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公开(公告)号:WO2006077204A3
公开(公告)日:2007-03-08
申请号:PCT/EP2006050220
申请日:2006-01-16
Applicant: BASF AG , GRIESBACH ULRICH , PUETTER HERMANN , WALDVOGEL SIEGFRIED R , MALKOWSKY ITAMAR
Inventor: GRIESBACH ULRICH , PUETTER HERMANN , WALDVOGEL SIEGFRIED R , MALKOWSKY ITAMAR
IPC: C25B3/10
CPC classification number: C25B3/10
Abstract: The invention relates to a method for producing hydroxy-substituted biarylene by the electrolytic oxidative electrodimerisation of a corresponding hydroxy-substituted aromatic, with the aid of an anodic surface containing a doped diamond layer.
Abstract translation: 本发明涉及一种用于通过使用阳极表面包括掺杂金刚石层中的相应的羟基取代芳烃的电解氧化electrodimerization制备羟基取代的联芳基化合物的方法。
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公开(公告)号:WO2005075709A2
公开(公告)日:2005-08-18
申请号:PCT/EP2005001066
申请日:2005-02-03
Applicant: BASF AG , ROMMEL CHRISTINA E , MALKOWSKY ITAMAR , WALDVOGEL SIEGFRIED , PUETTER HERMANN , GRIESBACH ULRICH
Inventor: ROMMEL CHRISTINA E , MALKOWSKY ITAMAR , WALDVOGEL SIEGFRIED , PUETTER HERMANN , GRIESBACH ULRICH
IPC: C25B3/10
CPC classification number: C25B3/10
Abstract: The invention relates to a method for producing biarylalcohols by means of the electrodimerisation of arylalcohols, said method comprising the following steps: a) an aryloxy compound of the alcohol to be coupled is produced with an element from the group B and Al; b) the aryloxy compounds obtained in a) are electrolytically oxidised and coupled to form the corresponding biaryl derivatives; and c) the desired biaryl alcohols are released. The inventive method enables the dimerisation of arylalcohols with a high degree of selectivity in order to obtain an ortho product.
Abstract translation: 本发明描述了通过包括以下步骤的芳基醇的electrodimerization为Biarylalkoholen的制备方法:a)制备醇的芳氧基化合物被加上从B组和Al的元素; B)电解氧化,并在获得的Arylloxyverbindungen的耦合),得到相应的二芳基衍生物; c)中释放期望的Biarylalkohole。 本发明的方法使得能够芳基醇的二聚化具有高选择性的邻位产物。
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公开(公告)号:CA2655862A1
公开(公告)日:2008-01-10
申请号:CA2655862
申请日:2007-06-27
Applicant: BASF AG
Inventor: GRIESBACH ULRICH , KULISCH JOERG , WALDVOGEL SIEGFRIED R , MALKOWSKY ITAMAR
IPC: C25B3/25 , C07C209/30
Abstract: The invention relates to a method for producing an amine, comprising the step of cathodic reduction of a corresponding oxime derivative of general fo rmula (I), wherein R represents C1-6 alkyl or C2-6 alkenyl, which is optiona lly substituted with one or more substituents independently selected from th e group consisting of phenyl, O-C1-6 alkyl, NH-C1-6 alkyl, N(C1-6 alkyl)2, O H and NH2; R1 represents H; C1-6 alkyl or C(O)-C1-6 alkyl and A represents a 5-, 6- or 7-membered hydrocarbon ring which is saturated or which has a dou ble bond and wherein optionally at least one CH2 group is replaced by -O-, - S- -NH-, -N=, or -N(C1-6 alkyl)- and which is optionally substituted with on e or more other substituents independently selected from the group consistin g of phenyl, C1-6 alkyl, O-C1-6 alkyl, NH-C1-6-alkyl, N(C1-6 alkyl)2, OH and NH2; and the oxime derivative, with respect to the carbon ring having the s ubstituent R, having an excess of the R or S form of at least 10 %.
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公开(公告)号:DE102004005508A1
公开(公告)日:2005-08-25
申请号:DE102004005508
申请日:2004-02-04
Applicant: BASF AG
Inventor: GRIESBACH ULRICH , PUETTER HERMANN , WALDVOGEL SIEGFRIED R , MALKOWSKY ITAMAR , ROMMEL CHRISTINA E
Abstract: The invention relates to a method for producing biarylalcohols by means of the electrodimerisation of arylalcohols, said method comprising the following steps: a) an aryloxy compound of the alcohol to be coupled is produced with an element from the group B and Al; b) the aryloxy compounds obtained in a) are electrolytically oxidised and coupled to form the corresponding biaryl derivatives; and c) the desired biaryl alcohols are released. The inventive method enables the dimerisation of arylalcohols with a high degree of selectivity in order to obtain an ortho product.
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公开(公告)号:DE102005003012A1
公开(公告)日:2006-07-27
申请号:DE102005003012
申请日:2005-01-21
Applicant: BASF AG
Inventor: GRIESBACH ULRICH , PUETTER HERMANN , WALDVOGEL SIEGFRIED R , MALKOWSKY ITAMAR
IPC: C25B3/29
Abstract: The invention relates to a method for producing hydroxy-substituted biarylene by the electrolytic oxidative electrodimerisation of a corresponding hydroxy-substituted aromatic, with the aid of an anodic surface containing a doped diamond layer.
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