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公开(公告)号:JP2007075819A
公开(公告)日:2007-03-29
申请号:JP2006316854
申请日:2006-11-24
Applicant: Basf Ag , ビーエーエスエフ アクチェンゲゼルシャフトBASF Aktiengesellschaft
Inventor: KARRER LOTHAR , PAPE FRANK-FRIEDRICH , KOEHLER ULRICH , BECKER RAINER , WEIDLICH PETER
IPC: B01J23/22 , B01J23/18 , B01J23/30 , B01J37/02 , B01J37/08 , C07B61/00 , C07C253/28 , C07C255/50 , C07C255/51
CPC classification number: C07C253/28 , B01J23/18 , B01J23/22 , C07C255/51 , C07C255/50
Abstract: PROBLEM TO BE SOLVED: To simultaneously solve the unfavorable problems of a catalyst to be used for a fluidized-bed method, including low flowability, low abrasiveness, and low transmission property.
SOLUTION: The carrier catalyst for ammooxidation comprises (a) a carrier material containing aluminum oxide, silicon dioxide, titanium dioxide, and/or zirconium dioxide and (b) an active material containing as essential compositions vanadium and antimony in oxidic form, wherein the content of the carrier material is 80 wt.% or more of the total weight of the carrier catalyst. The carrier catalyst for ammonoxidation is obtained by (1) impregnating the carrier material with a solution or a suspension of a compound containing the active material, (2) separating and removing an excess amount of liquid from the thus obtained mixture, (3) drying the impregnated carrier material, and (4) calcining the impregnated carrier material under oxidation conditions.
COPYRIGHT: (C)2007,JPO&INPITAbstract translation: 要解决的问题:为了同时解决用于流化床方法的催化剂的不利问题,包括低流动性,低磨损性和低透射性。 用于氨氧化的载体催化剂包括(a)包含氧化铝,二氧化硅,二氧化钛和/或二氧化锆的载体材料和(b)以氧化物形式含有作为必需组成的钒和锑的活性材料, 其中载体材料的含量为载体催化剂总重量的80重量%以上。 用于氨氧化的载体催化剂通过以下方法获得:(1)用含有活性物质的化合物的溶液或悬浮液浸渍载体材料,(2)从由此获得的混合物中分离和除去过量的液体,(3)干燥 浸渍的载体材料,和(4)在氧化条件下煅烧浸渍的载体材料。 版权所有(C)2007,JPO&INPIT
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公开(公告)号:EP0720512B1
公开(公告)日:1997-12-29
申请号:EP94927623
申请日:1994-09-16
Applicant: BASF AG
Inventor: KARRER LOTHAR , NEUMANN HANS-PETER , EICHHORN HANS-DIETER , JARRET ROBIN STUART
IPC: B01J23/84 , B01J23/85 , B01J23/88 , B01J23/887 , B01J23/888 , B01J35/00 , B01J37/00 , C07B35/04 , C07B41/06 , C07B41/08 , C07B43/08 , C07C51/215 , C07C51/235 , C07C51/25 , C07C51/377 , C07C253/26 , C07C255/08 , B01J23/00 , B01J23/31
CPC classification number: C07C253/26 , B01J23/002 , B01J23/85 , B01J23/88 , B01J23/8876 , B01J23/888 , B01J23/8885 , B01J35/0006 , B01J37/0036 , B01J37/0045 , B01J2523/00 , C07B35/04 , C07B41/06 , C07B41/08 , C07B43/08 , C07C51/215 , C07C51/235 , C07C51/25 , C07C51/252 , C07C51/377 , Y02P20/52 , B01J2523/13 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , C07C255/08
Abstract: Catalysts of general formula (I): [AaBbOx]p [CcDdFeeCofEiFjOy]q, in which the variables have the following meanings: A = bismuth, tellurium, antimony, tin and/or copper; B = molybdenum and/or tungsten; C = an alkaline metal, thallium and/or samarium; D = an alkaline earth metal, nickel, copper, cobalt, manganese, zinc, tin, cerium, chromium, cadmium, molybdenum, bismuth and/or mercury; E = phosphorus, arsenic, boron and/or antimony; F = a rare-earth metal, vanadium and/or uranium; a = 0.01 to 8; b = 0.1 to 30; c = 0 to 4; d = 0 to 20; e = 0 to 20; f = 0 to 20; i = 0 to 6; j = 0 to 15; x and y are figures determined by the valency and frequency of the elements in (I) differing from oxygen and p and q are figures, the ratio p/q of which lies in the range from 0.001 to 0.099, and a process for producing said catalysts, their use for the ammono-oxidation, oxidation or dehydrogenation of ethylenically unsaturated compounds and a process for ammono-oxidation, oxidation or oxidative dehydrogenation of ethylenically unsaturated compounds in the presence of the catalyst of the invention.
