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公开(公告)号:DE2916356A1
公开(公告)日:1980-11-13
申请号:DE2916356
申请日:1979-04-23
Applicant: BASF AG
Inventor: STREIT WERNER DIPL CHEM DR , FIKENTSCHER ROLF DIPL CHEM DR , MELZER JAROSLAV DIPL ING , SCHARF EMIL DIPL CHEM DR , KOLHAUPT REINHOLD DIPL CHEM DR
Abstract: Polyetheramine are prepd. by condensing di- or polyamines (I) contg. 2-10 N atoms wich chlorohydrin ethers (II) prepd. from 1 mol divalent 2-5C alcohol, the ethoxylated adduct contg. up to 18 ethylene oxide units, glycerol or polyglycerol contg. up to 15 glycerol units and 2-8 mol epichlorohydrin at 110-200 degrees C in polar, water miscile solvents in the absence or extensive exclusion of water, adding an alkali(ne earth) metal base to neutralise >=20% of the HCl formed by the condensn. and post-condensing (I) is used in an amt. of 0.6-2.5 mol per mol. chlorohydrin gp. in (II). The aids are prepd. withou the necessity of having to graft components used during the condensn. with ethylene imine.