Abstract:
The invention relates to a method for producing aqueous copolymer dispersions of copolymers consisting of carbon monoxide and olefinically unsaturated compounds, by means of copolymerisation of carbon monoxide and olefinically unsaturated compounds in an aqueous medium in the presence of metallic complexes.
Abstract:
The invention relates to a method of producing aqueous copolymer dispersions from copolymers that comprise carbon monoxide and at least one olefinically unsaturated compound.
Abstract:
Water-soluble transition metal complexes of the formula (I)where R to R are linear or branched C2- to C28-alkyl, C3- to C14-cycloalkyl or alkylaryl where the alkyl moiety is of 1 to 28 carbon atoms and the aryl moiety is of 6 to 15 carbon atoms, each of which is substituted by at least one polar protic or ionic functional group based on nonmetallic elements of groups IVA to VIA of the Periodic Table of Elements.
Abstract:
The invention relates to water-soluble transition metal complexes of the general formula (I), in which the rests R to R are linear or branched C2-C28 alkyl substituted by at least one polar functional group which is ionic or has a protonic action and based on elements of groups IVA to VIA of the periodic table, C3-C14 cycloalkyl or alkyl aryl with between 1 and 28 C-atoms in the alkyl part and between 6 and 15 C-atoms in the aryl part.
Abstract:
A process is described for preparing polyoxymethylene by contacting a formaldehyde source with a catalyst of the formula I [ML 1 a L 2 b ] c m+ Z c.m/n n- (I) where M is a metal of group VIII; L 1 is a ligand having at least one pi-electron pair; each L 2 is independently tetrahydrofuran or a ligand which is displaceable by tetrahydrofuran; Z is an anion; a is 1 or 2; b is an integer from 0 to 4; c is 1 or 2; and m and n are integers from 1 to 4.
Abstract:
Water-soluble transition metal complexes of the formula (I)where R to R are linear or branched C2- to C28-alkyl, C3- to C14-cycloalkyl or alkylaryl where the alkyl moiety is of 1 to 28 carbon atoms and the aryl moiety is of 6 to 15 carbon atoms, each of which is substituted by at least one polar protic or ionic functional group based on nonmetallic elements of groups IVA to VIA of the Periodic Table of Elements.
Abstract:
The invention relates to a method of producing aqueous copolymer dispersions from copolymers that comprise carbon monoxide and at least one olefinically unsaturated compound.
Abstract:
A process is described for preparing polyoxymethylene by contacting a formaldehyde source with a catalyst of the formula I [ML 1 a L 2 b ] c m+ Z c.m/n n- (I) where M is a metal of group VIII; L 1 is a ligand having at least one pi-electron pair; each L 2 is independently tetrahydrofuran or a ligand which is displaceable by tetrahydrofuran; Z is an anion; a is 1 or 2; b is an integer from 0 to 4; c is 1 or 2; and m and n are integers from 1 to 4.
Abstract:
Sistemas catalizadores para la copolimerización de monóxido de carbono y compuestos con insaturación - olefínica, que contienen como componentes esenciales a) complejo metálico de la **fórmula** en la que los substituyentes e índices tienen el siguiente significado: G -(CRb2)r-, o -(CRb2)s-Si(Ra)2-(CRb)t-, -A¿-O-B¿- o ¿A¿-Z(R5)-B¿-, con R5 alquilo con 1 a 28 átomos de carbono no substituidos, o substituidos con grupos funcionales a base de elementos de los grupos IVA, VA, VIA o VIIA, cicloalquilo con 3 a 14 átomos de carbono, arilo con 6 a 15 átomos de carbono o alquilarilo con 1 a 20 átomos de carbono en el resto alquilo y 6 a 15 átomos de carbono en el resto arilo, -N(Rb)2, - Si(Rc)3 o un resto de la **fórmula** en la que q significa un número entero de 0 a 20, y los demás substituyentes que tienen el mismo significado que en A¿, B¿ -(CRb2)r, o -(CRb2)s-Si(Ra)2-(CRb2)t-, -N(Rb)-, un componente r¿-, s- o t-atómico de un sistema de anillo, o junto con Z un componente (r¿+1)-, (s+1)- o (t+1)-atómico de un heterociclo, Ra, independientemente entre sí, alquilo con 1 a 20 átomos de carbono, cicloalquilo con 3 a 10 átomos de carbono, arilo con 6 a 15 átomos de carbono o alquilarilo con 1 a 10 átomos de carbono en la parte alquilo y 6 a 15 átomos de carbono en la parte arilo, Rb como Ra o hidrógeno, o Si(Rc)3, Rc alquilo con 1 a 20 átomos de carbono, cicloalquilo con 3 a 10 átomos de carbono, arilo con 6 a 15 átomos de carbono, o alquilarilo con 1 a 10 átomos de carbono en la parte alquilo y 6 a 15 átomos de carbono en la parte arilo.