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公开(公告)号:PT788475E
公开(公告)日:2000-04-28
申请号:PT95917966
申请日:1995-04-26
Applicant: BASF AG
Inventor: ALBRECHT HARREUS DR , HARTMANN HORST , NORBERT GOTZ DR , HARALD RANG DR , HEIMANN FRANK , BORCHERS DIRK , MAYWALD VOLKER , BUSCHULTE THOMAS
IPC: B01J23/02 , B01J31/02 , C07B61/00 , C07C239/20 , C07C249/12 , C07C251/54 , C07C309/66
Abstract: PCT No. PCT/EP95/01581 Sec. 371 Date Nov. 4, 1996 Sec. 102(e) Date Nov. 4, 1996 PCT Filed Apr. 26, 1995 PCT Pub. No. WO95/30648 PCT Pub. Date Nov. 16, 1995Preparation of mixtures of O-phenoxyalkylhydroxylamines Ia and Ib (Ia): H2NOCH2CH(R1)OAr (Ib): H2NOCH(R1)CH2OAr and the corresponding salt mixtures by a) converting mixtures of isomers of O-(2-hydroxyethyl)oximes IIa and IIb (IIa): (III): into a mixture of sulfonates IVa and IVb (IVa): (IVb): b) reacting this mixture of IVa and IVb with a phenol HO-Ar (V) to give a mixture of O-phenoxyalkoximes VIa and VIb (VIa): (VIb): c) hydrolyzing this mixture in the presence of an acid and, if desired d) liberating the O-phenoxyalkylhydroxylamines Ia and Ib from the resulting salts using a mineral acid. Compounds Ia/Ib and VIa/VIb are important intermediates for crop protection agents.
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公开(公告)号:PT871609E
公开(公告)日:2002-04-29
申请号:PT96939936
申请日:1996-11-28
Applicant: BASF AG
Inventor: WESTPHALEN KARL-OTTO , HARALD RANG DR , BRATZ MATTHIAS , MISSLITZ ULF , JAGER KARL-FRIEDRICH , BENOIT REMY
IPC: A01N35/10 , A01N43/10 , A01N43/14 , A01N43/16 , A01N43/18 , C07C239/20 , C07C251/42 , C07C251/50 , C07C323/47 , C07D309/06 , C07D335/02
Abstract: PCT No. PCT/EP96/05255 Sec. 371 Date Jun. 5, 1998 Sec. 102(e) Date Jun. 5, 1998 PCT Filed Nov. 28, 1996 PCT Pub. No. WO97/20807 PCT Pub. Date Jun. 12, 1997Herbicidally active cyclohexenone oxime ether metal salts of formula I where Ra, Rb, Rc, Rd, Re, Alk and Rf are as defined in the specification disclosure, having an improved shelf life and thermal stability and reduced water vapor uptake.
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