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    1.
    发明专利
    未知

    公开(公告)号：DE2931737A1

    公开(公告)日：1981-02-26

    申请号：DE2931737

    申请日：1979-08-04

    Applicant: BASF AG

    Inventor： HEESE ANTON DIPL CHEM DR ,  NICOLAUS WALTER ,  SCHOLZ DANKMAR ING GRAD

    IPC: C08F283/00 ,  C08J3/28 ,  C08J5/24 ,  C08L67/06 ,  C08J5/04 ,  C08J7/08 ,  C08J7/18

    Abstract: A process for the production of moldings from unsaturated polyester resins wherein a mixture is first prepared from 1. an unsaturated polyester, 2. a copolymerizable vinyl compound, 3. an inhibitor, 4. a photoinitiator, 5. a thickener, preferably MgO, 6. a pulverulent auxiliary which transmits ultraviolet light and/or 7. a fibrous reinforcing material and 8. further conventional additives. This mixture is thickened, where appropriate after coating onto a sheet-like carrier, to form a semi-finished product, which is then finally shaped, and cured by UV irradiation after which it may or may not be heat-treated.

    UV curing unsaturated polyester compsns. - contg. acyl phosphine oxide cpds. as UV sensitisers
    8.
    发明专利
    UV curing unsaturated polyester compsns. - contg. acyl phosphine oxide cpds. as UV sensitisers 未知

    公开(公告)号：DE2909993A1

    公开(公告)日：1980-10-02

    申请号：DE2909993

    申请日：1979-03-14

    Applicant: BASF AG

    Inventor： HESSE ANTON DIPL CHEM DR ,  LECHTKEN PETER DIPL CHEM DR ,  NICOLAUS WALTER ,  SCHOLZ DANKMAR ING GRAD

    IPC: C07F9/32 ,  C07F9/53 ,  C08K5/5397 ,  C08L67/06 ,  C08K5/53 ,  C08L75/04 ,  C09D3/68 ,  C09D3/72 ,  C09D3/76 ,  C09D7/12

    Abstract: Light curing unsatd. polyester resin compsns. are made comprising (a) an unsatd. polyester resin, (b) a copolymerisable monomer (c) an inhibitor and (d) a UV sensitizer of formula R1R2-PO-CO-R3 (I) in which R1 and R2 (same or different) are 1-6C alkyl, cyclohexyl, cyclopentyl, aryl, halogen, alkyl- or alkoxy substd. aryl, or S- or N- contg. 5- or 6-membered heterocyclic gp.; or R2 may also be 1-6C alkoxy, aryloxy or arylalkoxy; or R1 and R2 together may form a ring; R3 is a 2-18C alkyl, 3-10C cycloaliphatic gp., phenyl, naphthyl, S-, O- or N-contg. 5- or 6-membered heterocyclic gp., which may opt. carry further substituents, or a gp. -X-CO-POR1R2, in which X is phenylene or a 2-6C (cyclo)aliphatic divalent gp. R1, R2 and R3 may be olefinically unsatd. The compsn. may als contain (d) paraffins, thermally decomposing initiators, fillers, reinforcing agents, lubricants, inert solvents, low shrink additives, etc. The acylphosphineoxide sensitizers give rapid curing of the compsn. on exposure to UV with less discolouration (yellowing) than with prior art UV sensitizers. The compsns. can be used for moulding, impregnation, coating etc.

    PROCESS FOR PRODUCING SHAPED ARTICLES FROM UNSATURATED POLYESTER RESINS
    10.
    发明专利
    PROCESS FOR PRODUCING SHAPED ARTICLES FROM UNSATURATED POLYESTER RESINS 未知

    公开(公告)号：DE3070577D1

    公开(公告)日：1985-06-05

    申请号：DE3070577

    申请日：1980-07-17

    Applicant: BASF AG

    Inventor： HESSE ANTON DR ,  SCHOLZ DANKMAR ,  NICOLAUS WALTER

    IPC: C08F283/00 ,  C08J3/28 ,  C08J5/24 ,  C08L67/06

    Abstract: A process for the production of moldings from unsaturated polyester resins wherein a mixture is first prepared from 1. an unsaturated polyester, 2. a copolymerizable vinyl compound, 3. an inhibitor, 4. a photoinitiator, 5. a thickener, preferably MgO, 6. a pulverulent auxiliary which transmits ultraviolet light and/or 7. a fibrous reinforcing material and 8. further conventional additives. This mixture is thickened, where appropriate after coating onto a sheet-like carrier, to form a semi-finished product, which is then finally shaped, and cured by UV irradiation after which it may or may not be heat-treated.

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