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    METHOD FOR THE PRODUCTION OF TETRAHYDROFURAN COPOLYMERS
    2.
    发明申请
    METHOD FOR THE PRODUCTION OF TETRAHYDROFURAN COPOLYMERS 审中-公开
    用于生产四氢呋喃的共聚物

    公开(公告)号：WO2004087787A3

    公开(公告)日：2005-01-06

    申请号：PCT/EP2004003345

    申请日：2004-03-30

    Applicant: BASF AG ,  HAUBNER MARTIN ,  PINKOS ROLF ,  SCHLITTER STEPHAN

    Inventor： HAUBNER MARTIN ,  PINKOS ROLF ,  SCHLITTER STEPHAN

    IPC: C08G65/20

    CPC classification number: C08G65/20 ,  C08G2650/08 ,  C08G2650/68

    Abstract: The invention relates to a method for single-step production of polyoxyalkylene glycols by copolymerization of THF and neopentyl glycol in the presence of a heteropoly acid, characterized in that the overall amount of all impurities of general formula (I), wherein R and R represent hydrogen when R is an oxyformyl or isopropionate radical, R represents hydrogen and R represents hydroxy when R is an isopropyl radical and R represents hydrogen when R and R together represent an OCH2-C(CH3)-CH2 radical, in the neopentyl glycol is less than 1000 ppm.

    Abstract translation: 本发明是一种用于单级制备聚氧化烯二醇的通过THF和在杂多酸的存在下的新戊二醇的共聚发现，其特点是在一个过程，在通式（I）的所有杂质的总量，其中R <1>和R <2 意味着>氢，当R <3>是Oxyformyl-或Isopropionatrest，R <2>的羟基<1>是氢并且R，当R <3>表示异丙基团和R <1>是氢，当R <2> 且R <3>一起形成-OCH 2 C（CH 3）-CH 2残基，新戊基二醇是小于1000ppm。

    TWO-STAGE METHOD FOR PRODUCING BUTANDIOL IN TWO REACTORS
    3.
    发明申请
    TWO-STAGE METHOD FOR PRODUCING BUTANDIOL IN TWO REACTORS 审中-公开
    两步反应器制备丁醇的两步法

    公开(公告)号：WO03104214A8

    公开(公告)日：2004-05-13

    申请号：PCT/EP0306060

    申请日：2003-06-10

    Applicant: BASF AG ,  HESSE MICHAEL ,  SCHLITTER STEPHAN ,  BORCHERT HOLGER ,  SCHUBERT MARKUS ,  ROESCH MARKUS ,  BOTTKE NILS ,  FISCHER ROLF-HARTMUTH ,  WECK ALEXANDER ,  WINDECKER GUNTHER ,  HEYDRICH GUNNAR

    Inventor： HESSE MICHAEL ,  SCHLITTER STEPHAN ,  BORCHERT HOLGER ,  SCHUBERT MARKUS ,  ROESCH MARKUS ,  BOTTKE NILS ,  FISCHER ROLF-HARTMUTH ,  WECK ALEXANDER ,  WINDECKER GUNTHER ,  HEYDRICH GUNNAR

    IPC: C07C29/149 ,  C07D315/00 ,  C07C31/20 ,  C07D307/20

    CPC classification number: C07D315/00 ,  C07C29/149 ,  C07C31/207

    Abstract: The invention relates to a method for producing optionally akyl-substituted 1,4-butandiol by two-stage catalytic hydration in the gaseous phase of C4 dicarboxylic acids and/or the derivatives thereof with the steps of: a) introducing a gaseous flow of a C4 dicarboxylic acid or a derivative thereof at 200 to 300 °C and 2 to 60 bar in a first reactor and catalytic gas phase hydration to a mainly optionally alkyl-substituted gamma-butyrolactone containing product; b) introducing the product flow so obtained into a second reactor at a temperature of from 150 °C to 240 °C and a pressure of from 15 to 100 bar and catalytic gas phase hydration to optionally alkyl-substituted 1,4-butandiol; c) removing the desired product from the intermediates, byproducts and possibly not reacted educt; d) optionally returning non-reacted intermediates to one or both hydration stages, whereby in both hydration stages one catalyst each is used which comprises = 5 % by weight, preferably 5 to 95 % by weight, especially 20 to 90 % by weight of an oxidic carrier, the pressure prevailing in the second reactor is higher than in the first reactor, and the product mixture removed from the first reactor is introduced into the second reactor without further purifying it.

    Abstract translation: 本发明涉及一种用于在C4二羧酸和/或其衍生物，包括以下步骤的气相制备任选被烷基取代的1,4-丁二醇，通过两阶段催化氢化：a）将C4二羧酸的气体流或它们的衍生物 在200〜300℃和2至在第一反应器和催化气相加氢在含有产物主要为任选被烷基取代的γ-丁内酯60巴; b）将由此获得进入第二反应器在150℃的温度至240℃的产品流和15至100巴和催化气相任选烷基取代的1,4-丁二醇的压力; c）从中间体，副产物和任选未反应的离析物中分离所需产物; d）任选地回收未转化的中间体在一个或两个氢化阶段，其中，在每种情况下，催化剂在两个氢化中使用的<= 95重量％，优选为5〜95重量％，特别是10至80重量％的CuO 和> = 5具有重量％，优选为5〜95重量％，特别是20至90重量的氧化载体的％，在第二反应器更高的压力占优势比在第一反应器和与第一反应器的产物混合物将取出的 不经进一步纯化而引入第二反应器中。

    METHOD FOR THE PRODUCTION OF DEFINED MIXTURES OF THF, BDO AND GBL BY GAS PHASE HYDROGENATION
    7.
    发明申请
    METHOD FOR THE PRODUCTION OF DEFINED MIXTURES OF THF, BDO AND GBL BY GAS PHASE HYDROGENATION 审中-公开
    PROCESS FOR通过气相氢化PRODUCING DEFINED MIXTURES FROM THF，BDO和GBL

