公开(公告)号：JP2002012571A

公开(公告)日：2002-01-15

申请号：JP2001136616

申请日：2001-05-07

Applicant: BASF AG

Inventor： MERGER MARTIN ,  GERLACH TILL ,  SCHWAB EKKEHARD ,  WULFF-DOERING JOACHIM ,  MUHLER MARTIN ,  HAGEN VOLKER

IPC: B01J21/06 ,  B01J23/10 ,  C07B61/00 ,  C07C45/41 ,  C07C47/02 ,  C07C47/11 ,  C07C221/00 ,  C07C223/02

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing corresponding aldehydes in high yield and selectivity by reacting a carboxylic acid or an ester thereof with hydrogen. SOLUTION: This method for synthesizing the aldehyde of general formula I [R1 to R3 are each hydrogen, a 1-6C alkyl, a 3-8C cycloalkyl, an aryl, a 7-12C alkylphenyl or a 7-12C phenylalkyl, or R1 and R2 may form a 3- to 7-membered alicyclic ring by bonding to each other] comprises reacting the carboxylic acid or the ester thereof, represented by general formula II [R1 to R3 are same as the above; R4 is hydrogen, a 1-6C alkyl, a 3-8C cycloalkyl, an aryl, a 7-12C alkylphenyl or a 7-12C phenylalkyl] with the hydrogen in a vapor phase in the presence of a catalyst containing zirconium oxide and one or more kinds of lanthanoid elements in the presence of water.

公开(公告)号：JP2002003431A

公开(公告)日：2002-01-09

申请号：JP2001136178

申请日：2001-05-07

Applicant: BASF AG

Inventor： MERGER MARTIN ,  GERLACH TILL ,  SCHWAB EKKEHARD ,  WULFF-DOERING JOACHIM ,  MUHLER MARTIN ,  HAGEN VOLKER

IPC: B01J23/10 ,  C07B61/00 ,  C07C45/41 ,  C07C47/02 ,  C07C47/42

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an aldehyde in good yield and selectivity. SOLUTION: This method for producing an aldehyde represented by a formula (I) [R1, R2 and R3 are each hydrogen, a 1-6C alkyl, a 3-8C cycloalkyl, an aryl, a 7-12C alkylphenyl or a 7-12C phenylalkyl and R1 and R2 together may form a 3- to 7-membered alicyclic ring and R1 and R3 may each be a 1-4C alkoxy, phenoxy, methylamino, dimethylamino or halogen and R1 may be hydroxy or amino] comprises reacting a carboxylic acid (ester) represented by a formula (II) [R1, R2 and R3 are mentioned above; R4 is hydrogen, a 1-6C alkyl, a 3-8C cycloalkyl, aryl, a 7-12C alkylphenyl or a 7-12C phenylalkyl] with hydrogen in the presence of a lanthanum (III) oxide catalyst in vapor phase.

公开(公告)号：DE10121026A1

公开(公告)日：2002-02-07

申请号：DE10121026

申请日：2001-04-28

Applicant: BASF AG

Inventor： MERGER MARTIN ,  GERLACH TILL ,  SCHWAB EKKEHARD ,  WULFF-DOERING JOACHIM ,  MUHLER MARTIN ,  HAGEN VOLKER

IPC: B01J21/06 ,  B01J23/10 ,  C07B61/00 ,  C07C45/41 ,  C07C47/02 ,  C07C47/11 ,  C07C221/00 ,  C07C223/02 ,  C07B41/06 ,  C07C47/32 ,  C07C223/00

Abstract: Synthesis of aldehyde (I) involves reacting carboxylic acid (II) or its ester with hydrogen and water in gaseous phase, in the presence of a catalyst containing at least 60-99.9 weight% (wt.%) of zirconium oxide and 20 wt.% or less of lanthanides as catalyst active ingredients. Synthesis of aldehyde of formula (I) involves reacting carboxylic acid of formula (II) or its ester with hydrogen and water in the presence of a catalyst containing at least 60-99.9 wt.% of zirconium oxide and 20 wt.% or less of lanthanides as catalyst active ingredients. R , R , R , R = hydrogen, 1-6C alkyl, 3-8C cycloalkyl, aryl, 7-12C alkylphenyl or 7-12C phenylalkyl, preferably R , R together form 3-7C alicyclic ring, and preferably R , R = 1-4C alkoxy, phenoxy, methylamino, dimethylamino or halogen, more preferably R = hydroxy or amino.

公开(公告)号：DE10240128A1

公开(公告)日：2004-03-11

申请号：DE10240128

申请日：2002-08-30

Applicant: BASF AG

Inventor： BORCHERT HOLGER ,  SCHLITTER STEPHAN ,  MUHLER MARTIN ,  BUSSER WILMER

IPC: B01J23/68 ,  B01J37/02 ,  C07D301/10 ,  B01J27/25

公开(公告)号：DE10121028A1

公开(公告)日：2002-01-31

申请号：DE10121028

申请日：2001-04-28

Applicant: BASF AG

Inventor： MERGER MARTIN ,  SCHWAB EKKEHARD ,  WULFF-DOERING JOACHIM ,  MUHLER MARTIN ,  HAGEN VOLKER ,  GERLACH TILL

IPC: B01J23/10 ,  C07B61/00 ,  C07C45/41 ,  C07C47/02 ,  C07C47/42 ,  C07B41/06 ,  C07C47/32 ,  C07C221/00 ,  C07C223/00

Abstract: Manufacture of an aldehyde (I) involves gaseous phase reaction of carboxylic acid or its ester (II) with hydrogen in presence of a lanthanum trioxide catalyst. Manufacture of an aldehyde of formula (I) involves gaseous phase reaction of carboxylic acid or its ester of formula (II) with hydrogen in presence of a lanthanum trioxide catalyst. R , R , R = 1-6C alkyl, 3-8C cycloalkyl, aryl, 7-12C alkylphenyl or phenylalkyl; (R and R ) = 3-7 membered alicyclic ring; R , R = 1-4C alkoxy, phenoxy, methylamino, dimethylamino or halogen; R = hydroxy or amino; and R = H, 1-6C alkyl, 3-8C cycloalkyl, aryl, 7-12C alkylphenyl or phenylalkyl.