1.
    发明专利
    未知

    公开(公告)号:ES2156359T3

    公开(公告)日:2001-06-16

    申请号:ES97903321

    申请日:1997-02-19

    Applicant: BASF AG

    Abstract: Polymers of alkenes are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are supported catalyst systems obtainable by A) reaction of an inorganic carrier with a metal compound of the general formula I M1(R1)r(R2)s(R3)t(R4)u I where M1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table, R1 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R2 to R4 are each hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, alkoxy or dialkylamino, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, r is an integer from 1 to 4 and s, t and u are integers from 0 to 3, the sum r+s+t+u corresponding to the valency of M1, B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions and C) subsequent reaction with a metal compound of the general formula II M2(R5)o(R6)p(R7)q IIin which M2 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table, R5 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R6 and R7 are each hydrogen, halogen, C1-C

    2.
    发明专利
    未知

    公开(公告)号:AT200784T

    公开(公告)日:2001-05-15

    申请号:AT97903321

    申请日:1997-02-19

    Applicant: BASF AG

    Abstract: Polymers of alkenes are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are supported catalyst systems obtainable by A) reaction of an inorganic carrier with a metal compound of the general formula I M1(R1)r(R2)s(R3)t(R4)u I where M1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table, R1 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R2 to R4 are each hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, alkoxy or dialkylamino, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, r is an integer from 1 to 4 and s, t and u are integers from 0 to 3, the sum r+s+t+u corresponding to the valency of M1, B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions and C) subsequent reaction with a metal compound of the general formula II M2(R5)o(R6)p(R7)q IIin which M2 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table, R5 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R6 and R7 are each hydrogen, halogen, C1-C

    Process for producing polymers of alkenes by suspension polymerisation

    公开(公告)号:AU1792197A

    公开(公告)日:1997-09-10

    申请号:AU1792197

    申请日:1997-02-19

    Applicant: BASF AG

    Abstract: Polymers of alkenes are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are supported catalyst systems obtainable by A) reaction of an inorganic carrier with a metal compound of the general formula I M1(R1)r(R2)s(R3)t(R4)u I where M1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table, R1 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R2 to R4 are each hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, alkoxy or dialkylamino, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, r is an integer from 1 to 4 and s, t and u are integers from 0 to 3, the sum r+s+t+u corresponding to the valency of M1, B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions and C) subsequent reaction with a metal compound of the general formula II M2(R5)o(R6)p(R7)q IIin which M2 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table, R5 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R6 and R7 are each hydrogen, halogen, C1-C

    Supported catalyst system
    8.
    发明专利

    公开(公告)号:AU1791997A

    公开(公告)日:1997-09-10

    申请号:AU1791997

    申请日:1997-02-19

    Applicant: BASF AG

    Abstract: Supported catalyst systems are obtainable byA) reaction of an inorganic carrier with a metal compound of the general formula I whereM1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table,R1 is hydrogen, Ch1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,R2 to R4 are each hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, alkoxy or dialkylamino each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,r is an integer from 1 to 4 ands, t and u are integers from 0 to 3 the sum r+s+t+u corresponding to the valency of M1,B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions andC) subsequent reaction with a metal compound of the general formula II whereM2 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table,R5 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,R6 and R7 are hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl or alkoxy each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,o is an integer from 1 to 3 andp and q are integers from 0 to 2 the sum o+p+q corresponding to the valency of M2.

    PROCESS FOR PRODUCING POLYMERS OF ALKENES BY SUSPENSION POLYMERISATION

    公开(公告)号:CA2246389A1

    公开(公告)日:1997-08-28

    申请号:CA2246389

    申请日:1997-02-19

    Applicant: BASF AG

    Abstract: A process for producing polymers of alkenes by suspension polymerisation in the presence of catalyst systems where use is made of supported catalyst systems obtainable by A) reacting an inorganic support material with a metal compound of the general formula (I): M1(R1)r(R2)s(R3)t(R4)u, in which M1 is an alkaline or alkaline earth metal or a metal from main group III or IV of the periodic system; R1 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R2 to R4 are hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl, alkoxy or dialkylamino with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; r is a whole number from 1 to 4; and s, t and u are whole numbers from 0 to 3, where the sum r+s+t+u corresponds to the valency of M1; B) reacting the material obtained from A) with a metallocene complex in its metal dihalogenide form and a metallocenium ionforming compound; and C) subsequent reaction with a metal compound of the general formula (II): M2(R5)o(R6)p(R7)q, in which M2 is an alkaline or alkaline earth metal or a metal of main group III of the periodic system; R5 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R6 and R7 are hydrogen, halogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl, aryl alkyl, or alkoxy with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, o is a whole number from 1 to 3; and p and q are whole numbers from 0 to 2 where the sum o+p+q corresponds to the valency of M2.

    PROCESS FOR PRODUCING ALKENE POLYMERS BY GAS PHASE POLYMERISATION

    公开(公告)号:CA2246307A1

    公开(公告)日:1997-08-27

    申请号:CA2246307

    申请日:1997-02-19

    Applicant: BASF AG

    Abstract: A process for producing polymers of alkenes by gas phase polymerisation in the presence of catalyst systems where use is made of supported catalyst systems obtainable by A) reacting an inorganic support material with a metal compound of the general formula (I) M1(R1)r(R2)s(R3)t(R4)u in which M1 is an alkaline or alkaline earth metal or a metal from main group III or IV of the periodic system, R1 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, R2 to R4 are hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl, alkoxy or dialkylamino with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, r is a whole number from 1 to 4 and s, t, and u are whole numbers from 0 to 3, where the sum r+s+t+u corresponds to the valency of M1, B) reacting the material obtained from A) with a metallocene complex in its metal dihalogenide from and a metallocenium ion-forming compound and C) subsequent reaction with a metal compound of the general formula (II) M2(R5)o(R6)p(R7)q in which M2 is a metal of main group III of the periodic system, R5 is hydrogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl or aryl alkyl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, R6 and R7 are hydrogen, halogen, C1-C10 alkyl, C6-C15 aryl, alkyl aryl, aryl alkyl or alkoxy with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, o is a whole number from 1 to 3 and p and q are whole numbers from 0 to 2 where the sum o+p+q corresponds to the valency of M2.

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