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公开(公告)号：WO2006029807A2
公开(公告)日：2006-03-23
申请号：PCT/EP2005009820
申请日：2005-09-13
Applicant: BASF AG , HUBER GUENTHER , LUTZ MICHAEL , WILLE MICHAEL , FRIEDRICH HOLGER , GUTH JOSEF , BEHLING UWE , FRANKE AXEL , GUNKEL ELISABETH
Inventor： HUBER GUENTHER , LUTZ MICHAEL , WILLE MICHAEL , FRIEDRICH HOLGER , GUTH JOSEF , BEHLING UWE , FRANKE AXEL , GUNKEL ELISABETH
Abstract: The invention relates to an electrolysis device for the production of alkali metals from a liquid alkali metal heavy metal alloy (6), comprising at least two tubes (1) which are arranged in a substantially horizontal manner above each other and which are connected to each other by means of tube couplings (3), forming an electrolysis unit (2); two solid electrolyte tubes (12) which are arranged in each tube (1) and which are closed at one end and which have an opening (11) at the other, conducting the alkali metal ions, wherein the solid electrolyte tubes (12) are arranged concentrically in the tube (1) and are oriented with the opening (11) towards one end of the tube (1) such that a first annular gap for guiding the liquid alkali metal heavy metal alloy (6) forming an anode, is located between the inside of the tube (1) and the outside of the solid electrolyte tubes (12); an alloy inlet (8) and an alloy outlet (9) for the liquid alkali metal heavy metal alloy (6) in each of the tubes (1) which lead into the first annular gap (13) of a tube (1), being horizontally distanced from each other, from the top down; an inner chamber (14) which is sealed off from the alloy inlet (8), first annular gap (13) and alloy outlet (9) in each of the solid electrolyte tubes (12) for receiving liquid alkali metal which can be used as a cathode and which is connected to the alkali metal outlet (15); and two respective closure devices (4) which are arranged at the two ends of each tube (1).
Abstract translation: 本发明涉及的电解装置用于从（6）具有液体碱金属 - 重金属合金制备碱金属 - 至少两个叠置基本水平设置，通过连接件的装置（3）相互连接的管（1）形成一个电解单元（2）， 布置的两个在每个管（1）的，在一端封闭，在另一端具有固体电解质管（12），其进行碱金属离子，固体电解质管（12）在所述管（1）同心布置，并具有开口（11） - 与（1）的面向所述管的开口（11）一个端部，使得第一环形间隙（13），用于引导阳极形成液态碱金属 - 重金属的管的内部之间的合金（6）（1）和外侧 固体电解质管（12）， - 一入口合金（8）和一个出口合金（9），用于将液体碱金属Schwermetalllegier UNG（6）在各管（1）的情况下，互相水平地从上方或从下方到管（1）开放的第一环形间隙（13）隔开， - 一个相对于该合金的入口（8），所述第一环形间隙（13） 并在每一个固体电解质管（12）的合金流动密封（9）的内部（14），用于接收所述可用作为与碱金属出口（15）连接的阴极液体碱金属，以及 - 两个封闭装置（4），这两个在 各管（1）被布置的结束。
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公开(公告)号：DE502005002528D1
公开(公告)日：2008-02-21
申请号：DE502005002528
申请日：2005-09-13
Applicant: BASF AG
Inventor： HUBER GUENTHER , LUTZ MICHAEL , WILLE MICHAEL , FRIEDRICH HOLGER , GUTH JOSEF , BEHLING UWE , FRANKE AXEL , GUNKEL ELISABETH
Abstract: An electrolysis device producing alkali metals from a liquid alkali metal heavy metal alloy, including at least two connected tubes forming an electrolysis unit. Two solid electrolyte tubes are arranged concentrically in each tube and oriented with openings towards one end of each tube such that a first annular gap for guiding a liquid alkali metal forming an anode is located between the inside of the tube and the outside of the solid electrolyte tubes. An alloy inlet and outlet for the liquid alkali metal in each of the tubes leads into the first annular gap of a tube. An inner chamber sealed off from the alloy inlet, first annular gap, and alloy outlet in each solid electrolyte tube receives liquid alkali metal that can be used as a cathode connected to the alkali metal outlet. Two respective closure devices are arranged at the two ends of each tube.
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公开(公告)号：AT383458T
公开(公告)日：2008-01-15
申请号：AT05784834
申请日：2005-09-13
Applicant: BASF AG
Inventor： HUBER GUENTHER , LUTZ MICHAEL , WILLE MICHAEL , FRIEDRICH HOLGER , GUTH JOSEF , BEHLING UWE , FRANKE AXEL , GUNKEL ELISABETH
Abstract: An electrolysis device producing alkali metals from a liquid alkali metal heavy metal alloy, including at least two connected tubes forming an electrolysis unit. Two solid electrolyte tubes are arranged concentrically in each tube and oriented with openings towards one end of each tube such that a first annular gap for guiding a liquid alkali metal forming an anode is located between the inside of the tube and the outside of the solid electrolyte tubes. An alloy inlet and outlet for the liquid alkali metal in each of the tubes leads into the first annular gap of a tube. An inner chamber sealed off from the alloy inlet, first annular gap, and alloy outlet in each solid electrolyte tube receives liquid alkali metal that can be used as a cathode connected to the alkali metal outlet. Two respective closure devices are arranged at the two ends of each tube.
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