公开(公告)号：CA2172259A1

公开(公告)日：1995-03-30

申请号：CA2172259

申请日：1994-09-16

Applicant: BASF AG

Inventor： KARRER LOTHAR ,  NEUMANN HANS-PETER ,  EICHHORN HANS-DIETER ,  JARRET ROBIN STUART

IPC: B01J23/84 ,  B01J23/00 ,  B01J23/31 ,  B01J23/85 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  B01J37/00 ,  C07B35/04 ,  C07B41/06 ,  C07B41/08 ,  C07B43/08 ,  C07C51/215 ,  C07C51/235 ,  C07C51/25 ,  C07C51/377 ,  C07C253/26 ,  C07C255/08 ,  C07C57/05 ,  C07C5/48

Abstract: Catalysts of general formula (I): ¢AaBbOx!p ¢CcDdFeeCofEiFjOy!q, in which the variables have the following meanings: A = bismuth, tellurium, antimony, tin and/or copper; B = molybdenum and/or tungsten; C = an alkaline metal, thallium and/or samarium; D = an alkaline earth metal, nickel, copper, cobalt, manganese, zinc, tin, cerium, chromium, cadmium, molybdenum, bismuth and/or mercury; E = phosphorus, arsenic, boron and/or antimony; F = a rare-earth metal, vanadium and/or uranium; a = 0.01 to 8; b = 0.1 to 30; c = 0 to 4; d = 0 to 20; c = 0 to 20; f = 0 to 20; i = 0 to 6; j = 0 to 15; x and y are figures determined by the valency and frequency of the elements in (I) differing from oxygen and p and are figures, the ration p/q of which lies in the range from 0.001 to 0.099, and a process for producing said catalysts, their use for the ammono-oxidation, oxidation or dehydrogenation of ethylenically unsaturated compounds and a process for ammono-oxidation, oxidation or oxidative dehydrogenation of ethylenically unsaturated compounds in the presence of the catalyst of the invention.

公开(公告)号：DE4332542A1

公开(公告)日：1995-03-30

申请号：DE4332542

申请日：1993-09-24

Applicant: BASF AG

Inventor： KARRER LOTHAR DR ,  NEUMANN HANS-PETER DR ,  EICHHORN HANS-DIETER DR ,  JARRET ROBIN STUART

IPC: B01J23/84 ,  B01J23/00 ,  B01J23/31 ,  B01J23/85 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  B01J37/00 ,  C07B35/04 ,  C07B41/06 ,  C07B41/08 ,  C07B43/08 ,  C07C51/215 ,  C07C51/235 ,  C07C51/25 ,  C07C51/377 ,  C07C253/26 ,  C07C255/08 ,  B01J23/30 ,  B01J23/28 ,  B01J27/199 ,  B01J27/192 ,  B01J27/19 ,  B01J27/188 ,  B01J27/057

Abstract: PCT No. PCT/EP94/03111 Sec. 371 Date Mar. 22, 1996 Sec. 102(e) Date Mar. 22, 1996 PCT Filed Sep. 16, 1994 PCT Pub. No. WO95/08391 PCT Pub. Date Mar. 30, 1995Catalysts of the formula I [AaBbOx]p [CcDdFeeCofEiFjOy]qI, where A is bismuth, tellurium, antimony, tin and/or copper, B is molybdenum and/or tungsten, C is an alkali metal, thallium and/or samarium, D is an alkaline earth metal, nickel, copper, cobalt, manganese, zinc, tin, cerium, chromium, cadmium, molybdenum, bismuth and/or mercury, E is phosphorus, arsenic, boron and/or antimony, F is a rare-earth metal, vanadium and/or uranium, a is from 0.01 to 8, b is from 0.1 to 30, c is from 0 to 4, d is from 0 to 20, e is from 0 to 20, f is from 0 to 20, i is from 0 to 6, j is from 0 to 15, x and y are numbers determined by the valency and frequency of the elements other than oxygen in I, and p and q are numbers whose ratio p/q is in the range from 0.001 to 0.099, and a process for the preparation of these catalysts, their use for the ammonoxidation, oxidation or dehydrogenation of ethylenically unsaturated compounds, and a process for the ammonoxidation, oxidation or oxidative dehydrogenation of ethylenically unsaturated compounds in the presence of the novel catalysts.

公开(公告)号：EP0720512B1

公开(公告)日：1997-12-29

申请号：EP94927623

申请日：1994-09-16

Applicant: BASF AG

Inventor： KARRER LOTHAR ,  NEUMANN HANS-PETER ,  EICHHORN HANS-DIETER ,  JARRET ROBIN STUART

IPC: B01J23/84 ,  B01J23/85 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  B01J37/00 ,  C07B35/04 ,  C07B41/06 ,  C07B41/08 ,  C07B43/08 ,  C07C51/215 ,  C07C51/235 ,  C07C51/25 ,  C07C51/377 ,  C07C253/26 ,  C07C255/08 ,  B01J23/00 ,  B01J23/31

CPC classification number: C07C253/26 ,  B01J23/002 ,  B01J23/85 ,  B01J23/88 ,  B01J23/8876 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/0006 ,  B01J37/0036 ,  B01J37/0045 ,  B01J2523/00 ,  C07B35/04 ,  C07B41/06 ,  C07B41/08 ,  C07B43/08 ,  C07C51/215 ,  C07C51/235 ,  C07C51/25 ,  C07C51/252 ,  C07C51/377 ,  Y02P20/52 ,  B01J2523/13 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08

