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公开(公告)号:ES2156359T3
公开(公告)日:2001-06-16
申请号:ES97903321
申请日:1997-02-19
Applicant: BASF AG
Inventor: LYNCH JOHN , FISCHER DAVID , GORTZ HANS-HELMUT , SCHWEIER GUNTHER
IPC: C08F2/14 , C08F2/18 , C08F4/02 , C08F4/60 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F110/02
Abstract: Polymers of alkenes are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are supported catalyst systems obtainable by A) reaction of an inorganic carrier with a metal compound of the general formula I M1(R1)r(R2)s(R3)t(R4)u I where M1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table, R1 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R2 to R4 are each hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, alkoxy or dialkylamino, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, r is an integer from 1 to 4 and s, t and u are integers from 0 to 3, the sum r+s+t+u corresponding to the valency of M1, B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions and C) subsequent reaction with a metal compound of the general formula II M2(R5)o(R6)p(R7)q IIin which M2 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table, R5 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R6 and R7 are each hydrogen, halogen, C1-C
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公开(公告)号:AT200784T
公开(公告)日:2001-05-15
申请号:AT97903321
申请日:1997-02-19
Applicant: BASF AG
Inventor: LYNCH JOHN , FISCHER DAVID , GOERTZ HANS-HELMUT , SCHWEIER GUENTHER
IPC: C08F2/14 , C08F2/18 , C08F4/02 , C08F4/60 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F110/02
Abstract: Polymers of alkenes are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are supported catalyst systems obtainable by A) reaction of an inorganic carrier with a metal compound of the general formula I M1(R1)r(R2)s(R3)t(R4)u I where M1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table, R1 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R2 to R4 are each hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, alkoxy or dialkylamino, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, r is an integer from 1 to 4 and s, t and u are integers from 0 to 3, the sum r+s+t+u corresponding to the valency of M1, B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions and C) subsequent reaction with a metal compound of the general formula II M2(R5)o(R6)p(R7)q IIin which M2 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table, R5 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R6 and R7 are each hydrogen, halogen, C1-C
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公开(公告)号:AU732527B2
公开(公告)日:2001-04-26
申请号:AU1874697
申请日:1997-02-19
Applicant: BASF AG
Inventor: LYNCH JOHN , FISCHER DAVID , GORTZ HANS-HELMUT , SCHWEIER GUNTHER
IPC: C08F2/34 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/68 , C08F10/00 , C08F110/02
Abstract: Polymerizable alkanes are prepared by gas-phase polymerization in the presence of catalyst systems by a process in which the catalyst systems used are supported castalyst systems.
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公开(公告)号:DE59700519D1
公开(公告)日:1999-11-11
申请号:DE59700519
申请日:1997-07-15
Applicant: BASF AG
Inventor: LYNCH JOHN , PERNER THOMAS , HAHN SUSANNE , LUEDDECKE ERIK
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公开(公告)号:AU5481398A
公开(公告)日:1998-06-22
申请号:AU5481398
申请日:1997-11-11
Applicant: BASF AG
Inventor: LYNCH JOHN , SUTORIS HEINZ FRIEDRICH , ZUBILLER JURGEN , AUMULLER ALEXANDER
Abstract: Vinyl monomers are polymerized in the aqueous phase in the presence of at least one N-oxyl compound of a secondary amine, having no hydrogen atoms bonded to the alpha carbon atoms. This process substantially eliminates deposits on reactor surfaces.