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公开(公告)号:ES2110780T3
公开(公告)日:1998-02-16
申请号:ES94927623
申请日:1994-09-16
Applicant: BASF AG
Inventor: KARRER LOTHAR , NEUMANN HANS-PETER , EICHHORN HANS-DIETER , JARRET ROBIN STUART
IPC: B01J23/84 , B01J23/00 , B01J23/31 , B01J23/85 , B01J23/88 , B01J23/887 , B01J23/888 , B01J35/00 , B01J37/00 , C07B35/04 , C07B41/06 , C07B41/08 , C07B43/08 , C07C51/215 , C07C51/235 , C07C51/25 , C07C51/377 , C07C253/26 , C07C255/08
Abstract: PCT No. PCT/EP94/03111 Sec. 371 Date Mar. 22, 1996 Sec. 102(e) Date Mar. 22, 1996 PCT Filed Sep. 16, 1994 PCT Pub. No. WO95/08391 PCT Pub. Date Mar. 30, 1995Catalysts of the formula I [AaBbOx]p [CcDdFeeCofEiFjOy]qI, where A is bismuth, tellurium, antimony, tin and/or copper, B is molybdenum and/or tungsten, C is an alkali metal, thallium and/or samarium, D is an alkaline earth metal, nickel, copper, cobalt, manganese, zinc, tin, cerium, chromium, cadmium, molybdenum, bismuth and/or mercury, E is phosphorus, arsenic, boron and/or antimony, F is a rare-earth metal, vanadium and/or uranium, a is from 0.01 to 8, b is from 0.1 to 30, c is from 0 to 4, d is from 0 to 20, e is from 0 to 20, f is from 0 to 20, i is from 0 to 6, j is from 0 to 15, x and y are numbers determined by the valency and frequency of the elements other than oxygen in I, and p and q are numbers whose ratio p/q is in the range from 0.001 to 0.099, and a process for the preparation of these catalysts, their use for the ammonoxidation, oxidation or dehydrogenation of ethylenically unsaturated compounds, and a process for the ammonoxidation, oxidation or oxidative dehydrogenation of ethylenically unsaturated compounds in the presence of the novel catalysts.
