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公开(公告)号:DE102004011346A1
公开(公告)日:2005-09-22
申请号:DE102004011346
申请日:2004-03-05
Applicant: BASF AG
Inventor: MALOTKI PETER VON , HENSIEK RAINER , LEHMANN PIT
Abstract: Production of isocyanate-based rigid foam by reacting polyisocyanates with compounds having at least 2 isocyanate-reactive hydrogen atoms, at least one of which is a polyester alcohol, comprises (A) reacting a polyester alcohol or a polyol mixture containing polyester alcohol(s) with less than the stoichiometric amount of at least difunctional isocyanate(s) to a prepolymer (I) containing urethane and hydroxyl groups, (B) reacting (I) with polyisocyanate. Independent claims are also included for the following: (1) (I) with a hydroxyl (OH) number in the 100-400 mg KOH/g range; (2) rigid isocyanate-based foams produced by this process.
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公开(公告)号:ES2282764T3
公开(公告)日:2007-10-16
申请号:ES04016059
申请日:2004-07-08
Applicant: BASF AG
Inventor: FABISIAK ROLAND , VON MALOTKI PETER DR , HENSIEK RAINER , LEHMANN PIT
Abstract: Espuma dura de poliuretano con una altura de llama según EN-ISO 11925-2 menor que 15 cm, que puede obtenerse mediante reacción de a) poliisocianatos con b) compuestos con átomos de hidrógeno reactivos frente a los grupos isocianato, que contienen, al menos, un poliéterpoliol iniciado con amina, c) agentes propulsores, que contienen hidrocarburos, d) estabilizantes de la espuma exentos de silicona y e) agentes protectores contra la llama en una cantidad desde un 12 hasta un 35 % en peso, referido al peso total de los componentes b) hasta e).
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公开(公告)号:DE10337787A1
公开(公告)日:2005-03-24
申请号:DE10337787
申请日:2003-08-14
Applicant: BASF AG
Inventor: FABISIAK ROLAND , MALOTKI VON PETER , HENSIEK RAINER , LEHMANN PIT
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公开(公告)号:AT356848T
公开(公告)日:2007-04-15
申请号:AT04016059
申请日:2004-07-08
Applicant: BASF AG
Inventor: FABISIAK ROLAND , VON MALOTKI PETER DR , HENSIEK RAINER , LEHMANN PIT
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公开(公告)号:DE102005041763A1
公开(公告)日:2007-03-08
申请号:DE102005041763
申请日:2005-09-01
Applicant: BASF AG
Inventor: LEHMANN PIT , MALOTKI PETER VON , TOMASI GIANPAOLO , PEDEN GILLIAN , HENSIEK RAINER
Abstract: The invention relates to a catalyst system, in particular for rigid polyisocyanurate foams blown by means of formic acid, a process for producing them and the rigid polyisocyanurate foams which can be obtained by such a process.
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公开(公告)号:DE102005017363A1
公开(公告)日:2006-10-19
申请号:DE102005017363
申请日:2005-04-14
Applicant: BASF AG
Inventor: LEHMANN PIT , MALOTKI PETER VON , HENSIEK RAINER , SCHOEN LARS
Abstract: The invention relates to a process for producing rigid polyurethane and polyisocyanurate foams by reacting polyisocyanates a) with compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b) in the presence of blowing agents c), wherein prepolymers which comprise isocyanate groups and have an NCO content in the range from 25 to 31% by weight, based on the weight of the prepolymer, and are prepared by reacting ai) mixtures of monomeric and polymeric diphenylmethane diisocyanate with at least one compound having more than one hydrogen atom which is reactive toward isocyanate groups aii) are used as polyisocyanates a) and the compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b) comprise at least one polyester alcohol bi) which comprises at least one starting component which is hydrophobic.
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公开(公告)号:DE102004050937A1
公开(公告)日:2006-04-20
申请号:DE102004050937
申请日:2004-10-18
Applicant: BASF AG
Inventor: FRERICKS ANSGAR , BINDER HORST , LEHMANN PIT , KAMPF GUNNAR , TEMPLIN MARKUS , FRENZEL ROBERT
Abstract: Preparation of polyurethane rigid foam material (I) comprises reaction of (a) polyisocyanate with (b) compounds with at least two reactive hydrogen atoms with isocyanate group in presence of propellants, where (b) contains an acrylate polyol (5-90 wt.%) (b1), prepared by radical polymerization of hydroxyl-functional (meth)acrylate or its mixtures with e.g. non hydroxyl-functional (meth)acrylate. Preparation of polyurethane rigid foam material (I) comprises reaction of (a) polyisocyanate with (b) compounds with at least two reactive hydrogen atoms with isocyanate group in presence of propellants, where (b) contains an acrylate polyol (5-90 wt.%) (b1), prepared by radical polymerization of hydroxyl-functional (meth)acrylate or its mixtures with non hydroxyl-functional (meth)acrylate and/or aliphatic or aromatic ethylenic unsaturated monomers, where the monomer used for the production of the acrylate polyol does not contain aminic nitrogen. Independent claims are also included for: (1) (I), prepared by the preparation method; and (2) use of acrylate polyol to the improvement of the flame stability of (I).
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公开(公告)号:CA2674738A1
公开(公告)日:2008-07-17
申请号:CA2674738
申请日:2008-01-02
Applicant: BASF AG
Inventor: THANE KATRIN , LEHMANN PIT , HWANG CHEOL-HYUN
Abstract: The present invention relates to a rigid polyurethane foam comprising rei nforcing materials and obtainable by mixing (a) isocyanates which have a vis cosity at 25°C of less than 500 mPas with (b) compounds having groups which are reactive toward isocyanates, (c) blowing agents comprising water, (d) ca talysts and, if appropriate, (e) further additives to form a reaction mixtur e and applying the reaction mixture to a reinforcing material, where the com pounds (b) having groups which are reactive toward isocyanates comprise a po lyetherol (b1) having a functionality of 4 or more and a viscosity at 25°C o f 10 000 mPas or less and a polyetherol (b2) having a functionality of 3 or less and a viscosity at 25°C of 500 mPas or less. The present invention furt her relates to a process for producing such rigid polyurethane foams and to the use of the rigid polyurethane foams for the insulation of liquefied natu ral gas tanks.
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公开(公告)号:DE502004003194D1
公开(公告)日:2007-04-26
申请号:DE502004003194
申请日:2004-07-08
Applicant: BASF AG
Inventor: FABISIAK ROLAND , VON MALOTKI PETER DR , HENSIEK RAINER , LEHMANN PIT
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10.
公开(公告)号:MX2007002117A
公开(公告)日:2007-04-27
申请号:MX2007002117
申请日:2005-09-10
Applicant: BASF AG
Inventor: MALOTKI PETER VON , CALGUA ERWIN , SCHAPER BERND , SCHON LARS , LEHMANN PIT , THATER MICHAEL
Abstract: La invencion se relaciona con un proceso para la produccion de elementos compuestos, compuestos de cuando menos una capa externa a) y de una espuma rigida basada en isocianato b), en donde entre la capa externa a) y la espuma rigida basada en isocianato b) un promotor de adhesion c) se ha aplicado, y en donde la capa externa a) se mueve continuamente y el promotor de adhesion c) y el material de partida para la espuma rigida a base de isocianato b) se aplican sucesivamente a la capa externa, que comprende aplicar el promotor de adhesion c) por medio de una placa giratoria que se ha instalado horizontalmente o con una desviacion de hasta 15 degree a partir de la horizontal, de preferencia paralela a la capa externa.
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