公开(公告)号：AU2003250141B2

公开(公告)日：2009-09-10

申请号：AU2003250141

申请日：2003-07-23

Applicant: BASF AG

Inventor： KINDLER KLAUS ,  HILL THOMAS ,  HEIDA BERND

IPC: C07C7/08

Abstract: Sudstituted the abstract with a new abstract as follows: The invention relates to a continuous process for separation a mixture of hydrocarbons which has beenobtained by extractive distillation of C 4 fraction useing a selective solvent and the hydrocarbons from the fraction C 4 which are more readily soluble in the selective solvent than are the butanes and the butenes. The mixture is fed into a first distillation column in which it is separated into a steam which is taken off at the top and comprises 1,3-butadiene, propyne, possibly further low boilers and possibly water and a bottom stream comprising 1,3-butadiene, 1,2-butadiene, acetylenes and possibly further high boilers, with the proportion of 1,3-butadiene in the bottom stream from the distillatin column being regulated in such a way that it is at least sufficiently high to dilute the acetylenes to outside the range in which there is a risk of spontaneous decomposition. The stream taken off from the top of the first distillation column is fed to a second distillation column and is separated into a steam which is taken off at the top and comprises propyne, possibly further low boilers and possibly water and a bottom stream comprising pure 1,3-butadiene in the second distillation column.

公开(公告)号：DE50210198D1

公开(公告)日：2007-07-05

申请号：DE50210198

申请日：2002-02-06

Applicant: BASF AG

Inventor： BOHNER GERD ,  KINDLER KLAUS ,  PAHL MELANIE ,  KAIBEL GERD

IPC: C07C11/167 ,  B01D3/40 ,  C07C7/08

Abstract: A process for recovering crude 1,3-butadiene from a C 4 fraction by extractive distillation using a selective solvent in a dividing wall column (TK) in which a dividing wall (T) is arranged in the longitudinal direction of the column to form a first subregion (A), a second subregion (B) and a lower common column region (C) and which is preceded by an extractive scrubbing column (K) is proposed.

公开(公告)号：CA2330137C

公开(公告)日：2006-12-19

申请号：CA2330137

申请日：1999-04-13

Applicant: BASF AG

Inventor： KINDLER KLAUS ,  PUHL HUBERT

IPC: C07C7/08 ,  C07C9/10 ,  C07C11/08 ,  C07C11/16

Abstract: The invention relates to a method for separating a C4 hydrocarbon mixture containing essentially 1,3 butadiene, butenes, butanes and other C4 hydrocarbons into at least 4 fractions as follows: a) fraction (a) consisting essentially of 1,3 butadiene; b) fraction (b) consisting essentially of butenes; c) fraction (c) consisting essentially of butanes; and d) one or more fractions (d) consisting essentially of 1,3 butadiene and the other C4 hydrocarbons. According to said method, the C 4 hydrocarbon mixture is separated by extractive distillation using N-methyl-2-pyrrolidinone or an aqueous solution of N-methyl-2- pyrrolidinone (NMP).

公开(公告)号：AU2003250141A1

公开(公告)日：2004-02-16

申请号：AU2003250141

申请日：2003-07-23

Applicant: BASF AG

Inventor： KINDLER KLAUS ,  HEIDA BERND ,  HILL THOMAS

IPC: C07C7/08 ,  C07C11/167

Abstract: Sudstituted the abstract with a new abstract as follows: The invention relates to a continuous process for separation a mixture of hydrocarbons which has beenobtained by extractive distillation of C 4 fraction useing a selective solvent and the hydrocarbons from the fraction C 4 which are more readily soluble in the selective solvent than are the butanes and the butenes. The mixture is fed into a first distillation column in which it is separated into a steam which is taken off at the top and comprises 1,3-butadiene, propyne, possibly further low boilers and possibly water and a bottom stream comprising 1,3-butadiene, 1,2-butadiene, acetylenes and possibly further high boilers, with the proportion of 1,3-butadiene in the bottom stream from the distillatin column being regulated in such a way that it is at least sufficiently high to dilute the acetylenes to outside the range in which there is a risk of spontaneous decomposition. The stream taken off from the top of the first distillation column is fed to a second distillation column and is separated into a steam which is taken off at the top and comprises propyne, possibly further low boilers and possibly water and a bottom stream comprising pure 1,3-butadiene in the second distillation column.

公开(公告)号：CA2493080A1

公开(公告)日：2004-02-05

申请号：CA2493080

申请日：2003-07-23

Applicant: BASF AG

Inventor： HILL THOMAS ,  KINDLER KLAUS ,  HEIDA BERND

IPC: C07C7/08 ,  C07C11/167

Abstract: The invention relates to a continuous method for the separation of a mixture of hydrocarbons, obtained by extractive distillation of a C4 fraction (C4) with a selective solvent (LM) and comprising the hydrocarbons from the C4 fraction (C4), which are more soluble in the selective solvent (LM) than butane or butene. The mixture is fed to a first distillation column (K I), i n which said mixture is separated into a top stream (K I-K), comprising 1,3- butadiene, propyne, optionally further low boilers and optionally water and a bottom stream (K I-S), comprising 1,3-butadiene, 1,2-butadiene, acetylene an d optionally further high boilers, whereby the proportion of 1,3-butadiene in the bottom stream (K I-S) of the distillation column (K I) is regulated such as to be at least high enough to dilute the acetylene from that region with a risk of spontaneous decomposition. The top stream (K I - K) from the first distillation column (K I) is fed to a second distillation column (K II) and separated in the second distillation column (K II) into a top stream (K II-K ), comprising propyne, optionally further low boilers and optionally water and a bottom stream (K II-S), comprising pure 1,3-butadiene.