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公开(公告)号:AU7697294A
公开(公告)日:1995-04-10
申请号:AU7697294
申请日:1994-09-16
Applicant: BASF AG
Inventor: KARRER LOTHAR , NEUMANN HANS-PETER , EICHHORN HANS-DIETER , JARRET ROBIN STUART
IPC: B01J23/84 , B01J23/00 , B01J23/31 , B01J23/85 , B01J23/88 , B01J23/887 , B01J23/888 , B01J35/00 , B01J37/00 , C07B35/04 , C07B41/06 , C07B41/08 , C07B43/08 , C07C51/215 , C07C51/235 , C07C51/25 , C07C51/377 , C07C253/26 , C07C255/08
Abstract: PCT No. PCT/EP94/03111 Sec. 371 Date Mar. 22, 1996 Sec. 102(e) Date Mar. 22, 1996 PCT Filed Sep. 16, 1994 PCT Pub. No. WO95/08391 PCT Pub. Date Mar. 30, 1995Catalysts of the formula I [AaBbOx]p [CcDdFeeCofEiFjOy]qI, where A is bismuth, tellurium, antimony, tin and/or copper, B is molybdenum and/or tungsten, C is an alkali metal, thallium and/or samarium, D is an alkaline earth metal, nickel, copper, cobalt, manganese, zinc, tin, cerium, chromium, cadmium, molybdenum, bismuth and/or mercury, E is phosphorus, arsenic, boron and/or antimony, F is a rare-earth metal, vanadium and/or uranium, a is from 0.01 to 8, b is from 0.1 to 30, c is from 0 to 4, d is from 0 to 20, e is from 0 to 20, f is from 0 to 20, i is from 0 to 6, j is from 0 to 15, x and y are numbers determined by the valency and frequency of the elements other than oxygen in I, and p and q are numbers whose ratio p/q is in the range from 0.001 to 0.099, and a process for the preparation of these catalysts, their use for the ammonoxidation, oxidation or dehydrogenation of ethylenically unsaturated compounds, and a process for the ammonoxidation, oxidation or oxidative dehydrogenation of ethylenically unsaturated compounds in the presence of the novel catalysts.
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公开(公告)号:DE102004012336A1
公开(公告)日:2005-09-22
申请号:DE102004012336
申请日:2004-03-11
Applicant: BASF AG
Inventor: QUASCHNING VERONIKA , BOHRES EDWARD , HIBST HARTMUT , STAECK BIANCA , KARRER LOTHAR , BECHTOLSHEIMER HANS-HEINRICH , BROX WOLFGANG
IPC: B01J23/18 , B01J23/843 , C07C41/03 , C07C43/11
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公开(公告)号:DE59603846D1
公开(公告)日:2000-01-13
申请号:DE59603846
申请日:1996-09-30
Applicant: BASF AG
Inventor: KARRER LOTHAR , PAPE FRANK-FRIEDRICH , KNEUPER HEINZ-JOSEF , HUELLMANN MICHAEL
IPC: C07D213/84 , B01J23/18 , B01J23/22 , B01J23/847 , B01J23/90 , C07B61/00 , C07C253/24 , C07C253/28 , C07C255/32 , C07C255/49
Abstract: Prepn. of (hetero)aromatic nitriles (I) of formula (A; at least one of R1-R6 = CN or 1-7 C cycloalkyl) involves gas phase reaction of (hetero)aromatic hydrocarbons (II) of formula (A; at least one of R1-R6 = 1-8 C alkyl) with NH3 and (gas contg.) O2 at 200-600 degrees C and 0.1-5 bar on supported catalyst contg. 0.5-20 wt.% V oxide. The novelty is that the supported catalyst consists of 2-30 grain fractions, the average dia. of which differs by 10-80%, and the support has a bulk density of 0.6-1.2 kg/l; X = N or C-R6; R1-R6 = as above, otherwise H, 1-8 C alkyl, halogen, CF3, NO2, amino, 1-8 C aminoalkyl or OH. Also claimed is the supported catalyst per se and its prepn.