    公开(公告)号：WO2005058853A3

    公开(公告)日：2005-08-04

    申请号：PCT/EP2004013811

    申请日：2004-12-04

    Applicant: BASF AG ,  ROESCH MARKUS ,  PINKOS ROLF ,  HESSE MICHAEL ,  SCHLITTER STEPHAN ,  JUNICKE HENRIK ,  SCHUBERT OLGA ,  WECK ALEXANDER ,  WINDECKER GUNTHER

    Inventor： ROESCH MARKUS ,  PINKOS ROLF ,  HESSE MICHAEL ,  SCHLITTER STEPHAN ,  JUNICKE HENRIK ,  SCHUBERT OLGA ,  WECK ALEXANDER ,  WINDECKER GUNTHER

    IPC: C07D307/08 ,  C07D307/33 ,  C07D307/32

    CPC classification number: C07D307/33 ,  C07D307/08

    Abstract: The invention relates to a method for variable production of mixtures of optionally alkyl-substituted BDO, GBL and THF by two-stage hydrogenation in the gaseous phase of C4-dicarboxylic acids and/or the derivatives thereof, characterized in that a) a gas flow of C4-dicarboxylic acids and/or the derivatives thereof is hydrogenated in a first stage in the gaseous phase on a catalyst at a pressure of 2-100 bars and at a temperature of 200 DEG C to 300 DEG C in a first reactor in the presence of a catalyst in the form of catalyst moulded bodies with a volume of less than 20 mm3, consisting of 5 - 95 wt. % Cu-oxide and 5 - 95 wt. % of an oxide with acid centres in order to form a flow maintly consisting of optionally aryl-substituted GBL and THF, b) succinic anhydride optionally arising therefrom is separated by partial condensation, c) the products THF, water and GBL which remain predominantly in the gaseous phase during said partial condensation are reacted at the same pressure or at a pressure which is reduced in order to reduce flow losses in the hydrogenation circuit at a temperature of 150 to 240 DEG C in a second reactor on a catalyst of > 95 wt. % CuO and 5 to 95 wt. % of one or several oxides selected from the group consisting of ZnO, Al2O3, SiO2, TiO2, ZrO2, CeO2, MgO, CaO, SrO, BaO, La2O3, and Mn2O3 in order to form a mixture consisting of a flow containing BDO, GBL and THF, d) the hydrogen is separated from the products and returned to the hydrogenation, e) the products THF, BDO, GBL and Wasser are separated in a distillatory manner, a flow rich in GBL is optionally returned to the second reactor or is optionally removed therefrom and BDO, THF and GBL are processed in a distillatory manner, and the ratio of the products THF, GBL and BDO is adjusted in relation to each other in the region of 10 to 100 wt. % THF, 0 to 90 wt. % GBL and 0 to 90 wt. % BDO exclusively by varying the temperatures in the two hydrogenation areas, in addition to that of the GBL return flow.

    Abstract translation: 本发明是一种用于在C4二羧酸和/或其衍生物的气相中的可变生产任选烷基取代的BDO，GBL的混合物，和THF通过两步氢化的方法中，在气相中的第一步骤a），其特征在于 以2至100巴的压力下的C4二羧酸和/或它们的衍生物的气体流过催化剂和200℃，在催化剂中的催化剂成型体的小的体积为一体的形式存在的温度〜300℃在第一反应器 20立方毫米，所述重量％Cu氧化物和氢化5至95重量具有酸性位点的主要来自任选烷基取代的GBL和THF电流含，b）可以通过琥珀酸酐得到的5至95，C的部分冷凝分离的氧化物％ ）在等于OD在气相产物THF，水和GBL通过部分冷凝保留了大部分 它超过= 95重量％的CuO的催化剂和5内流动损失在氢化电路减压和150至240℃的温度下在第二反应器至95重量选自氧化锌的一种或多种氧化物的％ 氧化铝，二氧化硅，二氧化钛，氧化锆，氧化铈，氧化镁，氧化钙，SRO，BaO的，镧，并流至BDO，GBL的混合物，以及含有的Mn2O3 THF反应。 d）分离从产物中的氢和再循环到氢化，E）产品THF，BDO，GBL和通过蒸馏分离水，GBL富流至第二反应器返回任选或任选ausschleust和BDO，THF和GBL后处理通过蒸馏 ，并在10〜彼此只通过在两个氢化区不同的温度THF，GBL和BDO的产物比例为100重量％THF，0至90重量GBL的％，和0至90重量％BDO 和任选的再循环流GBL被设置。

    10.
    发明专利
    未知

    公开(公告)号：DE102006009838A1

    公开(公告)日：2007-09-06

    申请号：DE102006009838

    申请日：2006-03-01

    Applicant: BASF AG

    Inventor： MAAS STEFFEN ,  JOHANN THORSTEN ,  KOCH MICHAEL ,  SIRCH TILMAN ,  SCHLITTER STEPHAN ,  RITTINGER STEFAN ,  STEINIGER MICHAEL

    IPC: C07C29/141 ,  B01J23/72 ,  C07C31/18 ,  C07C31/20

    Abstract: A process for catalytically hydrogenating methylolalkanals of the general formula in which R1 and R2 are each independently a further methylol group or an alkyl group having from 1 to 22 carbon atoms or an aryl or aralkyl group having from 6 to 33 carbon atoms, in the liquid phase over a hydrogenation catalyst, which comprises setting a pH of from 7.0 to 9.0 in the hydrogenation effluent by adding at least one tertiary amine, an inorganic base or an inorganic or organic acid to the hydrogenation feed.

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