Abstract: Catalysts of general formula (I): [AaBbOx]p [CcDdFeeCofEiFjOy]q, in which the variables have the following meanings: A = bismuth, tellurium, antimony, tin and/or copper; B = molybdenum and/or tungsten; C = an alkaline metal, thallium and/or samarium; D = an alkaline earth metal, nickel, copper, cobalt, manganese, zinc, tin, cerium, chromium, cadmium, molybdenum, bismuth and/or mercury; E = phosphorus, arsenic, boron and/or antimony; F = a rare-earth metal, vanadium and/or uranium; a = 0.01 to 8; b = 0.1 to 30; c = 0 to 4; d = 0 to 20; e = 0 to 20; f = 0 to 20; i = 0 to 6; j = 0 to 15; x and y are figures determined by the valency and frequency of the elements in (I) differing from oxygen and p and q are figures, the ratio p/q of which lies in the range from 0.001 to 0.099, and a process for producing said catalysts, their use for the ammono-oxidation, oxidation or dehydrogenation of ethylenically unsaturated compounds and a process for ammono-oxidation, oxidation or oxidative dehydrogenation of ethylenically unsaturated compounds in the presence of the catalyst of the invention.

公开(公告)号：ES2110780T3

公开(公告)日：1998-02-16

申请号：ES94927623

申请日：1994-09-16

Applicant: BASF AG

Inventor： KARRER LOTHAR ,  NEUMANN HANS-PETER ,  EICHHORN HANS-DIETER ,  JARRET ROBIN STUART

IPC: B01J23/84 ,  B01J23/00 ,  B01J23/31 ,  B01J23/85 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  B01J37/00 ,  C07B35/04 ,  C07B41/06 ,  C07B41/08 ,  C07B43/08 ,  C07C51/215 ,  C07C51/235 ,  C07C51/25 ,  C07C51/377 ,  C07C253/26 ,  C07C255/08

Abstract: PCT No. PCT/EP94/03111 Sec. 371 Date Mar. 22, 1996 Sec. 102(e) Date Mar. 22, 1996 PCT Filed Sep. 16, 1994 PCT Pub. No. WO95/08391 PCT Pub. Date Mar. 30, 1995Catalysts of the formula I [AaBbOx]p [CcDdFeeCofEiFjOy]qI, where A is bismuth, tellurium, antimony, tin and/or copper, B is molybdenum and/or tungsten, C is an alkali metal, thallium and/or samarium, D is an alkaline earth metal, nickel, copper, cobalt, manganese, zinc, tin, cerium, chromium, cadmium, molybdenum, bismuth and/or mercury, E is phosphorus, arsenic, boron and/or antimony, F is a rare-earth metal, vanadium and/or uranium, a is from 0.01 to 8, b is from 0.1 to 30, c is from 0 to 4, d is from 0 to 20, e is from 0 to 20, f is from 0 to 20, i is from 0 to 6, j is from 0 to 15, x and y are numbers determined by the valency and frequency of the elements other than oxygen in I, and p and q are numbers whose ratio p/q is in the range from 0.001 to 0.099, and a process for the preparation of these catalysts, their use for the ammonoxidation, oxidation or dehydrogenation of ethylenically unsaturated compounds, and a process for the ammonoxidation, oxidation or oxidative dehydrogenation of ethylenically unsaturated compounds in the presence of the novel catalysts.

公开(公告)号：AU7697294A

公开(公告)日：1995-04-10

申请号：AU7697294

申请日：1994-09-16

Applicant: BASF AG

Inventor： KARRER LOTHAR ,  NEUMANN HANS-PETER ,  EICHHORN HANS-DIETER ,  JARRET ROBIN STUART

IPC: B01J23/84 ,  B01J23/00 ,  B01J23/31 ,  B01J23/85 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  B01J37/00 ,  C07B35/04 ,  C07B41/06 ,  C07B41/08 ,  C07B43/08 ,  C07C51/215 ,  C07C51/235 ,  C07C51/25 ,  C07C51/377 ,  C07C253/26 ,  C07C255/08

Abstract: PCT No. PCT/EP94/03111 Sec. 371 Date Mar. 22, 1996 Sec. 102(e) Date Mar. 22, 1996 PCT Filed Sep. 16, 1994 PCT Pub. No. WO95/08391 PCT Pub. Date Mar. 30, 1995Catalysts of the formula I [AaBbOx]p [CcDdFeeCofEiFjOy]qI, where A is bismuth, tellurium, antimony, tin and/or copper, B is molybdenum and/or tungsten, C is an alkali metal, thallium and/or samarium, D is an alkaline earth metal, nickel, copper, cobalt, manganese, zinc, tin, cerium, chromium, cadmium, molybdenum, bismuth and/or mercury, E is phosphorus, arsenic, boron and/or antimony, F is a rare-earth metal, vanadium and/or uranium, a is from 0.01 to 8, b is from 0.1 to 30, c is from 0 to 4, d is from 0 to 20, e is from 0 to 20, f is from 0 to 20, i is from 0 to 6, j is from 0 to 15, x and y are numbers determined by the valency and frequency of the elements other than oxygen in I, and p and q are numbers whose ratio p/q is in the range from 0.001 to 0.099, and a process for the preparation of these catalysts, their use for the ammonoxidation, oxidation or dehydrogenation of ethylenically unsaturated compounds, and a process for the ammonoxidation, oxidation or oxidative dehydrogenation of ethylenically unsaturated compounds in the presence of the novel catalysts.