1.
    发明专利
    未知

    公开(公告)号:DE3201226A1

    公开(公告)日:1983-07-28

    申请号:DE3201226

    申请日:1982-01-16

    Applicant: BASF AG

    Abstract: An amino-containing and carboxyl-containing polymer tanning agent containing more carboxyl groups than amino groups, when used for retanning mineral-tanned leather, gives, alone or in combination with conventional anionic retanning agents, leather which is readily dyeable and has good sensory properties.

    3.
    发明专利
    未知

    公开(公告)号:DE3124172A1

    公开(公告)日:1982-12-30

    申请号:DE3124172

    申请日:1981-06-19

    Applicant: BASF AG

    Abstract: The present invention discloses substituted phenyl di and trisazo dyes free of reactive groups having two or three sulfonic acid groups, of the general formula: (I) wherein D1 is Z is hydrogen or D4-N=N-; D2 is phenyl substituted by hydroxyl, hydroxysulfonyl, chlorine or nitro, or is naphthyl substituted by hydroxy, hydroxysulfonyl or nitro, X, independently of one another, are hydroxyl or amino, D3 is phenyl which is substituted by hydroxysulfonyl, chlorine, bromine, methyl, methoxy, ethoxy, nitro, phenylamino, sulfophenylamino or nitrosulfophenylamino, or is naphthyl which is substituted by hydroxysulfonyl; D4 is phenyl which is unsubstituted or substituted by methyl, ethyl, methoxy, ethoxy, chlorine, bromine, nitro, sulfamoyl or hydroxysulfonyl, or is naphthyl which is substituted by hydroxysulfonyl; and R2 is methyl, ethyl or allyl; the rings B and E may additionally be substituted by methyl, ethyl, methoxy, ethoxy, chlorine, bromine or hydroxysulfonyl, with the proviso that D2 has a hydroxyl group ortho to the azo bond; or the iron, manganese, cobalt, chromium, nickel or copper complexes of this dye. These compounds, particularly in the form of their metal complexes are suitable for dyeing nitrogen-containing fibers such as wool, and preferably, leather. The present dyes yield very fast brown hues, in particular on retanned leather.

    5.
    发明专利
    未知

    公开(公告)号:DE2843233A1

    公开(公告)日:1980-04-10

    申请号:DE2843233

    申请日:1978-10-04

    Applicant: BASF AG

    Abstract: Mineral tanned leather is frequently retanned with synthetic tanning agents to improve the fullness and softness, but leather retanned by the prior art methods is difficult to dye in full shades with anionic dyes. According to the invention, condensation products of C1-4 aldehydes with certain aromatic sulfonic acids or carboxylic acids containing amino groups are employed for retanning, thereby improving the receptivity of the leather for anionic dyes. These acids have the general formula where X and X' are independently H, -CH2-SO3H or -CH2-OH, A is a benzene radical, Y and Z are independently H, -SO3H or -CO2H, R is H or C1-4-alkyl and n is from 0 to 10, with the proviso that at least one sulfonic acid or carboxyl group is present in the molecule.

    7.
    发明专利
    未知

    公开(公告)号:DE3115646A1

    公开(公告)日:1982-11-18

    申请号:DE3115646

    申请日:1981-04-18

    Applicant: BASF AG

    Abstract: Water-soluble or self-dispersing resin tanning agents are prepared by heating from 5 to 30% by weight of melamine, from 15 to 45% by weight of urea, from 20 to 35% by weight (calculated as anhydrous material) of formaldehyde and from 15 to 55% by weight of sodium bisulfite or of a corresponding amount of some other salt of sulfurous acid for from two to twelve hours in aqueous solution at 40 DEG -120 DEG C. and a pH of from 5 to 9.

    10.
    发明专利
    未知

    公开(公告)号:DE2524747A1

    公开(公告)日:1976-12-16

    申请号:DE2524747

    申请日:1975-06-04

    Applicant: BASF AG

    Abstract: A process for the isolation of mixtures of 1,5-dinitroanthraquinone and 1,8-dinitroanthraquinone which have a high content of alpha , alpha '-dinitroanthraquinones by heating a suspension of the crude dinitroanthraquinone mixture in certain organic liquids at from 60 DEG to 200 DEG C until solution equilibrium has been set up, and separating the undissolved material from the solution. The undissolved material contains more than 90% and as a rule more than 95% by weight of 1,5-dinitroanthraquinone and 1,8-dinitroanthraquinone. The pure mixture of 1,5-dinitroanthraquinone and 1,8-dinitroanthraquinone may be used for the manufacture of dyes.

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