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公开(公告)号:DE112005000519A5
公开(公告)日:2007-07-26
申请号:DE112005000519
申请日:2005-03-04
Applicant: BASF AG
Inventor: WLOKA VERONIKA , BOHRES EDWARD , HIBST HARTMUT , STAECK BIANCA , KARRER LOTHAR , BECHTOLSHEIMER HANS-HEINRICH , BROX WOLFGANG
IPC: C07C41/03 , B01J23/18 , B01J23/843 , C07C43/13
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公开(公告)号:DE59404905D1
公开(公告)日:1998-02-05
申请号:DE59404905
申请日:1994-09-16
Applicant: BASF AG
Inventor: KARRER LOTHAR , NEUMANN HANS-PETER , EICHHORN HANS-DIETER , JARRET ROBIN
IPC: B01J23/84 , B01J23/00 , B01J23/31 , B01J23/85 , B01J23/88 , B01J23/887 , B01J23/888 , B01J35/00 , B01J37/00 , C07B35/04 , C07B41/06 , C07B41/08 , C07B43/08 , C07C51/215 , C07C51/235 , C07C51/25 , C07C51/377 , C07C253/26 , C07C255/08
Abstract: PCT No. PCT/EP94/03111 Sec. 371 Date Mar. 22, 1996 Sec. 102(e) Date Mar. 22, 1996 PCT Filed Sep. 16, 1994 PCT Pub. No. WO95/08391 PCT Pub. Date Mar. 30, 1995Catalysts of the formula I [AaBbOx]p [CcDdFeeCofEiFjOy]qI, where A is bismuth, tellurium, antimony, tin and/or copper, B is molybdenum and/or tungsten, C is an alkali metal, thallium and/or samarium, D is an alkaline earth metal, nickel, copper, cobalt, manganese, zinc, tin, cerium, chromium, cadmium, molybdenum, bismuth and/or mercury, E is phosphorus, arsenic, boron and/or antimony, F is a rare-earth metal, vanadium and/or uranium, a is from 0.01 to 8, b is from 0.1 to 30, c is from 0 to 4, d is from 0 to 20, e is from 0 to 20, f is from 0 to 20, i is from 0 to 6, j is from 0 to 15, x and y are numbers determined by the valency and frequency of the elements other than oxygen in I, and p and q are numbers whose ratio p/q is in the range from 0.001 to 0.099, and a process for the preparation of these catalysts, their use for the ammonoxidation, oxidation or dehydrogenation of ethylenically unsaturated compounds, and a process for the ammonoxidation, oxidation or oxidative dehydrogenation of ethylenically unsaturated compounds in the presence of the novel catalysts.
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公开(公告)号:CA2172259A1
公开(公告)日:1995-03-30
申请号:CA2172259
申请日:1994-09-16
Applicant: BASF AG
Inventor: KARRER LOTHAR , NEUMANN HANS-PETER , EICHHORN HANS-DIETER , JARRET ROBIN STUART
IPC: B01J23/84 , B01J23/00 , B01J23/31 , B01J23/85 , B01J23/88 , B01J23/887 , B01J23/888 , B01J35/00 , B01J37/00 , C07B35/04 , C07B41/06 , C07B41/08 , C07B43/08 , C07C51/215 , C07C51/235 , C07C51/25 , C07C51/377 , C07C253/26 , C07C255/08 , C07C57/05 , C07C5/48
Abstract: Catalysts of general formula (I): ¢AaBbOx!p ¢CcDdFeeCofEiFjOy!q, in which the variables have the following meanings: A = bismuth, tellurium, antimony, tin and/or copper; B = molybdenum and/or tungsten; C = an alkaline metal, thallium and/or samarium; D = an alkaline earth metal, nickel, copper, cobalt, manganese, zinc, tin, cerium, chromium, cadmium, molybdenum, bismuth and/or mercury; E = phosphorus, arsenic, boron and/or antimony; F = a rare-earth metal, vanadium and/or uranium; a = 0.01 to 8; b = 0.1 to 30; c = 0 to 4; d = 0 to 20; c = 0 to 20; f = 0 to 20; i = 0 to 6; j = 0 to 15; x and y are figures determined by the valency and frequency of the elements in (I) differing from oxygen and p and are figures, the ration p/q of which lies in the range from 0.001 to 0.099, and a process for producing said catalysts, their use for the ammono-oxidation, oxidation or dehydrogenation of ethylenically unsaturated compounds and a process for ammono-oxidation, oxidation or oxidative dehydrogenation of ethylenically unsaturated compounds in the presence of the catalyst of the invention.
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