公开(公告)号：JP2005119269A

公开(公告)日：2005-05-12

申请号：JP2004226647

申请日：2004-08-03

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフト

Inventor： BAUMGARTL HORST ,  GROSS BERND ,  SCHIERHOLZ JENS

IPC: B29C43/02 ,  B29C44/56 ,  B29K61/20 ,  B29K105/04

CPC classification number: B29C44/5636 ,  B29C44/569

Abstract: PROBLEM TO BE SOLVED: To provide a molded article of melamine/formaldehyde foam, which makes the amount of emitted formaldehyde smaller.
SOLUTION: In this molded article composed of the melamine/formaldehyde foam, the amount of formaldehyde emitted from the molded article, which is measured according to the Deutsche Industrie Norm 55666, is smaller than 0.1 ppm. The molded article is obtained by the following treatments: (a) a foam is manufactured from a melamine/formaldehyde pre-condensate wherein a molar ratio between melamine and formaldehyde is higher than 0.5; (b) the foam, which is formed by the treatment (a), is annealed at a temperature lower than 200; and (c) the annealed foam is molded in a compressor for 15-120 seconds at a temperature of 160-240°C under an absolute pressure of 5-100 bars, so that the molded article can be obtained.
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供三聚氰胺/甲醛泡沫塑料的模制品，这使得排出的甲醛的量更小。 解决方案：在由三聚氰胺/甲醛泡沫体组成的模塑制品中，根据德国工业标准55666测量的模制品发射的甲醛的量小于0.1ppm。 通过以下处理获得成型品：（a）由三聚氰胺/甲醛预缩合物制造泡沫体，其中三聚氰胺与甲醛的摩尔比高于0.5; （b）通过处理（a）形成的泡沫体在低于200℃的温度下退火; 和（c）将退火的泡沫在压缩机中在160-240℃的温度下在5-100巴的绝对压力下在压缩机中模制15-120秒，从而可以获得模塑制品。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：WO0194436A3

公开(公告)日：2002-05-16

申请号：PCT/EP0106399

申请日：2001-06-06

Applicant: BASF AG ,  BAUMGARTL HORST ,  GROSS BERND ,  GRAVE ISIDOR DE ,  TRAUZETTEL WULF

Inventor： BAUMGARTL HORST ,  GROSS BERND ,  DE GRAVE ISIDOR ,  TRAUZETTEL WULF

IPC: C08G12/32 ,  C08J9/00 ,  C08L61/28

CPC classification number: C08J9/00 ,  C08G12/32 ,  C08J2205/05 ,  C08J2205/06 ,  C08J2361/28 ,  C08L61/28

Abstract: The invention relates to a method for producing elastic foamed materials which are based on a melamine/formaldehyde condensation product. According to the inventive method, a pre-condensate, having a mol ratio of melamine to formaldehyde which is greater than 1: 2, is foamed. Practically no emission of formaldehyde emanates from the foamed materials. No signal or only a very low signal ranging from 65ppm to 85 ppm occurs in the NMR 13 C/MAS spectrum.

Abstract translation: 本发明涉及一种方法，用于生产基于三聚氰胺/甲醛缩合产物的弹性泡沫体，其中，从大于1具有三聚氰胺到的甲醛的摩尔比预缩合：发泡2 该泡沫塑料显示出65〜85 ppm的，没有或仅有非常弱的信号的区域中无甲醛释放量实用C / MAS NMR谱中13发生。

公开(公告)号：DE3615561A1

公开(公告)日：1987-11-12

申请号：DE3615561

申请日：1986-05-09

Applicant: BASF AG

Inventor： WEBER HEINZ DR ,  GROSS BERND

IPC: C08K3/38 ,  C08G18/14 ,  C08G18/02 ,  C08G18/76 ,  C08L75/02 ,  E04B1/94

Abstract: Flame-resistant polyurea foams are produced by reacting organic polyisocyanates with water in the presence of catalysts, assistants, additives and borax as flameproofing agent, expediently in an amount of from 150 to 400 parts by weight per 100 parts by weight of organic polyisocyanate. The polyurea foams filled according to the invention with borax have densities of from 60 to 160 kg/m and are suitable for the insulation of buildings and means of transport.