公开(公告)号：AU2003233194A1

公开(公告)日：2003-11-17

申请号：AU2003233194

申请日：2003-04-29

Applicant: BASF AG

Inventor： ADRIAN TILL ,  HEIDA BERND ,  KINDLER KLAUS

IPC: B01D3/14 ,  B01D3/40 ,  C07C7/08 ,  C07C9/10 ,  C07C11/08

Abstract: A continuous process for isolating butenes from a C 4 fraction comprising butanes, butenes and other C 3 -C 5 -hydrocarbons by extractive distillation using a selective solvent (LM), comprising a first process stage I in a scrubbing zone (E) and a second process stage II in a degassing zone (A), wherein the liquid or a substream of the liquid is taken off from the degassing zone (A) at a theoretical plate located one or more theoretical plates below the feed point for the bottom stream (LM/C 4 H 8 ) from the scrubbing zone (E), heated and/or vaporized by indirect heat exchange with the hot bottom stream (LM) from the degassing zone (A) and returned to the degassing zone (A) at the same theoretical plate or above this, with the theoretical plate from which the liquid or substream of liquid is taken off being selected so that the total energy requirement in the process stages I and II is minimized, is proposed.

公开(公告)号：HU0302011A2

公开(公告)日：2003-09-29

申请号：HU0302011

申请日：2001-05-09

Applicant: BASF AG

Inventor： ADRIAN TILL ,  BOHNER GERD ,  HILL THOMAS ,  KAIBEL GERD ,  KINDLER KLAUS ,  MEYER GERALD ,  PAHL MELANIE ,  PICKENAECKER KARIN

IPC: C07C7/08 ,  B01D3/14 ,  B01D3/40 ,  C07C5/09 ,  C07C7/00 ,  C07C11/167 ,  C10G7/08 ,  C10G70/00 ,  C10G70/02

Abstract: In a process for the work-up of a C4 fraction, comprising the process steps Extractive distillation (I), Selective hydrogenation over a heterogeneous catalyst (II), a crude 1,3-butadiene stream being obtained following process steps (I) and (II) and Distillation of the crude 1,3-butadiene stream for isolating pure 1,3-butadiene (III), the process steps I and II are carried out in a single column or in thermally coupled columns and the process step III is carried out in a second column.

公开(公告)号：HU0102611A2

公开(公告)日：2003-04-28

申请号：HU0102611

申请日：1999-04-13

Applicant: BASF AG

Inventor： KINDLER KLAUS ,  PUHL HUBERT

IPC: C07C7/08 ,  C07C9/10 ,  C07C11/08 ,  C07C11/16

Abstract: A C4-hydrocarbon mixture essentially containing 1,3-butadiene, butenes, butanes and other C4-hydrocarbons is separated into at least 4 fractions,a) the fraction (a) essentially comprising 1,3-butadiene,b) the fraction (b) essentially comprising butenes,c) the fraction (c) essentially comprising butanes andd) one or more fractions (d) essentially comprising 1,3-butadiene and the other C4-hydrocarbons,by extractive distillation by means of N-methyl-2-pyrrolidinone or an aqueous solution of N-methyl-2-pyrrolidinone (NMP).

公开(公告)号：CZ20023681A3

公开(公告)日：2003-04-16

申请号：CZ20023681

申请日：2001-05-09

Applicant: BASF AG

Inventor： MEYER GERALD ,  KAIBEL GERD ,  BOHNER GERD ,  KINDLER KLAUS ,  ADRIAN TILL ,  PICKENACKER KARIN ,  PAHL MELANIE ,  HILL THOMAS

IPC: C07C7/08 ,  B01D3/14 ,  B01D3/40 ,  C07C5/09 ,  C07C7/00 ,  C07C11/167 ,  C10G7/08 ,  C10G70/00 ,  C10G70/02 ,  C07C7/163

Abstract: In a process for the work-up of a C4 fraction, comprising the process steps Extractive distillation (I), Selective hydrogenation over a heterogeneous catalyst (II), a crude 1,3-butadiene stream being obtained following process steps (I) and (II) and Distillation of the crude 1,3-butadiene stream for isolating pure 1,3-butadiene (III), the process steps I and II are carried out in a single column or in thermally coupled columns and the process step III is carried out in a second column.

公开(公告)号：AU2002244706B8

公开(公告)日：2002-08-19

申请号：AU2002244706

申请日：2002-02-06

Applicant: BASF AG

Inventor： PAHL MELANIE ,  KINDLER KLAUS ,  BOHNER GERD ,  KAIBEL GERD

IPC: C07C11/167 ,  B01D3/40 ,  C07C7/08

Abstract: A process for recovering crude 1,3-butadiene from a C 4 fraction by extractive distillation using a selective solvent in a dividing wall column (TK) in which a dividing wall (T) is arranged in the longitudinal direction of the column to form a first subregion (A), a second subregion (B) and a lower common column region (C) and which is preceded by an extractive scrubbing column (K) is proposed.