公开(公告)号：DE50000542D1

公开(公告)日：2002-10-31

申请号：DE50000542

申请日：2000-02-25

Applicant: BASF AG

Inventor： MACKEWITZ THOMAS DR ,  ROEPER DR ,  BREIT PROF DR BERNHARD

IPC: C07F9/6568

Abstract: Preparation of phosphabenzene compounds (A) by reacting the corresponding pyrilium salt (III) with phosphine, optionally in presence of solvent but without addition of acid catalyst or base. (III) and phosphine are contacted at about 0 degrees C then reacted at 0-200 degrees C at pressure over 1 bar. (A) have formulae (I) or (II); R -R = hydrogen, COOM, SO3M, NR3X, NR2, OR, COOR, SR, 1-12C alkyl, 6-12C aryl, 7-12C aralkyl or alkaryl, or 3-6C heterocyclylalkyl with 1-3 heteroatoms, optionally substituted by the above groups, or two or more R groups together form a fused aliphatic ring; M = hydrogen, ammonium or alkali metal; X = anion; R = hydrogen or 1-6C alkyl; W = bridge comprising covalent bond, oxygen, sulfur, amino, di(1-6C)alkylsilyl or 1-16C residue that includes one or more linked cyclic or aromatic nuclei and optionally interrupted by 1-3 heteroatoms, and each o- or m-position on the phosphabenzene ring that is not bound to the bridge may be substituted by R -R .

公开(公告)号：ES2182742T3

公开(公告)日：2003-03-16

申请号：ES00103428

申请日：2000-02-25

Applicant: BASF AG

Inventor： MACKEWITZ THOMAS DR ,  ROEPER MICHAEL DR ,  BREIT PROF DR BERNHARD

IPC: C07F9/6568

Abstract: Preparation of phosphabenzene compounds (A) by reacting the corresponding pyrilium salt (III) with phosphine, optionally in presence of solvent but without addition of acid catalyst or base. (III) and phosphine are contacted at about 0 degrees C then reacted at 0-200 degrees C at pressure over 1 bar. (A) have formulae (I) or (II); R -R = hydrogen, COOM, SO3M, NR3X, NR2, OR, COOR, SR, 1-12C alkyl, 6-12C aryl, 7-12C aralkyl or alkaryl, or 3-6C heterocyclylalkyl with 1-3 heteroatoms, optionally substituted by the above groups, or two or more R groups together form a fused aliphatic ring; M = hydrogen, ammonium or alkali metal; X = anion; R = hydrogen or 1-6C alkyl; W = bridge comprising covalent bond, oxygen, sulfur, amino, di(1-6C)alkylsilyl or 1-16C residue that includes one or more linked cyclic or aromatic nuclei and optionally interrupted by 1-3 heteroatoms, and each o- or m-position on the phosphabenzene ring that is not bound to the bridge may be substituted by R -R .

公开(公告)号：AT224903T

公开(公告)日：2002-10-15

申请号：AT00103428

申请日：2000-02-25

Applicant: BASF AG

Inventor： MACKEWITZ THOMAS DR ,  ROEPER MICHAEL DR ,  BREIT PROF DR BERNHARD

IPC: C07F9/6568

Abstract: Preparation of phosphabenzene compounds (A) by reacting the corresponding pyrilium salt (III) with phosphine, optionally in presence of solvent but without addition of acid catalyst or base. (III) and phosphine are contacted at about 0 degrees C then reacted at 0-200 degrees C at pressure over 1 bar. (A) have formulae (I) or (II); R -R = hydrogen, COOM, SO3M, NR3X, NR2, OR, COOR, SR, 1-12C alkyl, 6-12C aryl, 7-12C aralkyl or alkaryl, or 3-6C heterocyclylalkyl with 1-3 heteroatoms, optionally substituted by the above groups, or two or more R groups together form a fused aliphatic ring; M = hydrogen, ammonium or alkali metal; X = anion; R = hydrogen or 1-6C alkyl; W = bridge comprising covalent bond, oxygen, sulfur, amino, di(1-6C)alkylsilyl or 1-16C residue that includes one or more linked cyclic or aromatic nuclei and optionally interrupted by 1-3 heteroatoms, and each o- or m-position on the phosphabenzene ring that is not bound to the bridge may be substituted by R -R .

公开(公告)号：MY140689A

公开(公告)日：2010-01-15

申请号：MYPI20044320

申请日：2004-10-20

Applicant: BASF AG

Inventor： VOLLAND MARTIN DR ,  MACKEWITZ THOMAS DR ,  AHLERS WOLFGANG DR ,  SCHAEFER ANSGAR DR ,  RICHTER WOLFGANG DR ,  PACIELLO ROCCO DR

IPC: C07C45/50 ,  B01J31/18 ,  B01J31/24

Abstract: PROCESS FOR THE CONTINUOUS PREPARATION OF ALDEHYDES HAVING FROM 5 TO 21 CARBON ATOMS BY ISOMERIZING HYDROFORMYLATION IN THE HOMOGENEOUS PHASE OF OLEFIN COMPOSITIONS HAVING FROM 4 TO 20 CARBON ATOMS AND COMPRISING (ALPHA)-OLEFINS AND OLEFINS HAVING INTERNAL DOUBLE BONDS BY MEANS OF SYNTHESIS GAS IN THE PRESENCE OF A HOMOGENEOUS RHODIUM CATALYST COMPLEXED WITH AN OXYGEN- AND/OR NITROGEN-CONTAINING ORGANOPHOSPHORUS LIGAND AND FREE LIGAND AT ELEVATED TEMPERATURE AND ELEVATED PRESSURE IN A MULTISTAGE REACTION SYSTEM COMPRISING AT LEAST TWO REACTION ZONES, IN WHICH THE OLEFIN COMPOSITION IS FIRSTLY REACTED WITH SYNTHESIS GAS HAVING A CO/H2 MOLAR RATIO OF FROM 4:1 TO 1:2 AT A TOTAL PRESSURE OF FROM 10 TO 40 BAR IN A GROUP OF ONE OR MORE FIRST REACTION ZONES TO A CONVERSION OF THE (ALPHA)-OLEFINS OF FROM 40 TO 95AND THE HYDROFORMYLATION MIXTURE FROM THIS GROUP OF ONE OR MORE FIRST REACTION ZONES IS REACTED WITH SYNTHESIS GAS HAVING A CO/H2 MOLAR RATIO OF FROM 1:4 TO 1:1000 AT A TOTAL PRESSURE OF FROM 5 TO 30 BAR IN A GROUP ONE OR MORE DOWNSTREAM REACTION ZONES, WHERE THE TOTAL PRESSURE IN THE ONE OR MORE DOWNSTREAM REACTION ZONES IS IN EACH CASE FROM 1 TO (T1-Tf) BAR LOWER THAN IN THE PRECEDING REACTION ZONE, WHERE T1 IS THE TOTAL PRESSURE IN THE PRECEDING REACTION ZONE AND Tf IS THE TOTAL PRESSURE IN THE REACTION ZONE DOWNSTREAM OF THE ONE OR MORE FIRST REACTION ZONES, WITH THE PROVISO THAT THE DIFFERENCE T1-Tf IS GREATER THAN 1 BAR, AND THE CO PARTIAL PRESSURE IN THE ONE OR MORE DOWNSTREAM REACTION ZONES IS IN EACH CASE LOWER THAN IN THE REACTION ZONE PRECEDING THIS REACTION ZONE.