公开(公告)号：DE4004599A1

公开(公告)日：1991-08-22

申请号：DE4004599

申请日：1990-02-15

Applicant: BASF AG

Inventor： GROSS BERND ,  WEBER HEINZ DR

IPC: B32B3/12 ,  B32B5/18 ,  B32B5/24 ,  B32B5/28

Abstract: Laminate comprises (a) foamed or honeycomb core layer, density 30-150 kg/cub m, of temp-resistant thermoplast or thermoset plastics material (A) and (b) at least one top layer of fibre-reinforced, temp-resistant, thermoplast or thermoset plastics material (B), core layer (a) having (c) at least one foamed insert, density 200-1000 kg/cub m, of temp-resistant thermoplast (C). - More specifically layer (a) is 4-40 mm thick, layer (b) is 0.1-1.5 mm thick, and insert (c) has dia 0.5-10 cm. (A), (B), and (C) have heat-dimensional stability temp, DIN 53461 (B), at least 130 deg C. Layer (a) is of foam and (A) and (C) are of same type of thermoplast, partic polyether-sulphone (I), polysulphone (II), polyetherimide, or polyamide. Or layer (a) is honeycomb of phenol resin-impregnated aromatic polyamide.

公开(公告)号：DE4002067A1

公开(公告)日：1991-08-14

申请号：DE4002067

申请日：1990-01-25

Applicant: BASF AG

Inventor： GROSS BERND ,  WEBER HEINZ DR ,  SCHUON GEORG

IPC: B32B3/02 ,  B29C44/12 ,  B32B1/04 ,  B32B3/12 ,  B32B5/18 ,  B32B27/28 ,  B32B27/34 ,  B32B27/42

公开(公告)号：DE502004005548D1

公开(公告)日：2008-01-03

申请号：DE502004005548

申请日：2004-07-31

Applicant: BASF AG

Inventor： BAUMGARTL HORST DR ,  GROSS BERND ,  SCHIERHOLZ JENS DR

IPC: B29C43/02 ,  C08J9/36 ,  B29C44/56 ,  B29K61/20 ,  B29K105/04

Abstract: Shaped article (A) of melamine-formaldehyde foam that has formaldehyde emission below 0.1 ppm, as measured by DIN 556661. Shaped article (A) of melamine-formaldehyde foam that has formaldehyde emission below 0.1 ppm, as measured by DIN 556661, is prepared by: (a) generating a foam from a precondensate having melamine:formaldehyde mole ratio over 0.5; (b) conditioning the foam at below 200[deg]C; and (c) compressing the foam, in a press, at 160-240[deg]C and 5-100 bar (absolute) for 15-120 s. Independent claims are also included for the following: (1) method for preparing (A), as described; and (2) melamine-formaldehyde foam with formaldehyde emission below 0.1 ppm, prepared by steps (a) and (b) above.

公开(公告)号：AU8573101A

公开(公告)日：2001-12-17

申请号：AU8573101

申请日：2001-06-06

Applicant: BASF AG

Inventor： BAUMGARTL HORST ,  GROSS BERND ,  GRAVE ISIDOR DE ,  TRAUZETTEL WULF

IPC: C08G12/32 ,  C08J9/00 ,  C08L61/28

公开(公告)号：DE3433389A1

公开(公告)日：1986-03-20

申请号：DE3433389

申请日：1984-09-12

Applicant: BASF AG

Inventor： GROSS BERND ,  HAHN KLAUS DR ,  WEBER HEINZ DR

IPC: C08G18/08 ,  C08K3/22 ,  C08K5/098 ,  C08L75/02 ,  C08G18/14 ,  C08J9/02 ,  C09K21/14 ,  E04B1/94

Abstract: Flame-resistant polyurea foams having reducing evolution of smoke and fumes in the event of fire and advantageously having densities of from 5 to 15 kg/m are prepared by reacting organic polyisocyanates with water in the presence of catalysts, assistants, flameproofing additives and smoke-reducing additives. The smoke-reducing additives used are molybdenum compounds, such as, for example, molybdenum oxides, molybdic acid and molybdenum chlorides, metal oxides, such as, for example, copper(II) and/or molybdenum(VI) oxide, and preferably soluble organic metal compounds, such as, for example, copper naphthenate and/or copper oleate, expediently in amounts of from 3 to 30 parts by weight per 100 parts by weight of organic polyisocyanate. The polyurea foams according to the invention are particularly useful for filling cavities in mining.