homo- or co-polymers.
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公开(公告)号:DE10295499B4
公开(公告)日:2007-04-19
申请号:DE10295499
申请日:2002-11-28
Applicant: BASF AG
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公开(公告)号:DE50306511D1
公开(公告)日:2007-03-29
申请号:DE50306511
申请日:2003-05-13
Applicant: BASF AG
Inventor: FRIESE KATRIN , RAULS MATTHIAS , FREYHOF REINHARD , FRIESE THORSTEN , ARMBRUSTER HARALD , ZEINER HARTMUT , EGBERS GITTA , STROEFER ECKHARD , HECK LUDWIG , HILDENBRAND PETER
IPC: C07D323/06
Abstract: Production of trioxane by trimerization of formaldehyde in aqueous acid solution followed by separation of trioxane from a crude trioxane product mixture of trioxane, water and formaldehyde comprises: distillation of the crude trioxane; crystallization of the trioxane and; separation from the mother liquor followed by melting and distillation of other byproducts. A process for the production of trioxane by trimerization of formaldehyde in aqueous acid solution followed by separation of trioxane from a crude trioxane product mixture of trioxane, water and formaldehyde comprises: (a) distillation of the crude trioxane; (b) crystallization of the trioxane and; (c) separation from the mother liquor followed by; (d) melting and; (e) distillation of other byproducts.
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公开(公告)号:AT353883T
公开(公告)日:2007-03-15
申请号:AT03752664
申请日:2003-05-13
Applicant: BASF AG
Inventor: FRIESE KATRIN , RAULS MATTHIAS , FREYHOF REINHARD , FRIESE THORSTEN , ARMBRUSTER HARALD , ZEINER HARTMUT , EGBERS GITTA , STROEFER ECKHARD , HECK LUDWIG , HILDENBRAND PETER
IPC: C07D323/06
Abstract: Production of trioxane by trimerization of formaldehyde in aqueous acid solution followed by separation of trioxane from a crude trioxane product mixture of trioxane, water and formaldehyde comprises: distillation of the crude trioxane; crystallization of the trioxane and; separation from the mother liquor followed by melting and distillation of other byproducts. A process for the production of trioxane by trimerization of formaldehyde in aqueous acid solution followed by separation of trioxane from a crude trioxane product mixture of trioxane, water and formaldehyde comprises: (a) distillation of the crude trioxane; (b) crystallization of the trioxane and; (c) separation from the mother liquor followed by; (d) melting and; (e) distillation of other byproducts.
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公开(公告)号:PL374560A1
公开(公告)日:2005-10-31
申请号:PL37456003
申请日:2003-05-13
Applicant: BASF AG
Inventor: FRIESE KATRIN , RAULS MATTHIAS , FREYHOF REINHARD , FRIESE THORSTEN , ARMBRUSTER HARALD , ZEINER HARTMUT , EGBERS GITTA , STROEFER ECKHARD , HECK LUDWIG , HILDENBRAND PETER
IPC: C07D323/06
Abstract: Production of trioxane by trimerization of formaldehyde in aqueous acid solution followed by separation of trioxane from a crude trioxane product mixture of trioxane, water and formaldehyde comprises: distillation of the crude trioxane; crystallization of the trioxane and; separation from the mother liquor followed by melting and distillation of other byproducts. A process for the production of trioxane by trimerization of formaldehyde in aqueous acid solution followed by separation of trioxane from a crude trioxane product mixture of trioxane, water and formaldehyde comprises: (a) distillation of the crude trioxane; (b) crystallization of the trioxane and; (c) separation from the mother liquor followed by; (d) melting and; (e) distillation of other byproducts.
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公开(公告)号:AU2003232760A8
公开(公告)日:2003-12-02
申请号:AU2003232760
申请日:2003-05-13
Applicant: BASF AG
Inventor: HECK LUDWIG , HILDENBRAND PETER , EGBERS GITTA , FREYHOF REINHARD , ARMBRUSTER HARALD , STROFER ECKHARD , FRIESE KATRIN , FRIESE THORSTEN , RAULS MATTHIAS , ZEINER HARTMUT
IPC: C07D323/06
Abstract: Production of trioxane by trimerization of formaldehyde in aqueous acid solution followed by separation of trioxane from a crude trioxane product mixture of trioxane, water and formaldehyde comprises: distillation of the crude trioxane; crystallization of the trioxane and; separation from the mother liquor followed by melting and distillation of other byproducts. A process for the production of trioxane by trimerization of formaldehyde in aqueous acid solution followed by separation of trioxane from a crude trioxane product mixture of trioxane, water and formaldehyde comprises: (a) distillation of the crude trioxane; (b) crystallization of the trioxane and; (c) separation from the mother liquor followed by; (d) melting and; (e) distillation of other byproducts.
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