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公开(公告)号:DK172228B1
公开(公告)日:1998-01-12
申请号:DK436582
申请日:1982-10-01
Applicant: BASF AG
Inventor: LECHTKEN PETER , BUETHE INGOLF , BRONSTERT BERND , HESSE ANTON , HOFFMANN GERHARD , JACOBI MANFRED , LYNCH JOHN , TRIMBORN WERNER , VYVIAL RUDOLF
IPC: B41N20060101 , C08F20060101 , C08F2/50 , C08K20060101 , C08K5/53 , C09D20060101 , G03C20060101 , G03F7/028
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公开(公告)号:AU1792197A
公开(公告)日:1997-09-10
申请号:AU1792197
申请日:1997-02-19
Applicant: BASF AG
Inventor: LYNCH JOHN , FISCHER DAVID , GORTZ HANS-HELMUT , SCHWEIER GUNTHER
IPC: C08F2/14 , C08F2/18 , C08F4/02 , C08F4/60 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F110/02
Abstract: Polymers of alkenes are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are supported catalyst systems obtainable by A) reaction of an inorganic carrier with a metal compound of the general formula I M1(R1)r(R2)s(R3)t(R4)u I where M1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table, R1 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R2 to R4 are each hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, alkoxy or dialkylamino, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, r is an integer from 1 to 4 and s, t and u are integers from 0 to 3, the sum r+s+t+u corresponding to the valency of M1, B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions and C) subsequent reaction with a metal compound of the general formula II M2(R5)o(R6)p(R7)q IIin which M2 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table, R5 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R6 and R7 are each hydrogen, halogen, C1-C
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公开(公告)号:AU1791997A
公开(公告)日:1997-09-10
申请号:AU1791997
申请日:1997-02-19
Applicant: BASF AG
Inventor: LYNCH JOHN , FISCHER DAVID , GORTZ HANS-HELMUT , SCHWEIER GUNTHER
IPC: C08F4/12 , C08F4/44 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/68 , C08F10/00 , C08F110/02
Abstract: Supported catalyst systems are obtainable byA) reaction of an inorganic carrier with a metal compound of the general formula I whereM1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table,R1 is hydrogen, Ch1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,R2 to R4 are each hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, alkoxy or dialkylamino each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,r is an integer from 1 to 4 ands, t and u are integers from 0 to 3 the sum r+s+t+u corresponding to the valency of M1,B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions andC) subsequent reaction with a metal compound of the general formula II whereM2 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table,R5 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,R6 and R7 are hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl or alkoxy each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,o is an integer from 1 to 3 andp and q are integers from 0 to 2 the sum o+p+q corresponding to the valency of M2.
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公开(公告)号:CA2246389A1
公开(公告)日:1997-08-28
申请号:CA2246389
申请日:1997-02-19
Applicant: BASF AG
Inventor: LYNCH JOHN , G RTZ HANS-HELMUT , SCHWEIER GUENTHER , FISCHER DAVID
IPC: C08F2/14 , C08F2/18 , C08F4/02 , C08F4/60 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F110/02 , C08F4/62
Abstract: A process for producing polymers of alkenes by suspension polymerisation in the presence of catalyst systems where use is made of supported catalyst systems obtainable by A) reacting an inorganic support material with a metal compound of the general formula (I): M1(R1)r(R2)s(R3)t(R4)u, in which M1 is an alkaline or alkaline earth metal or a metal from main group III or IV of the periodic system; R1 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R2 to R4 are hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl, alkoxy or dialkylamino with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; r is a whole number from 1 to 4; and s, t and u are whole numbers from 0 to 3, where the sum r+s+t+u corresponds to the valency of M1; B) reacting the material obtained from A) with a metallocene complex in its metal dihalogenide form and a metallocenium ionforming compound; and C) subsequent reaction with a metal compound of the general formula (II): M2(R5)o(R6)p(R7)q, in which M2 is an alkaline or alkaline earth metal or a metal of main group III of the periodic system; R5 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R6 and R7 are hydrogen, halogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl, aryl alkyl, or alkoxy with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, o is a whole number from 1 to 3; and p and q are whole numbers from 0 to 2 where the sum o+p+q corresponds to the valency of M2.
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公开(公告)号:CA2246307A1
公开(公告)日:1997-08-27
申请号:CA2246307
申请日:1997-02-19
Applicant: BASF AG
Inventor: G RTZ HANS-HELMUT , LYNCH JOHN , SCHWEIER GUENTHER , FISCHER DAVID
IPC: C08F2/34 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/68 , C08F10/00 , C08F110/02 , C08F4/02 , C08F4/62
Abstract: A process for producing polymers of alkenes by gas phase polymerisation in the presence of catalyst systems where use is made of supported catalyst systems obtainable by A) reacting an inorganic support material with a metal compound of the general formula (I) M1(R1)r(R2)s(R3)t(R4)u in which M1 is an alkaline or alkaline earth metal or a metal from main group III or IV of the periodic system, R1 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, R2 to R4 are hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl, alkoxy or dialkylamino with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, r is a whole number from 1 to 4 and s, t, and u are whole numbers from 0 to 3, where the sum r+s+t+u corresponds to the valency of M1, B) reacting the material obtained from A) with a metallocene complex in its metal dihalogenide from and a metallocenium ion-forming compound and C) subsequent reaction with a metal compound of the general formula (II) M2(R5)o(R6)p(R7)q in which M2 is a metal of main group III of the periodic system, R5 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, R6 and R7 are hydrogen, halogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl, aryl alkyl or alkoxy with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, o is a whole number from 1 to 3 and p and q are whole numbers from 0 to 2 where the sum o+p+q corresponds to the valency of M2.
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